激光熔覆纳米TiN-Ni45A复合涂层组织与性能

在38CrMoAl表面激光熔覆了纳米TiN-Ni45A复合涂层.利用X射线衍射仪、扫描电镜、电子探针、显微硬度计和摩擦磨损试验机,系统分析了纳米TiN含量对复合涂层的相组成、微观组织、硬度和摩擦磨损性能的影响.研究表明,不同纳米TiN含量的镍基复合涂层主要是由γ-Ni树枝晶、(γ-Ni+Ni3B)共晶,以及分布于γ-Ni晶粒内的M23C6和TiN硬质相所组成.当纳米TiN的添加量为5.0％(质量分数)时,复合涂层中γ-Ni树枝晶发生了明显粗化,且其数量有所增加.而当纳米TiN的添加量超过5.0％时,γ-Ni树枝晶则开始逐渐细化,其数量逐渐减少,且树枝晶的生长形态逐渐由等轴树枝晶转变为柱状树枝晶.与此同时,通过团聚长大的微米TiN颗粒数量逐渐增多,分布也越趋均匀.随着纳米TiN添加量的增加,复合涂层的平均硬度在整体上呈逐渐增加的变化趋势,减摩性和耐磨性在纳米TiN的添加量为15.0％时达到最优,其摩擦系数和磨损体积较未添加纳米TiN的镍基合金涂层分别降低了8.7％和32.3％,而平均硬度值则提高了7.0％.     

ZL205A铝合金大型复杂筒体构件淬火过程模拟与变形预报

基于ABAQUS软件采用有限元方法建立ZL205A铝合金大型复杂构件淬火过程的温度场与应力场模型,分析构件在淬火过程中不同时刻的温度场分布.根据构件结构特征,选择4个特征点获得淬火过程冷却曲线,并对构件厚壁、加强筋与薄壁部分的冷却曲线进行研究,使用有限元模拟方法预报构件变形和残余应力.ZL205A铝合金大型复杂构件淬火变形主要为径向变形,通过比较淬火后残余应力的6个分量可知正应力远大于剪应力.模拟厚壁在不同换热系数下的淬火效果,发现增加换热系数可以提高厚壁淬火冷却速度,但是作用比较有限.     

Ti2AlNb合金双层辉光等离子表面渗钼的扩散行为研究

Ti2AlNb合金(O相)具有高的比强度、断裂韧性以及优良的抗蠕变性能,因而在航空制造中成为一种颇具吸引力的高温结构材料.但是,较差的耐磨性是其主要的缺陷并限制其实际应用.为解决这一问题,对Ti2AlNb合金进行双层辉光等离子表面渗Mo.探讨主要工艺参数对Mo的扩散行为的影响.采用扫描电镜(SEM)、X射线衍射(XRD)和辉光放电光谱仪(GDS)分析表面合金化层的成分分布和微观结构.测定从表面到中心的显微硬度变化曲线.结果表明温度与时间均对扩散过程具有显著的影响.最后通过回归分析计算出在优化的工艺温度980℃下的扩散系数.     

Investigation on a Sol-gel Coating Containing Inhibitors on 2024-T3 Aluminum Alloy

For a long time, chromate incorporated conversion coatings have been drawn special attention in corrosion protection of air-craft-used aluminum alloys. However,ever-increasing environmental pressures requires that non-chromate conversion coatings be developed because of the detrimental carcinogenic effects of the chromate compounds. In recent years, the sol-gel coatings doped with inhibitors were developed to replace chromate conversion coatings, and showed real promise. A sol-gel coating was prepared and its anti-corrosion behavior was investigated using the potentiodynamic scanning (PDS) and the electrochemical impedance spectroscopy (EIS). It is found that the sol-gel coating obtained by the hydrolysis and condensation of 3-glycidoxypropyltrimethoxysilane (GPTMS) and tetramethoxysilane (TMOS) is prone to form defects if cured at the room temperature, whereas if cured at a higher temperature (100 ℃), these flaws can be avoided. Furthermore, it can be seen that addition of anti-foam agents and surfactants will reduce the faults if cured at the room temperature. Effects of the corrosion inhibitors, CeCl3 and mercaptobenzothiazole (MBT), in the sol-gel coatings on 2024-T3 aluminum alloy were also investigated. Results show that the corrosion resistance of the sol-gel coatings containing CeCl3 proves to be better than that of the pure and MBT added sol-gel coatings by the electrochemical methods.     

