重复热处理对1J116材料磁性能及机械性能的影响

为研究Fe-Cr耐蚀软磁合金1J116经重复热处理后其磁性能和机械性能的变化,从数理统计、磁性能理论和微观组织分析等方面进行了比较研究和试验。结果表明重复热处理可显著提高材料的磁性能,不会引起材料机械性能的恶化,且使合金的塑性水平有一定程度的提高。     

Effect of Processing and Composition on the Structure and Properties of P/M EP741NP Type Alloys

A study was carried out on the effects of processing and composition on the structure and properties of P/M EP741NP type alloys. The objectives of this study were to understand the role of Hf in a P/M superalloy containing high niobium used in aircraft engines and to determine the effects of extrusion and forging the powders as contrasted to HIPing (hot isostatic pressing) only. Two alloys of the P/M EP741NP composition were atomized: one alloy contained 0.26%Hf and the other was Hf free. After the as-atomized powders from both alloys were characterized, the powders were extruded into billets, forged and heat treated. After each process, the microstructures were characterized by SEM and the phases were extracted and identified by X-ray diffraction. The presence of Hf in the residues was probed by EDS (energy dispersive spectroscopy). The alloys were given the published Russian heat treatment as well as a more conventional heat treatment more typical of western powder alloys. Tensile, creep and stress rupture mechanical property tests were run. Results of the structural behavior of the alloys after each processing step will be presented and discussed. The role of the Hf on the mechanical proper- ties will be discussed.     

Interfacial Properties Modification of Carbon Fiber/ Polyarylacetylene Composites

This work was dedicated to performing surface oxidation and coating treatments on carbon fibers (CF) and investigating the changes of fiber surface properties after these treatments, including surface composition, relative volume of functional groups, and sur- face topography with X-ray photoelectron spectroscopy (XPS) and atom force microscopy (AFM) technology. The results show that, after oxidation treatments, interfacial properties between CF and non-polar polyarylacetylene (PAA) resin are remarkably modified by removing weak surface layers and increasing fiber surface roughness. Coating treatment by high char phenolic resin solution after oxida- tion makes interface of CF/PAA composites to be upgraded and the interfacial properties further bettered.     

ZL114A合金疲劳行为研究

研究ZL114A合金的拉伸性能和轴向应力疲劳行为(K1=1,R=-1).结果表明,ZL114A合金的疲劳性能与美国A357合金的疲劳性能相当.系统研究了L114A合金疲劳损伤特征,分析疏松、夹杂物等铸造缺陷在疲劳裂纹的形核、裂纹的扩展以及瞬断中所起的作用,表明铸造过程中形成的铸造缺陷数量、尺寸、位置对金属的疲劳性能都有不同程度的影响.     

小角度晶界对单晶高温合金DD6持久性能的影响

在800℃,850℃和900℃的温度条件下,研究小角度晶界对第二代单晶高温合金DD6持久性能的影响.结果表明,带有小角度晶界合金的持久性能低于[001]取向DD6合金的持久性能.并且,随着晶界角度的增加,持久性能具有明显的降低倾向.晶界角度较大时,带有小角度晶界合金的持久性能明显低于[001]取向的性能.晶界角度较小时,与[001]取向相比,800℃温度条件下带有小角度晶界合金的持久性能明显较低;而在850℃和900℃的温度条件下,尽管带有小角度晶界合金的持久性能较低,但数值与[001]取向的性能相差不大,表明随着温度的升高,小角度晶界对持久性能的影响减弱.     

热暴露对TC11钛合金断裂行为的影响

对TC11钛合金经不同温度和时间热暴露后的拉伸性能进行了考察,对不同热暴露后断裂行为的变化及其原因进行了分析研究。结果表明,热暴露温度不高于550℃,热暴露后的室温拉伸性能与未处理时相差不大,断面由纤维区和剪切唇区组成,无放射区;热暴露温度高于550℃时,热暴露后TC11钛合金的塑性急剧下降,断面由放射区和剪切唇区组成,无纤维区,且放射区收敛于断面上靠近试样表面附近,点源。放射区微观上可见韧窝、准解理及沿相界、晶界分离的混合形貌特征,不同于纤维区的等轴韧窝形貌,且剪切唇区可见解理、准解理脆性断裂特征。热暴露后TC11钛合金这种宏微观断裂行为的变化是由试样表面氧污染层的缺口效应、针状α2(Ti3Al)相的析出以及次生α与β的长大所致。     

热压辅助先驱体裂解制备的三维Cf／Si—O—C复合材料的微观结构与力学性能

采用聚硅氧烷(PSO)先驱体浸渍裂解工艺制备出碳纤维三维编织物增强Si—O—C复合材料(3D-B C_(?)/Si—O—C)。研究发现,第一周期采用热压辅助裂解可以显著提高材料的力学性能与致密度。第一周期经1600℃、10MPa的条件热压裂解处理5min后,材料的弯曲强度和断裂韧性从未处理前的246.2MPa和9.4MPa·m~(1/2)提高到502MPa和23.7MPa·m~(1/2)。该材料的弯曲强度在真空中可以保持到1400℃。探讨了工艺参数对材料结构与力学性能的影响。高温裂解弱化界面结合同时提高纤维就位强度以及加压提高材料致密度是热压辅助裂解能提高材料力学性能的主要原因。     

Z-pin增强泡沫夹层结构面压缩性能研究

Z-pin增强泡沫夹层结构作为一种新兴的复合材料夹层结构形式,能够克服传统蜂窝夹层结构的诸多缺陷。采用预浸碳纤维增强Rohacell夹芯,进行Z-pin角度为15°和25°,夹芯厚度分别为12.7mm和8mm两种Z-pin增强泡沫夹层结构的面内压缩性能试验,并与相同批次和尺寸的未增强件进行对比,考察其对传统泡沫夹层结构的增强作用。试验发现X状Z-pin增强能够大幅度提高夹层结构的压缩强度与刚度。同时,增强材料表现出与传统泡沫夹层结构不同的压缩变形与破坏模式。证实Z-pin的弹性屈曲控制着结构的压缩强度,夹芯厚度和Z-pin角度影响Z-pin屈曲的计算长度,从而成为材料压缩强度的控制因数。在此基础上,考虑面板对Z-pin的有限转动约束,通过引进约束修正系数改进现有的压缩强度预测模型,预测值与试验结果更加接近。     

不同粒径SiC对氟醚橡胶性能的影响

研究了不同粒径SiC对氟醚硫化胶力学性能,导热性能和摩擦磨损性能的影响.结果表明,随着SiC粒径的减小,橡胶100%定伸模量增大,拉伸强度提高;填充体积含量为15%的20nm SiC时橡胶的综合力学性能比较优异;大粒径SiC与基体间的界面热阻更小,比小粒径填料更能提高橡胶的导热性能;不同粒径的SiC以一定比例并用也可以提高橡胶的导热系数;SiC晶须能显著提高橡胶的摩擦磨损性能.     

固体推进剂火箭发动机贮存性能规律研究

依据固体推进剂火箭发动机大量试验数据的统计规律，提出了估算固体推进剂火箭发动机主要参量随贮存年限、温度变化而改变的数学关系式：R^1=KRR0(1 a)^△t-1，并通过了反算、验证试验和实际中的应用。