High-temperature oxidation behavior and analysis of impedance spectroscopy of 7YSZ thermal barrier coating prepared by plasma spray-physical vapor deposition

Quasi-columnar structure 7YSZ(yttria stabilized zirconia) thermal barrier coatings(TBCs) are prepared by plasma spray-physical vapor deposition(PS-PVD) onto pretreated and un-pretreated bond coating, respectively. An isothermal oxidation experiment of 7YSZ TBCs is carried out in the atmosphere of 950 °C in order to simulate the high-temperature oxidation process of engine blades. The isothermal oxidation process of 7YSZ thermal barrier coatings is investigated systematically by impedance spectroscopy. The electrochemical physical model and equivalent circuit of columnar 7YSZ coatings are established. Results show that the isothermal oxidation kinetic curve of columnar 7YSZ thermal barrier coatings appears to follow the parabolic law. A pretreatment of bond coating can reduce the growth rate of the thermally grown oxide(TGO) layer, restraining the initiation and propagation of microcracks between YSZ and TGO layers. The oxidation rate constants of 7YSZ coatings with pretreated and un-pretreated bond coating are 0.101×10~(-12) cm~2·s~(-1) and 0.115 × 10~(-13) cm~2 ·s~(-1), respectively. Impedance analysis shows that the content of oxygen vacancies decreases and the density increases after the TGO layer is oxidized for 150 h. In addition, shrinkage microcracks formed by sintering during the oxidation process is the main reason for an increase of the capacitance and a decrease of the resistance in the grain boundary of YSZ.     

复合材料界面的微观力学行为研究单纤维拉出试验

使用一专门设计的模型制作了碳化硅／玻璃复合材料单纤维拉出试样。利用纤维拉曼峰波九偏移一纤维所受应变的近似线性关系,首先测定纤维热残余应变的分布,随后对伸出玻璃基体外的纤维段施加给定的拉伸应变,沿纤维轴向用拉曼光谱术逐点测定基体内外纤维的应变,最后依据力平衡原理将应变分布转换为界面剪切应力沿纤维轴向的分布。结果表明：在给出一实验参数下,界面传递应力长度为０．１８ｍｍ,最大界面剪切应力的位置在ｘ为０．     

基于差分吸收光谱技术的烟道SO2浓度的测量

利用差分光谱吸收（DOAS）技术，测量大气中痕量污染气体的浓度，是当前环保行业一项热门技术。对此方法适当改进，可以用来监测工业烟道排出的SO2的浓度和排放量，研究了利用DOAS技术测量烟气的测量方法、数据处理以及减小误差的方法，实现了烟气中SO2的在线实时测量。     

燃烧场吸收光谱诊断技术研究进展

基于可调谐半导体激光吸收光谱（TDLAS）的视线测量技术,有能力实现流场温度、速度、组分浓度等参数的快速测量。作为一种有效的诊断工具,TDLAS传感器已经在燃烧和推进系统的研究和开发中获得广泛应用,为改善系统的性能发挥着越来越重要的作用。新应用机会的出现,对传感器提出新挑战的同时也促进了相关技术的进步。概括介绍了TDLAS技术的发展水平、在燃烧场诊断中的应用及未来的潜力,为相关研究人员提供参考。     

Status of the Stratospheric Observatory for Infrared Astronomy (SOFIA)

The Stratospheric Observatory for Infrared Astronomy (SOFIA), a joint US/German project, is a 2.5-m infrared airborne telescope carried by a Boeing 747-SP that flies in the stratosphere at altitudes as high as 45,000 ft (13.72 km). This facility is capable of observing from 0.3 μm to 1.6 mm with an average transmission greater than 80% averaged over all wavelengths. SOFIA will be staged out of the NASA Dryden Flight Research Center aircraft operations facility at Palmdale, CA. The SOFIA Science Mission Operations (SMO) will be located at NASA Ames Research Center, Moffett Field, CA. First science flights began in 2010 and a full operations schedule of up to one hundred 8 to 10 hour-long flights per year will be reached by 2014. The observatory is expected to operate until the mid-2030s. SOFIA’s initial complement of seven focal plane instruments includes broadband imagers, moderate-resolution spectrographs that will resolve broad features due to dust and large molecules, and high-resolution spectrometers capable of studying the kinematics of atomic and molecular gas at sub-km/s resolution. We describe the SOFIA facility and outline the opportunities for observations by the general scientific community and for future instrumentation development. The operational characteristics of the SOFIA first-generation instruments are summarized. The status of the flight test program is discussed and we show First Light images obtained at wavelengths from 5.4 to 37 μm with the FORCAST imaging camera. Additional information about SOFIA is available at http://www.sofia.usra.edu and http://www.sofia.usra.edu/Science/docs/SofiaScienceVision051809-1.pdf.     