Electrolytic Passivation of Nitinol Shape Memory Alloy in Different Electrolytes

The corrosion behavior of the nitinol alloy was studied in various corrosion media of different Cl^- ion concentrations. The results demonstrate that the Cl^- ion concentration has significant influences on the corrosion behavior of the nitinol alloy. In order to enhance the corrosion resistance, protective films were generated on the surface of the nitinol alloy by means of the electrochemical passivation method, for which five different electrolytic solutions were investigated. The surface analysis indicates full growth of all samples passivated in the different electrolytic solutions with layers, however, showing different morphological features. Without any defects like micro-cracks and pores, the surface of the samples passivated in the molybdate solution turns out smoother and denser than those passivated in other solutions. It is shown that the electro-chemical passivation will reduce Ni content but increase Ti content in the surface, reaching the Mole ratio of Ti：Ni = 9.01：1 on the outermost surface. Potentiodynamic polarization test demonstrates that the samples electrochemically passivated in the molybdate solution present a significant increase in breakdown potential due to titanium enrichment on the outermost surface.     

Microstructure and Mechanical Properties of Cross-rolled Ti50Ni47Fe3 Shape Memory Alloy

The microstructures, the phase transformation characteristics, and the mechanical properties of the Ti50Ni47Fe3 alloy in as-forged and as-cross-rolled states were investigated. It is found that, after cross-rolling, the phase transformation temperature （Ms） of the alloy decreases drastically and the grains get refined. Moreover, its yield strength and fracture strength after cross-rolling hit 540 MPa and 687 MPa respectively, up by about 200 MPa over those in as-forged state.     

Deformation Behavior of Mg-8 wt%Li Alloy under High-speed Impact

Deformation behavior of the Mg-8 wt%Li alloy at high strain rate was studied by means of the Split Hopkinson Pressure Bar （with strain rate of 10^3 s^-1）. It is found that shear localization proves to be the main damage mode for the alloy during dynamic loading. Strain and strain rate arc the two necessary parameters affecting the occurrence of deformation and shear bands. Deformation bands begin to form when the strain and strain rate reach 0.20 and 1 900 s^-1 respectively and will develop gradually with the strain rate increasing. Besides, deformation bands will transform into shear bands when the strain and strain rate reach above 0.25 and 3 500 s^-1 separately.     

Al-5.3Cu-0.8Mg-0.6Ag合金的超塑性变形

研究了Al-5.3Cu-0.8Mg-0.6Ag合金板在400～520℃以及应变速率为1×10^-4 ～ 1×10^-1/s下的超塑性变形能力及其变形机制.结果显示,轧制态的Al-5.3Cu-0.8Mg-0.6Ag合金在500℃及应变速率5×10^-4/s时的最大伸长率为320%,应变速率敏感系数m达到0.58.高应变速率下超塑性变形过程中主要机制为晶界滑动,协调机制则是空洞的形核长大与断裂.     

Ti2AlNb基合金的研究进展

着重介绍了Ti2AlNb基合金的成分、显微组织及性能，综述了合金元素及热处理工艺对Ti2Al-Nb基合金组织性能的影响，介绍了Ti2AlNb基合金熔炼凝固特性，并展望Ti2AlNb基合金的未来。     

钛合金激光未穿透焊气孔形成的机理研究

针对钛合金激光焊接的气孔问题进行了研究，对不同工艺参数下钛合金自熔激光焊接试样中的气孔数量及分布进行了金相观察，并进行了酸洗试样的对比试验。研究结果表明：钛合金未穿透激光焊接过程会形成气孔，酸洗对气孔的形成没有明显影响。根据气孔的位置分布及尺寸大小，提出将钛合金激光焊接气孔分为Ⅰ型气孔和Ⅱ型气孔，并阐述了未穿透激光焊接过程中Ⅰ型气孔形成的机理。