碳纤维表面特征对碳/环氧复合材料界面性能影响研究

为了研究碳纤维表面特征与碳/环氧复合材料界面剪切强度的定量关系。采用扫描电子显微镜、比表面积分析仪、X射线光电子能谱仪对T800级碳纤维表面形貌、比表面积和表面化学特征进行了测试表征,并使用微珠脱粘法测试了复合材料的界面剪切强度（IFSS）。基于碳纤维比表面积测试结果,引入真实界面面积的概念,重点分析了界面面积和化学特征对IFSS的影响机理和规律。结果表明,不同表面状态的T800级碳纤维比表面积存在明显差异,两种除浆方法处理的碳纤维比表面积相差25.4%。消除界面面积影响的真实界面剪切强度（IFSS’）与碳纤维表面氧碳比呈现出较好的线性相关性,R2达到了0.94。反映出提高碳纤维比表面积和表面氧碳比是改善复合材料界面性能的有效手段。同时,也为定量研究碳纤维表面物理和化学特征对复合材料界面性能的影响提供了一种新的分析思路。     

CFRP电流辅助铆接的连接域热响应建模与验证

钛合金铆钉变形时易不均匀、易开裂,在碳纤维增强树脂基复合材料（CFRP）铆接过程中引入脉冲电流作用,软化铆钉并改善其塑性。研究了连接域内的热响应机制与温度场分布,基于能量守恒、焦耳热定律、热传导定律构建了静态焦耳热模型表征稳态换热铆接工况下的CFRP温度,考虑铆接过程电流波动、温度分布不均和热区域分散性建立了动态温度场模型预测铆接过程温升。结果表明：CFRP孔周一定辐射半径范围处温度与钉中心温度线性相关,模型准确模拟出了40 s内的过程温度。静态模型在11%误差以内精准预测了中心饱和温度,动态模型模拟的温升趋势与实测温度值吻合较好。热量传递的滞后性使得动态模型对快速温升时的温度预测存在误差,该误差随电流密度变大而增加,最大达17.15%。接头损伤评估表明过程温度控制在150℃内时可获得质量合格的铆接接头。     

Wetting behavior of AgCu-4.5Ti filler reinforced by carbon nanotubes on C/C composite

The effect of Carbon Nanotubes (CNTs) content on the wettability of AgCu-4.5Ti + x CNTs (wt%) composite filler alloys on C/C composite was investigated. The results show that the added CNTs reacted with element Ti in the filler and produced the dispersed fine in situ synthesized TiC particles, which increased the consumption of element Ti and provided the nucleus for the growth of Ti-Cu compounds simultaneously. The above effects of introducing CNTs, inhibited the formation of Ti-Cu compounds, also changed the distribution of compounds, which dramatically influenced the interfacial microstructure and characteristics of wetting behavior. The increase of CNTs content refined and dispersed coarse Ti-Cu compounds, decreased the initial spreading temperature, and improved the wettability, but high content of CNTs (more than 0.3wt%) decreased the wettability of the filler alloy. The wetting interfacial microstructure of corresponding composite filler alloys were analyzed by Scanning Electron Microscope (SEM), Energy Dispersive X-ray Spectrometer (EDS) and Transmission Electron Microscope (TEM), which consisted of TiC, TiCu, TiCu₂ and TiCu₄ compound. The typical wetting behavior of AgCu-4.5Ti + 0.3wt% CNTs composite filler on C/C composite was divided into four stages. The effect mechanism of CNTs content on the wetting behavior was proposed.     

Laser joining of CFRTP to titanium alloy via laser surface texturing

Grid pattern was textured on Ti-6Al-4V alloy (TC4) substrate surface by nanosecond laser system. Laser joining of carbon fiber reinforced thermoplastic composite (CFRTP) to TC4 joints were performed, and the effect of texture grid depth was investigated. The contact angle of molten CFRTP on textured TC4 surface was measured and the tensile-shear force was tested. The fracture surface and interface morphology were observed. The results indicated that the wettability of molten CFRTP on TC4 surface improved remarkably after laser textured TC4. Shear force of CFRTP/TC4 joints was increased by 156% after laser textured TC4 surface. When the depth of grid was deeper than 100 μm, contact angle increased and incomplete filling of molten CFRTP in grid occurred, the shear force thus decreased gradually. Resin-carbon fibers mixture was adhered on the fracture surface of TC4, and the variation tendency of adhesion ratio was consistent with that of shear force. TC4 matrix was exfoliated from substrate and adhered at the fracture surface of CFRTP, indicating stronger mechanical interlocking occurred at the joining interface after laser textured TC4 surface. Beside mechanical interlocking, compound layer consisted of CTi_0.42V_1.58 carburization phase was also confirmed at interface, suggesting that chemical bonding also occurred at the joining interface.     

大尺寸CFRP固体火箭发动机壳体湿法缠绕用树脂配方研制

针对大尺寸炭纤维增强复合材料（CFRP）固体火箭发动机壳体的制备要求,研制了一种具 有良好粘度－温度及粘度－时间特性的炭纤维复合材料湿法缠绕成型树脂配方A。采用差示 扫描量热法（DSC）、傅立叶红外光谱（FT-IR）等分析技术对树脂基体的固化反应进行了系 统地研究,并测试了配方的粘度、力学性能及容器爆破强度。结果表明,该树脂配方A的反应 表观活化能为41.71 kJ／moL,室温下粘度低（≤0.5390 Pa·s）,适用期较长 （＞48 h ） ,不仅完全满足大尺寸CFRP固体火箭发动机壳体的湿法缠绕成型工艺要求,而且其树脂基体 及其炭纤维复合材料表现出优良的力学性能。炭纤维复合材料界面粘接良好,缠绕的
Φ150 mm容器的PV／W均大于48 km,纤维强度转化率达到89.0％以上。
     

碳纤维沥青裂解碳涂层研究

研究了沥青裂解法在碳纤维表面涂覆均匀碳涂层的工艺,并探讨了不同溶剂,不同浓度的涂层溶液对纤维表面形貌和纤维强度的影响。     

基于碳纳米纸的CFRP制孔质量控制

进行了钻削预埋碳纳米纸薄膜传感器碳纤维复合材料的试验,钻削结果采用超声波扫描显微镜进行检测.试验结果表明:层间预埋碳纳米纸,可以实时监测钻头位置,根据钻头位置改变进给率,实现对制孔质量的精确控制.采用ABAQUS对试验方案进行模拟仿真,模拟的结果与试验结果很好地吻合,证明了该方法的有效性.     

碳纤维复合材料卫星天线反射面型面精度稳定性分析

文章简述了卫星天线的组成、制造工艺过程,着重对影响天线反射面型面精度和尺寸稳定性有关内容,从材料特性、铺层分析、成型模具材料和产品质量控制等内容进行了分析。     

碳/环氧复合材料电池壁板的研制

航天器用电池壁板是由碳 /环氧复合材料制成的。文章介绍了其结构特征及研制过程中的技术问题 ,同时叙述了模具方面的有关内容     

碳含量对FGH4169合金组织的影响

通过组织观察及图像测量或统计计算分析了两种碳含量(0.022wt%、0.078wt%)对FGH4169合金的影响。结果表明,高碳含量的FGH4169合金平均晶粒尺寸较小,晶粒尺寸差异明显;碳含量对FGH4169合金中碳化物种类及形貌没有明显影响,但改变碳化物的尺寸,高碳含量的FGH4169合金更易形成PPB;低碳含量的FGH4169合金中强化相增多,强化相平均尺寸增大,强化相平均间隙减小,这有利于合金强度的提高。