Aqueous corrosion of phosphide minerals from iron meteorites: a highly reactive source of prebiotic phosphorus on the surface of the early Earth

We present the results of an experimental study of aqueous corrosion of Fe-phosphide under conditions relevant to the early Earth. The results strongly suggest that iron meteorites were an important source of reactive phosphorus (P), a requirement for the formation of P-based life. We further demonstrate that iron meteorites were an abundant source of phosphide minerals early in Earth history. Phosphide corrosion was studied in five different solutions: deionized water, deionized water buffered with sodium bicarbonate, deionized water with dissolved magnesium and calcium chlorides, deionized water containing ethanol and acetic acid, and deionized water containing the chlorides, ethanol, and acetic acid. Experiments were performed in the presence of both air and pure Ar gas to evaluate the effect of atmospheric chemistry. Phosphide corrosion in deionized water results in a metastable mixture of mixed-valence, P-bearing ions including pyrophosphate and triphosphate, key components for metabolism in modern life. In a pH-buffered solution of NaHCO(3), the condensed and reduced species diphosphonate is an abundant corrosion product. Corrosion in ethanol- and acetic acid-containing solutions yields additional P-bearing organic molecules, including acetyl phosphonate and a cyclic triphosphorus molecule. Phosphonate is a major corrosion product of all experiments and is the only P-bearing molecule that persists in solutions with high concentrations of magnesium and calcium chlorides, which suggests that phosphonate may have been a primitive oceanic source of P. The stability and reactivity of phosphonate and hypophosphite in solution were investigated to elucidate reaction mechanisms and the role of mineral catalysts on P-solution chemistry. Phosphonate oxidation is rapid in the presence of Fe metal but negligible in the presence of magnetite and in the control sample. The rate of hypophosphite oxidation is independent of reaction substrate.     

A search for chiral signatures on Mars

It is thought that the chiral molecules of living material can induce circular polarization in light at levels much higher than expected from abiotic processes. We therefore obtained high quality imaging circular polarimetry of the martian surface during the favorable opposition of 2003 to seek evidence of anomalous optical activity. We used two narrow-band filters covering 43% of the martian surface, 15% of it in-depth. With polarization noise levels <0.1% (4.3 upper limits 0.2-0.3%) and spatial resolution 210 km, we did not find any regions of circular polarization. When data were averaged over the observed face of the planet, we did see a small non-zero circular polarization 0.02%, which may be due to effects associated with the opposition configuration though it is at the limit of the instrumental capability. Our observations covered only a small fraction of parameter space, so although we obtained a null result, we cannot exclude the presence of optical activity at other wavelengths, in other locations, or at higher spatial resolution.     

Geocorona of Hot Plasma

This review deals with basic results of experimental and theoretical studies (numerical simulations included) of the distributions, composition, and dynamics of particles of a hot plasma in the geomagnetosphere. Attention is drawn mainly to the ring current and the plasma sheet of the magnetotail, which play a key role in physics of the magnetosphere. The integrity (unity) of the system outer radiation belt–ring current–near plasma sheet is substantiated (the concept of a hot plasma geocorona). From the viewpoint of this concept, the physical processes and theories are considered that were suggested in order to explain the structure and dynamics of the hot magnetosphere plasma. An emphasis is made on disputable issues and topical problems so far unsolved.     

Convective Motions in Near-Critical Fluids under Real Zero-Gravity Conditions

The results of processing and interpreting the data of joint Russian–French experiments for studying the heat and mass transfer in near-critical fluids are presented. The experiments were carried out with the ALICE-1 instrument during an orbital flight of the Mirstation from September 30 to October 2, 1995 [1]. For such fluids with a point-like source of heat, when they are placed in the field of uncontrolled inertial accelerations of the spacecraft, the influence of thermovibrational and thermogravitational mechanisms of convection on the propagation of the region of optical irregularity is investigated. It is shown that, near the thermodynamic critical point, local heating of the medium leads to generation of either intense thermogravitational convection or averaged vibroconvective flow, depending on the frequency of variations of the microaccelerations. The structure and characteristics of discovered motions are studied. The results of numerical simulations are presented that confirm the conclusion about a possibility of generation of an averaged convective flow of a vibrational type by the high-frequency component of microaccelerations.     

