Lithium micro-battery development at the Jet Propulsion Laboratory

Recent successes in the effort to miniaturize spacecraft components using MEMS technology, integrated passive components, and low power electronics have driven the need for very low power, low profile, low mass micro-power sources for micro/nanospacecraft applications. Recent work at JPL has focused upon developing thin film/micro-batteries compatible with temperature sensitive substrates. A process to prepare crystalline LiCoO₂ films with RF sputtering and moderate (<700°C) annealing temperature has been developed. Thin film batteries with cathode films prepared with this process have specific capacities approaching the practical limit for LiCoO₂, with acceptable rate capabilities and discharge voltage profiles. Solid-state micro-scale batteries have also been fabricated with feature sizes on the order of 50 microns     

FEM code simulation of the magnetospheric proton fluxes

We report a study of the numeric solution to the diffusive transport equation for energetic protons magnetically trapped in the Earth's equatorial magnetosphere. The analysis takes into account the pertinent physical processes in this region, including deceleration of protons by Coulomb collisional interactions with free and bound electrons, the charge exchange process, cosmic ray albedo neutron decay source, and electric and magnetic radial diffusion. These results were obtained using the Finite Element Method with magnetic moment and geomagnetic L-shell as free variables. Steady state boundary conditions were imposed at L=1 as zero distribution function and at L=7 with proton distribution function extracted from ATS 6 satellite observations. The FEM-code yields unidirectional proton flux in the energy range of 0.1–1000 MeV at the equatorial top of the geomagnetic lines, and the results are found to be in satisfactorily agreement with the empirical NASA AP-8 model proton flux within the energy range of 0.5–100 MeV. Below 500 keV, the empirical AP-8 model proton fluxes are several orders of magnitude greater than those computed with the FEM-code at L<3. This discrepancy is difficult to explain by uncertainties of boundary spectrum parameters or transport coefficients.     

The Sun–Earth Connection in Time Scales from Years to Decades and Centuries

The Sun–Earth connection is studied using long-term measurements from the Sun and from the Earth. The auroral activity is shown to correlate to high accuracy with the smoothed sunspot numbers. Similarly, both geomagnetic activity and global surface temperature anomaly can be linked to cyclic changes in the solar activity. The interlinked variations in the solar magnetic activity and in the solar irradiance cause effects that can be observed both in the Earth's biosphere and in the electromagnetic environment. The long-term data sets suggest that the increase in geomagnetic activity and surface temperatures are related (at least partially) to longer-term solar variations, which probably include an increasing trend superposed with a cyclic behavior with a period of about 90 years.     

Statistical Relationships between Solar, Interplanetary, and Geomagnetospheric Disturbances, 1976–2000

Within the framework of the Space Weather program, 25-year data sets for solar X-ray observations, measurements of plasma and magnetic field parameters in the solar wind, and D _st index variations are analyzed to reveal the factors that have had the greatest influence on the development of magnetospheric storms. The correlation between solar flares and magnetic storms practically does not exceed a level of correlation for random processes. In particular, no relation was found between the importance of solar flares and the minimum of the D _st index for storms that could be connected with considered flares by their time delay. The coronal mass ejections (CME; data on these phenomena cover a small part of the interval) result in storms with D _st < –60 nT only in half of the cases. The most geoeffective interplanetary phenomena are the magnetic clouds (MC), which many believe to be interplanetary manifestations of CMEs, and compressions in the region of interaction of slow and fast streams in the solar wind (the so-called Corotating Interaction Region, CIR). They correspond to about two-thirds of all observed magnetic storms. For storms with –100 < D _st < –60 nT, the frequencies of storms from MC and CIR being approximately equal. For strong storms with D _st < – 100 nT, the fraction of storms from MC is considerably higher. The problems of reliable prediction of geomagnetic disturbances from observations of the Sun and conditions in interplanetary space are discussed.     

Abiogenic synthesis of pyrimidine nucleotides in solid state by vacuum ultraviolet radiation.

The abiogenic synthesis of pyrimidine nucleotides in solid state has been investigated. Our experiment indicates that natural nucleotides are produced in thin films prepared from nucleoside and inorganic phosphate by irradiating with vacuum ultraviolet light (VUV, lambda=100-200 nm). We have investigated the influence of the type of nucleic acids base (thymidine, cytosine, uracil) and the structure of sugar moiety (ribose or deoxyribose) on the course and yield of reaction. We compared the action of vacuum ultraviolet light with action of gamma-radiation, heat and biology significant UV (254 nm) which have been investigated earlier. The occurrence of these reaction in open space is discussed.     

