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聚甲基丙烯酰亚胺(PMI)泡沫经两步制得:(1)通过本体聚合得到可发性甲基丙烯酸/丙烯腈共聚物板;(2)190℃发泡1h制得PMI泡沫.采用傅里叶变换红外光谱仪(FTIR)、核磁共振氢谱(1H-NMR)、动态机械热分析(DMTA)、差示扫描量热法(DSC)分析了热处理对共聚物结构的影响,并研究了发泡过程中的分子结构转变.结果表明共聚物在发泡过程中分子内生成六元酰亚胺环以及酸酐环:发泡剂分解产生的氨气亦参与反应,并使得酸酐环进一步转变为酰亚胺环;同时分子间生成交联结构;酰亚胺环中N-H键氢的化学位移δ为10.50.SEM照片表明所得泡沫为高闭孔率结构,泡孔结构完整,泡孔尺寸较均一. 相似文献
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C/C minicomposites were manufactured by CVI with propylene as resource gas and Ar as diluent gas. Effects of deposition temperature, the flow rate of propylene and total system pressure on theof C/C minicomposites were investigated. Deposition conditions are as follows: deposition temperature ranging from 870℃ to 1000℃. the flow rate of propylene from 10 to 60 ml/min, and total system pressure from 3 to 16kPa. The results revealed : The deposit distributes non-uniformly as increasing the deposition temperature or total system pressure. The effect of the flow rate of propylene on the distribution of deposit observes different principles at different deposition temperatures. If the deposition temperature rises to 900℃, the deposit distributes more non-uniformly as increasing the flow rate of propylene. The morphology of deposit varies with deposition condition, such as smooth, droplet-like or spike-like. Deposition mechanism varies with deposition condition. It can be surface reaction nucleation and growth, heterogeneous nucleation of liquid droplet on carbon fiber or gas-borne nuclei-growth. With the principle of nuclei-growth of crystal and the method of phenomenology, the changes of deposition mechanism and the morphology of pyrolytic carbon with deposition condition were explained successfully. The effect of deposition condition on deposit homogeneity stems from the effect of deposition condition on the CVI kinetics and the deposition mechanism of pyrolytic carbon. 相似文献
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赵飞明%安思彤%穆晗 《宇航材料工艺》2008,38(1):1-9
综述了聚甲基丙烯酰亚胺(PMI)泡沫的性能、制备和运用.PMI 泡沫耐高温、高比强度、高比模量、具有很宽的高频稳定性、100%闭孔,非常适合于制备泡沫夹心结构.配方技术、分子结构控制技术是 PMI泡沫制备的关键技术.泡沫配方与主原料(甲基丙烯睛和甲基丙烯酸)、引发剂、发泡剂、交联剂、阻燃剂和其他添加剂有关,其种类和用量需要通过试验仔细选择.阐述了反应原理.二步法工艺即低温预聚合和高温发泡,适合于PMI泡沫的制备.预期了未来的发展方向. 相似文献