Effect of volatile metabolites of dill, radish and garlic on growth of bacteria

In a model experiment plants were grown in sealed chambers on expanded clay aggregate under the luminance of 150 W/m2 PAR and the temperature of 24 degrees C. Seven bacterial strains under investigation, replicated on nutrient medium surface in Petri dishes, were grown in the atmosphere of cultivated plants. Microbial response was evaluated by the difference between colony size in experiment and in control. In control, bacteria grew in the atmosphere of clean air. To study the effects of volatile metabolites of various plant on microbial growth, the experimental data were compared with the background values defined for each individual experiment. Expanded clay aggregate, luminance, temperature, and sealed chamber (without plants) for the background were the same. Volatile metabolites from 28-days old radish plants have been reliably established to have no effect on the growth of microbes under investigation. Metabolites of 30-days old dill and 50-days old garlic have been established to have reliable bacteriostatic effect on the growth of three bacterial strains. Dill and garlic have been found to have different range of effects of volatile substances on bacterial growth. Volatile metabolites of dill and garlic differed in their effect on the sensitivity spectrum of bacteria. An attempt has been made to describe the obtained data mathematically.     

Martian polar expeditions: problems and solutions.

The Martian polar ice caps are regions of substantial scientific interest, being the most dynamic regions of Mars. They are volatile sinks and thus closely linked to Martian climatic conditions. Because of their scale and the precedent set by the past history of polar exploration on Earth, it is likely that an age of polar exploration will emerge on the surface of Mars after the establishment of a capable support structure at lower latitudes. Expeditions might be launched either from a lower latitude base camp or from a human-tended polar base. Based on previously presented expeditionary routes to the Martian poles, in this paper a "spiral in-spiral out" unsupported transpolar assault on the Martian north geographical pole is used as a Reference expedition to propose new types of equipment for the human polar exploration of Mars. Martian polar "ball" tents and "hover" modifications to the Nansen sledge for sledging on CO2-containing water ice substrates under low atmospheric pressures are suggested as elements for the success of these endeavours.Other challenges faced by these expeditions are quantitatively and qualitatively addressed.     

Making space for history

This report summarizes the presentations given at the third annual British Rocketry Oral-History Project, held in Surrey, UK in April 2001. A wide range of papers was given (to an equally diverse audience), covering past and present developments in air and space, both military and civilian. Many of the scientists and engineers who had worked on specific projects were present and their personal reminiscences enlivened proceedings. The importance of history in understanding not only the past but also the future of space efforts was emphasized.     

Mineralogical biosignatures and the search for life on Mars

If life ever existed, or still exists, on Mars, its record is likely to be found in minerals formed by, or in association with, microorganisms. An important concept regarding interpretation of the mineralogical record for evidence of life is that, broadly defined, life perturbs disequilibria that arise due to kinetic barriers and can impart unexpected structure to an abiotic system. Many features of minerals and mineral assemblages may serve as biosignatures even if life does not have a familiar terrestrial chemical basis. Biological impacts on minerals and mineral assemblages may be direct or indirect. Crystalline or amorphous biominerals, an important category of mineralogical biosignatures, precipitate under direct cellular control as part of the life cycle of the organism (shells, tests, phytoliths) or indirectly when cell surface layers provide sites for heterogeneous nucleation. Biominerals also form indirectly as by-products of metabolism due to changing mineral solubility. Mineralogical biosignatures include distinctive mineral surface structures or chemistry that arise when dissolution and/or crystal growth kinetics are influenced by metabolic by-products. Mineral assemblages themselves may be diagnostic of the prior activity of organisms where barriers to precipitation or dissolution of specific phases have been overcome. Critical to resolving the question of whether life exists, or existed, on Mars is knowing how to distinguish biologically induced structure and organization patterns from inorganic phenomena and inorganic self-organization. This task assumes special significance when it is acknowledged that the majority of, and perhaps the only, material to be returned from Mars will be mineralogical.     

Gravitational Interaction of Celestial Bodies and neutron flux bursts from Their Surfaces

The gravitational interaction between the Sun and the planetary solar system gives rise to the well-known tidal waves at the planets. The tidal wave originating in the Earth's crust perpetually transforms the microstructure of the Earth's crust leading to a variation of the concentration of natural radioactive gases in the terrestrial air and to changed conditions of their leakage to the Earth's atmosphere. These variations give rise to bursts of thermal and slow neutrons in the vicinity of the Earth's crust, because the radioactive gases are sources of energetic alpha particles that induce neutron production upon the interaction with the nuclei of elements of the Earth's crust and atmosphere. In this work, the idea of neutron production in the ground coat is extended to the other celestial bodies interacting with one another.