Changes in surface UV solar irradiance and ozone over the balkans during the eclipse of August 11, 1999

Intensive measurements of UV solar irradiance, total ozone and surface ozone were carried out during the solar eclipse of 11 August 1999 at Thessaloniki, Greece and Stara Zagora, Bulgaria, located very close to the footprint of the moon's shadow during the solar eclipse with the maximum coverage of the solar disk reaching about 90% and 96% respectively. It is shown that during the eclipse the diffuse component is reduced less compared to the decline of the direct solar irradiance at the shorter wavelengths. A 20-minute oscillation of erythemal UV-B solar irradiance was observed before and after the time of the eclipse maximum under clear skies, indicating a possible 20-minute fluctuation in total ozone presumably caused by the eclipse induced gravity waves. The surface ozone measurements at Thessaloniki display a decrease of around 10–15 ppbv during the solar eclipse. Similarly, ozone profile measurements with a lidar system indicate a decrease of ozone up to 2 km during the solar eclipse. The eclipse offered the opportunity to test our understanding of tropospheric ozone chemistry. The use of a chemical box model suggested that photochemistry can account for a significant portion of the observed surface ozone decrease.     

Particle trajectories in seeds of Lactuca sativa and chromosome aberrations after exposure to cosmic heavy ions on Cosmos Biosatellites 8 and 9.

The potentially specific importance of the heavy ions of the galactic cosmic radiation for radiation protection in manned spaceflight continues to stimulate in situ, i.e., spaceflight experiments to investigate their radiobiological properties. Chromosome aberrations as an expression of a direct assault on the genome are of particular interest in view of cancerogenesis being the primary radiation risk for man in space. In such investigations the establishment of the geometrical correlation between heavy ions' trajectories and the location of radiation sensitive biological substructures is an essential task. The overall qualitative and quantitative precision achieved for the identification of particle trajectories in the order of approximately 10 micrometers as well as the contributing sources of uncertainties are discussed. We describe how this was achieved for seeds of Lactuca sativa as biological test organisms, whose location and orientation had to be derived from contact photographies displaying their outlines and those of the holder plates only. The incidence of chromosome aberrations in cells exposed during the COSMOS 1887 (Biosatellite 8) and the COSMOS 2044 (Biosatellite 9) mission was determined for seeds hit by cosmic heavy ions. In those seeds the incidence of both single and multiple chromosome aberrations was enhanced. The results of the Biosatellite 9 experiment, however, are confounded by spaceflight effects unrelated to the passage of heavy ions.     

Radial profile measurements of the solar wind speed using radio sounding techniques

Velocity measurements of the solar wind in the region of its acceleration were carried out in 1984 with Venera Orbiters using the following specific radio sounding techniques: (i) phase and frequency correlations from two or three widely-spaced ground stations; (ii) phase and frequency correlations from two spacecraft and two widely-spaced ground stations; (iii) two station two-way coherent Doppler measurements; (iv) determination of the break frequency in power spectra of intensity fluctuations. Our results are substantially lower than those derived from direct Doppler shift measurements of transition region and lower coronal resonance lines and those from measurements applying the Doppler dimming technique.     

Formation of bioorganic compounds in simulated planetary atmospheres by high energy particles or photons.

Various types of organic compounds have been detected in Jupiter, Titan, and cometary coma. It is probable that organic compounds were formed in primitive Earth and Mars atmospheres. Cosmic rays and solar UV are believed to be two major energy sources for organic formation in space. We examined energetics of organic formation in simulated planetary atmospheres. Gas mixtures including a C-source (carbon monoxide or methane) and a N-source (nitrogen or ammonia) was irradiated with the followings: High energy protons or electrons from accelerators, gamma-rays from 60Co, UV light from a deuterium lamp, and soft X-rays or UV light from an electron synchrotron. Amino acids were detected in the products of particles, gamma-rays and soft X-rays irradiation from each gas mixture examined. UV light gave, however, no amino acid precursors in the gas mixture of carbon monoxide, nitrogen and nitrogen. It gave only a trace of them in the gas mixture of carbon monoxide, ammonia and water or that of methane, nitrogen and water. Yield of amino acid precursors by photons greatly depended on their wavelength. These results suggest that nitrogen-containing organic compounds like amino acid precursors were formed chiefly with high energy particles, not UV photons, in Titan or primitive Earth/Mars atmospheres where ammonia is not available as a predominant N-source.