耐碱棉纸中含铁量的测定方法

用Ｎ２ＯＣ２Ｈ２原子吸收法来测定某型导弹热电池耐碱棉纸中的铁含量。并对测定条件和干扰困素进行了综合考虑。该测定方法具有很好的灵敏度，很好的精确度、干扰少、选择性和重现性好等优点。相对标准偏差ＲＳＤ＜１．０％（ｎ＝１０）。标准加入回收率均在９８％～１０２％（ｎ＝３）范围内。完全适用于耐碱棉纸中的含铁量的控制和样品系统分析。在实际应用中取得了很好的效果。     

Instrument concept and preliminary performance analysis of GLORIA

The Global Radiance Limb Imager Experiment for the Atmosphere (GLORIA) shall provide a detailed global picture of the upper troposphere/lower stratosphere region (UTLS) and make available novel information on small-scale atmospheric dynamics.

The instrument will be a space borne imaging Fourier Transform Spectrometer operating in the thermal infrared spectral region. It will produce spectrally resolved images of the earth’s limb with a vertical extension of 60 km and a horizontal extension of 400 km. The paper focuses on the preliminary instrument concept and on results of studies concerning sensitivity and spectrometric performance. GLORIA has been proposed as a national German space mission. An aircraft version is currently under development.     

月壤含水特性原位快速预判传感器设计与验证

基于月壤和水冰对不同谱段近红外激光存在吸收/反射差异性的特点,提出了采用多模近红外激光光强差异反演月壤含水特性的水冰原位快速预判方法。通过发射/接收光路同轴设计及多模激光光路分时复用设计,实现了多模激光光学系统轻小型化设计,研制出基于多模近红外激光的月壤水冰原位快速预判传感器工程样机,并开展了针对低含水率极区模拟月壤的含水特性原位预判试验。试验结果表明：该传感器水冰检测限可达0.39%,单次预判时间可优于1 s,光斑直径@检测距离为5 cm@500 mm,传感器具备对地面模拟月壤含水特性进行原位快速预判的能力。     

An in situ laser induced breakdown spectroscope (LIBS) for Chandrayaan-2 rover: Ablation kinetics and emissivity estimations

A miniaturized in situ laser induced breakdown spectroscope-LIBS is one of the two lunar rover payloads to be flown in India’s next lunar mission Chandrayaan-2, with an objective to carry-out a precise qualitative and quantitative elemental analyses of lunar regolith at the proximity of the landing region. As per the imposed mission constraints and the executed design optimization studies, a compact and light-weight LIBS prototype model is developed at our premises. This paper mainly concerns with the estimation of theoretical aspects; especially on evaluation of elemental ablation parameters and signal-to-noise ratio (SNR) calculations for the designed instrument. Theoretical estimations and simulations yielded an incident laser power density of the order of 5 × 10¹⁰ W/cm² on the target surface at a defined lens-to-surface distance (LTSD) of 200 mm and revealed an SNR > 100 for most of the elements under consideration. This paper also addresses the impact of LTSD variation on detection capability. The estimation of plasma-temperatures was carried out utilizing the emission spectra obtained under high vacuum environments employing the LIBS laboratory model. Experimental investigations and the performed theoretical estimations asserted the successful operation of the configured LIBS instrument for in situ elemental analyses on lunar surface.     

Characterization of lunar soils through spectral features extraction in the NIR

Recently launched hyper-spectral instrumentation with ever-increasing data return capabilities deliver the remote-sensing data to characterize planetary soils with increased precision, thus generating the need to classify the returned data in an efficient way for further specialized analysis and detection of features of interest. This paper investigates how lunar near-infrared spectra generated by the SIR-2 on Chandrayaan-1 can be classified into distinctive groups of similar spectra with automated feature extraction algorithms. As common spectral parameters for the SIR-2 spectra, two absorption features near 1300 nm and 2000 and their characteristics provide 10 variables which are used in two different unsupervised clustering methods, the mean-shift clustering algorithm and the recently developed graph cut-based clustering algorithm by Müller et al. (2012). The spectra used in this paper were taken on the lunar near side centering around the Imbrium region of the Moon. More than 100,000 spectra were analyzed.