非硅氧化物的滤出及其机理探讨

 采用B核磁共振仪,激光拉曼光谱仪,隧道扫描显微镜及各种化学分析等方法,较系统地研究了沥滤温度、时间和酸液浓度对拉制的钠硼硅玻璃纤维纯度的影响。结果表明,高钝超细SiO_2,纤维可以用酸沥滤法获得;揭示了纤维中非硅氧化物沥出的规律;并初步探讨了沥滤机理,认为沥滤过程主要是B~(3+)和N~+与H~+发生交换扩散的过程。     

三硝基间苯二酚中硫酸测定的研究

本文研究了硫酸钡在氨水溶液中与ＥＤＴＡ的反应条件，提出用ＥＤＴＡ滴定法测定三硝基间苯二酚中的硫酸。本法准确度较高，稳定性好，操作简单，与样品标准值对照，结果满意。     

POSS 催化剂改性氰酸酯复合材料的性能

通过POSS 催化剂改性氰酸酯树脂,并采用热熔法排布制备了碳纤维/ 中温固化氰酸酯预浸料, 验证了改性氰酸酯的工艺性。同时考察了氰酸酯树脂及其复合材料的性能。结果表明, POSS 催化剂的加入, 降低了氰酸酯的固化温度,同时其使用温度、室温及-18℃的储存性能和复合材料力学性能与改性前相当。     

免维护铅酸蓄电池滤气片制造工艺研究

免维护铅酸蓄电池用滤气片的组成，烧结工艺及疏水处理工艺对孔隙率、透气率、疏水性及耐酸性有很大影响。以Ａｌ２Ｏ３和ＳｉＯ２为主要成份的滤气片在１１００～１６００℃烧结后，经聚四氟乙烯疏水处理后用于免维护电池，能有效地阻止水份的损耗。     

二烯丙基双酚 A 共聚双马来酰亚胺改性氰酸酯树脂的性能

采用二烯丙基双酚A和二苯甲烷型双马来酰亚胺与双酚A型氰酸酯共聚,以改善氰酸酯树脂的工艺和耐热性能;利用DSC,TGA,DMA表征了树脂的固化行为和耐热性能;此外,还研究了树脂的力学性能及高频下的介电性能。结果表明,改性后的氰酸酯树脂固化反应温度降低了约60℃,改性树脂固化物在氮气气氛下Td5约400℃,Tg约270℃,显示了良好的耐热性能。在7~15 GHz宽频范围下,改性树脂的介电常数3,介电损耗0.008~0.01,显示了良好的介电性能。     

藜蒿中绿原酸溶剂提取方法研究

应用醇溶剂回流法提取藜蒿中绿原酸，通过正交试验，对藜蒿中绿原酸进行溶剂提取条件的优化研究，并分剐讨论了各因素对绿原酸提取率的影响。实验表明，乙醇浓度70％、12倍的提取剂用量、温度85℃、提取时间4h、提取两次为乙醇溶剂提取藜蒿中绿原酸的最佳条件，总绿原酸提取率为1.24％。     

海洋大气环境下微动开关触点回跳时间增大故障的试验复现与分析

结合某型微动开关触点回跳时间增大导致某系统故障问题,设计了由干湿交替酸性盐雾试验和湿热试验组成的海洋大气环境效应加速模拟试验剖面,选取与外场故障件型号一致的微动开关为研究对象,通过实验室加速模拟试验,成功复现了外场故障现象,并结合试验结果对腐蚀性环境、电烧蚀等因素对触点回跳时间增大的影响机制进行了分析。     

国内氰酸酯树脂增韧改性新技术研究进展

从增韧改性CE角度出发,介绍了近几年增韧改性氰酸酯树脂的方法,包括纳米粒子(SiO2、SiC)改性、笼型倍半硅氧烷(POSS)改性、热固性树脂(EP、BMI)改性、热塑性树脂改性及其他改性方法,并且着重阐述了增韧机理..     

双酚B型氰酸酯的制备与性能

研究了碱性催化法合成非晶态双酚B型氰酸酯的制备工艺,利用红外光谱(FTIR)、核磁共振(NMR)、热分析(DSC)、流变仪等方法分析了双酚B型氰酸酯的结构性能和工艺特性,研究和测试了树脂固化物介电性能、耐热性能和力学性能.研究结果表明,制备的双酚B型氰酸酯纯度高,200 ℃时的凝胶时间在100 min以上;该型氰酸酯具有较低的粘度(η_25℃=470 mPa·s,η_40℃=210 mPa·s),适于室温树脂传递模塑(RTM,Resin Transfer Molding)成型工艺;250 ℃固化后的介电常数为2.75,介质损耗角正切0.007(10 GHz),玻璃化转变温度299 ℃,弯曲强度174 MPa,模量3.2 GPa,综合性能优异.     

Investigation on Thermal and Dimensional Stability of Epoxy Resin In-Situ Modified by Cyanate Ester Resin and Polydimethylsiloxane

The thermal and dimensional stability of epoxy resin (EP) in-situ modified by cyanate ester (CE) and polydimethylsiloxane (PDMS) are investigated by means of experiments and numerical simulation. Thermal gravimetric analysis (TGA) and differential scanning calorimeter (DSC) are used to analyze the heat resistance of the modified EP. The dimensional stability is characterized by the volume shrinkage of the series PDMS/CE/EP obtained by the density method. The chemical structure of the PDMS/CE/EP is analyzed by Fourier transform infrared spectroscopy (FTIR). The results of TGA and DSC indicate that the thermal stability of PDMS/CE/EP decreases firstly and then increases with the increase in the amount of CE. The addition of PDMS shows a slight effect on the thermal stability. The 40% CE makes the blending system exhibit the lowest initial decomposition temperature, which reduces by 15.5% and 40.8% compared with pure EP and CE, respectively. The FTIR results suggested that the influence of CE on the thermal stability of the modified EP is mainly ascribed to the generation of oxazolidinone ring with low thermal stability and the increase in the triazine ring with high thermal stability. The volume shrinkage measurement results show that the introduction of CE and PDMS are both beneficial to the improvement of the dimensional stability of the blending systems. The in-situ addition of 80% CE shows the lowest volume shrinkage of 6.11%. The thermal stress distribution of PDMS/CE/EP generated during the solidification process is simulated by the finite element analysis. The results suggested that the introduction of 80% CE into EP results in the lowest thermal stress in the blending system, which indicates that the system has the lowest volume shrinkage, which agrees well with the experimental results.