二烯丙基双酚 A 共聚双马来酰亚胺改性氰酸酯树脂的性能

采用二烯丙基双酚A和二苯甲烷型双马来酰亚胺与双酚A型氰酸酯共聚,以改善氰酸酯树脂的工艺和耐热性能;利用DSC,TGA,DMA表征了树脂的固化行为和耐热性能;此外,还研究了树脂的力学性能及高频下的介电性能。结果表明,改性后的氰酸酯树脂固化反应温度降低了约60℃,改性树脂固化物在氮气气氛下Td5约400℃,Tg约270℃,显示了良好的耐热性能。在7~15 GHz宽频范围下,改性树脂的介电常数3,介电损耗0.008~0.01,显示了良好的介电性能。     

藜蒿中绿原酸溶剂提取方法研究

应用醇溶剂回流法提取藜蒿中绿原酸，通过正交试验，对藜蒿中绿原酸进行溶剂提取条件的优化研究，并分剐讨论了各因素对绿原酸提取率的影响。实验表明，乙醇浓度70％、12倍的提取剂用量、温度85℃、提取时间4h、提取两次为乙醇溶剂提取藜蒿中绿原酸的最佳条件，总绿原酸提取率为1.24％。     

海洋大气环境下微动开关触点回跳时间增大故障的试验复现与分析

结合某型微动开关触点回跳时间增大导致某系统故障问题,设计了由干湿交替酸性盐雾试验和湿热试验组成的海洋大气环境效应加速模拟试验剖面,选取与外场故障件型号一致的微动开关为研究对象,通过实验室加速模拟试验,成功复现了外场故障现象,并结合试验结果对腐蚀性环境、电烧蚀等因素对触点回跳时间增大的影响机制进行了分析。     

国内氰酸酯树脂增韧改性新技术研究进展

从增韧改性CE角度出发,介绍了近几年增韧改性氰酸酯树脂的方法,包括纳米粒子(SiO2、SiC)改性、笼型倍半硅氧烷(POSS)改性、热固性树脂(EP、BMI)改性、热塑性树脂改性及其他改性方法,并且着重阐述了增韧机理..     

双酚B型氰酸酯的制备与性能

研究了碱性催化法合成非晶态双酚B型氰酸酯的制备工艺,利用红外光谱(FTIR)、核磁共振(NMR)、热分析(DSC)、流变仪等方法分析了双酚B型氰酸酯的结构性能和工艺特性,研究和测试了树脂固化物介电性能、耐热性能和力学性能.研究结果表明,制备的双酚B型氰酸酯纯度高,200 ℃时的凝胶时间在100 min以上;该型氰酸酯具有较低的粘度(η_25℃=470 mPa·s,η_40℃=210 mPa·s),适于室温树脂传递模塑(RTM,Resin Transfer Molding)成型工艺;250 ℃固化后的介电常数为2.75,介质损耗角正切0.007(10 GHz),玻璃化转变温度299 ℃,弯曲强度174 MPa,模量3.2 GPa,综合性能优异.     

Investigation on Thermal and Dimensional Stability of Epoxy Resin In-Situ Modified by Cyanate Ester Resin and Polydimethylsiloxane

The thermal and dimensional stability of epoxy resin (EP) in-situ modified by cyanate ester (CE) and polydimethylsiloxane (PDMS) are investigated by means of experiments and numerical simulation. Thermal gravimetric analysis (TGA) and differential scanning calorimeter (DSC) are used to analyze the heat resistance of the modified EP. The dimensional stability is characterized by the volume shrinkage of the series PDMS/CE/EP obtained by the density method. The chemical structure of the PDMS/CE/EP is analyzed by Fourier transform infrared spectroscopy (FTIR). The results of TGA and DSC indicate that the thermal stability of PDMS/CE/EP decreases firstly and then increases with the increase in the amount of CE. The addition of PDMS shows a slight effect on the thermal stability. The 40% CE makes the blending system exhibit the lowest initial decomposition temperature, which reduces by 15.5% and 40.8% compared with pure EP and CE, respectively. The FTIR results suggested that the influence of CE on the thermal stability of the modified EP is mainly ascribed to the generation of oxazolidinone ring with low thermal stability and the increase in the triazine ring with high thermal stability. The volume shrinkage measurement results show that the introduction of CE and PDMS are both beneficial to the improvement of the dimensional stability of the blending systems. The in-situ addition of 80% CE shows the lowest volume shrinkage of 6.11%. The thermal stress distribution of PDMS/CE/EP generated during the solidification process is simulated by the finite element analysis. The results suggested that the introduction of 80% CE into EP results in the lowest thermal stress in the blending system, which indicates that the system has the lowest volume shrinkage, which agrees well with the experimental results.     

大型弹簧电镀锌工艺优化

采用扫描电镜(SEM)研究了发蓝、超声波酸洗前处理工艺对大型弹簧零件表面残余氧化皮的去除效果以及这两种前处理工艺对镀锌层的结合力与抗腐蚀性能的影响。结果表明,采用适当的发蓝、超声波酸洗等前处理工艺,能够有效去除零件表面顽固的残余氧化皮,较大幅度地提高镀锌层与金属基体的结合力,并提高镀锌层的抗腐蚀性能。     

Atmospheric Ion-induced Aerosol Nucleation

Ion-induced nucleation has been suggested to be a potentially important mechanism for atmospheric aerosol formation. Ions are formed in the background atmosphere by galactic cosmic rays. A possible connection between galactic cosmic rays and cloudiness has been However, the predictions of current atmospheric nucleation models are highly uncertain because the models are usually based on the liquid drop model that estimates cluster thermodynamics based on bulk properties (e.g., liquid drop density and surface tension). Sulfuric acid (H₂SO₄) and water are assumed to be the most important nucleating agents in the free troposphere. Measurements of the molecular thermodynamics for the growth and evaporation of cluster ions containing H₂SO₄ and H₂O were performed using a temperature-controlled laminar flow reactor coupled to a linear quadrupole mass spectrometer as well as a temperature-controlled ion trap mass spectrometer. The measurements were complemented by quantum chemical calculations of the cluster ion structures. The analysis yielded a complete set of H₂SO₄ and H₂O binding thermodynamics extending from molecular cluster ions to the bulk, based on experimental thermodynamics for the small clusters. The data were incorporated into a kinetic aerosol model to yield quantitative predictions of the rate of ion-induced nucleation for atmospheric conditions. The model predicts that the negative ion-H₂SO₄-H₂O nucleation mechanism is an efficient source of new particles in the middle and upper troposphere.     

用内文丘里管流量计测量酸气流量

介绍了新型差压装置--内文丘里管的结构、测量原理、技术性能;根据差压式流量计的测量原理,建立了计算酸气流量的数学模型,并将内文丘里管流量计成功地应用于酸气流量的测量.     

硝酸与固体燃料燃烧性能计算研究

建立了固液火箭发动机燃烧性能计算模型,采用一维化学平衡(ODE)方法对以硝酸为氧化剂的固液火箭发动机燃烧性能进行了初步探讨。计算表明,固液火箭发动机的比冲、特征速度和燃烧温度以及燃烧产物组分等与氧化剂和燃料的配比有密切关系,氧化剂与燃料质量配比在3.75附近时,固液火箭发动机内部的温度较高,燃烧产物组分以及特征速度达到最佳状态,比冲最高。