用固体吸附/分光光度法同时监测空气中的肼、一甲肼和偏二甲肼

介绍了用一甲肼浓缩采样采集空气中三肼混合气体,用分光光度法分别测出肼、一甲肼和偏二甲肼各组分的含量。测定结果通过标准气验证,相对误差小于１７％,各组份回收率均大于８０％。本方法适用于空气中低浓度三肼废气的测定。     

乙酸铈晶体的红外光谱与热分析

本文制备了乙酸铈品体,EDTA络合滴定法测定其中铈的含量,利用傅立叶变换红外光谱仪对其进行了红外光谱分析,利用高温综合热分析仪对其进行了热重和差热分析,讨论了乙酸铈晶体在空气气氛中的热分解机理。     

激光照射离体血液的衰变规律

采用FLS900型稳态荧光光谱仪对激光持续照射的离体血液进行了荧光检测,得到了血液成分变化及荧光光谱特征随时间衰变的规律。实验结果表明：随着血液离体时间的延长,当受407nm的光激励时,605nm处的荧光峰峰位保持不变仅强度缓慢减弱。但在离体后的14h出现了谱形突变,并在474nm处产生了一个强荧光峰。分析认为,激光对离体血液的衰变有明显的延缓作用,但当激光持续照射一定时间后却导致了细胞的形态改变进而加速了细胞的溶血进程,产生了大量的内源性荧光物质还原烟碱腺嘌呤二核苷酸。研究结果为研究血细胞的活性衰变及细胞功能结构异常等提供了参考。     

沸石分子筛对航天器分子污染物的吸附性能研究

针对空间环境中有机污染物沉积在航天器敏感部件上造成相关功能失效问题,提出一种利用沸石分子筛多孔结构在轨清除有机污染物的新方法。研究了真空环境中,Naβ、NaY、13X三种分子筛对某型号电缆真空放气产物的吸附能力,结果表明13X的吸附能力优于其它两种分子筛,饱和吸收率为14.03%。将其作为分子吸附器的吸附材料应用到航天器易污染的部位,将会有效控制航天器在轨运行的污染水平,提高可靠性。     

磁过滤直流真空阴极弧制备类金刚石膜的结构和力学性能研究

采用磁过滤直流真空阴极弧沉积技术在硅片、不锈钢片基体上制备了类金刚石(DLC)膜。检测结果表明,膜中存在着微米级的大颗粒分布,膜厚为290nm,sp3键的含量为62.23%。所制备的薄膜具有典型的DLC膜Raman光谱特征,耐磨性能优良,膜与基体的结合性能良好。     

微等离子体转化二氧化碳发射光谱诊断

火星大气层的主要成分为二氧化碳,如果能够利用低温等离子体方法高效分解二氧化碳,使其转化为氧气和一氧化碳加以利用,可以大幅降低航天员生命保障相关载荷长途运输的成本,进一步提高生命保障能力.低温等离子体放电过程中会产生大量活性组分,可以在数百度温度下实现二氧化碳的高效解离,是具有很大潜力的二氧化碳解离与转化方式.设计了一种...     

Triton, Pluto, Centaurs, and Trans-Neptunian Bodies

The diverse populations of icy bodies of the outer Solar System (OSS) give critical information on the composition and structure of the solar nebula and the early phases of planet formation. The two principal repositories of icy bodies are the Kuiper belt or disk, and the Oort Cloud, both of which are the source regions of the comets. Nearly 1000 individual Kuiper belt objects have been discovered; their dynamical distribution is a clue to the early outward migration and gravitational scattering power of Neptune. Pluto is perhaps the largest Kuiper belt object. Pluto is distinguished by its large satellite, a variable atmosphere, and a surface composed of several ices and probable organic solid materials that give it color. Triton is probably a former member of the Kuiper belt population, suggested by its retrograde orbit as a satellite of Neptune. Like Pluto, Triton has a variable atmosphere, compositionally diverse icy surface, and an organic atmospheric haze. Centaur objects appear to come from the Kuiper belt and occupy temporary orbits in the planetary zone; the compositional similarity of one well studied Centaur (5145 Pholus) to comets is notable. New discoveries continue apace, as observational surveys reveal new objects and refined observing techniques yield more physical information about specific bodies.     

Pre-Main Sequence Stars Seen by ISO

Observations of pre-main sequence objects (T Tauri, Herbig Ae/Be and FU Orionis stars) obtained with the instrumentation on board the Infrared Space Observatory (ISO) are reviewed. All the observations have been mainly carried out by using the two spectrographs SWS and LWS, adopting their low resolution modes and such data have been used both for lines detection and to reconstruct the spectral energy distributions. Line emission and photometric behaviour of pre-main sequence objects have been analyzed in the framework of the current models, discussing the agreement (or disagreement) with them and trying to derive the questions which should be answered by the forthcoming FIR instrumentation. Based on observations with ISO, an ESA project with instruments funded by ESA Member States (especially the PI countries: France, Germany, The Netherlands, and the United Kingdom), and with the participation of ISAS and NASA.     

The Cool Interstellar Medium

Infrared spectroscopy and photometry with ISO covering most of the emission range of the interstellar medium has led to important progress in the understanding of the physics and chemistry of the gas, the nature and evolution of the dust grains and also the coupling between the gas and the grains. We review here the ISO results on the cool and low-excitation regions of the interstellar medium, where T _gas≲ 500 K, n _H∼ 100–10⁵ cm⁻³ and the electron density is a few 10⁻⁴. JEL codes: D24, L60, 047 Based on observations with ISO, an ESA project with instruments funded by ESA Member States (especially the PI countries: France, Germany, The Netherlands, and the United Kingdom), and with the participation of ISAS and NASA.     

内反射红外光谱在污染物成分测试中的应用

介绍了内反射光谱的原理及其在放气沉积污染物成分测试中的应用。