TD-1HNMR measurements show enantioselective dissociation of ribose and glucose in the presence of H2(17)O

We used Time Domain (1)H Nuclear Magnetic Resonance (NMR) to characterize changes in proton exchange between water and sugar enantiomers at different concentrations of H(2)(17)O (approximately 15-450 mM) and found that dissociation of the (-)-enantiomers of glucose and ribose occurs at significantly higher rates at higher concentrations of H(2)(17)O. The mechanism behind this enantioselective effect is unclear. The hypothesis we propose is that the large magnetic field (B(o) approximately 0.6T) applied during NMR measurements induces electric moments opposite in sign for the D and L-isomers. Because (17)O has a nuclear electric quadrupole moment not = 0, asymmetrically hydrated complexes may form between the B(o)-polarized enantiomers and H(2)(17)O. Either H(2)(17)O is more often hydrating the (+) than the (-)-enantiomers--and consequently pK differences between H(2)(16)O and H(2)(17)O lead to differences in proton exchange between enantiomers and water--or the orientation of H(2)(17)O relative to the B(o)-polarized enantiomers is different, in total or in part, which leads to hydrated complexes with different spatial geometries and different proton exchange properties. This effect is significant for Magneto-Chiral Stereo-Chemistry (MCSC) and astrobiology, and it may help us better understand specific instances of mass independent isotopic fractionation and aid in the development of new technologies for chiral and isotopic separation.     

用于YF—23A原型机飞行试验的分布式实时数据处理

１９９０年下半年，为了验证和鉴定为ＹＦ－２３Ａ原型机飞行试验而开发的几项新技术，诺思罗普／麦．道公司的两架ＹＦ－２３Ａ先进战术战斗机（ＡＴＦ）原型机投放试飞，ＹＦ－２３Ａ飞行试验队为该试验计划研制了一种性能卓越的，费用低廉的实时地面数据站。为了满意ＡＴＦ原型机飞行试验工作的需要，该地面站主要基于分布式数据处理的概念。尽管ＹＦ－２３Ａ地面数据站的核心是ＤＳＩ公司的ＱＵＡＤ－７计算机系统，但安装在各种     

跟踪与数据中继卫星系统的性能

一、引言 自60年代初,NASA就组建和操作一个为近地轨道卫星服务的跟踪和数据获取网。TDRSS是一个新测控网,为目前和直到2000年的预期卫星任务服务。该网利用了已经验证的空间和地面系统有关技术构成一个全新的测控站,只是其前端设备置于地球同步轨道上。尽量采用了自动化技术,使系统设置到数据采集以及整个跟踪期间的通信几乎都不需要人操作。     

陆军机动防空的发展趋势

地面部队的低空防空可分为保护固定发射场和机动设施两种.后者或者安装在机动车辆上限随机动部队进行,或者被牵引着用于保护构筑工事的部队.     

GENERATION AND APPLICATION OF UNSTRUCTURED ADAPTIVE MESHES WITH MOVING BOUNDARIES

INTRODUCTIONMany engineering applications require thenumerical prediction of strongly unsteady flowsinteracting with moving bodies.A case in pointis that the detailed calculation of sphere motionsin an unsteady field induced by blast waves is akey issue to determine the drag force exerting up-on the sphere by the surrounding gas and,inturn,to reveal the mechanism of unsteady effectson the drag coefficient.To cope with such pro-blems,one should simulate unsteady flows withmoving boundary co…     

Psychological considerations of man in space: problems & solutions

With concrete plans for long duration flight taking form a new impetus is lent to preparing man for this hostile and unnatural environment. Cramped conditions, isolation from family and loved ones, work stress, fear, and incompatibility with fellow crew, are but a few of the problems suffered by astronauts and cosmonauts during their long missions in orbit about the earth.

Although criteria for selection of crew is one aspect of attacking the problem, it has not solved it Notwithstanding good selection, team combination, and counselling before flight, problems have still occurred with unwanted consequences. Incompatibility of team members, far from being the exception, has been frequent. This has been detrímental both physiologically and psychologically for the individual as well as for the operational success and safety of the missions.

Because problems will inevitably occur in future long duration missions, especially when they are of international and multi-cultural nature, the importance of dealing with them is underlined. This paper takes a different approach towards ameliorating these problems, namely that of psychological group training before a mission.     

Effects of microgravity on the binding of acetylsalicylic acid by Rhizobium leguminosarum bv. trifolii

Bacteroids can be induced in vitro by treating growing Rhizobium leguminosarum bv. trifolii with succinic acid or succinic acid structural analogs like acetysalicylic acid. Quantitating bacteroid induction by measuring acetylsalicylic binding under normal (1 g) conditions showed two forms of binding to occur. In one form of binding cells immediately bound comparatively high levels of acetylsalicylic acid, but the binding was quickly reversed. The second form of binding increased with time by first order kinetics and reached saturation in 40 s. Similar experiments performed in the microgravity environment aboard the NASA 930 aircraft showed only one form of binding and total acetylsalicyclic acid bound was 32% higher than at 1 g.     

预测固体推进剂火箭发动机侵蚀燃烧的数值法

对于固体推进剂火箭燃烧可采用一维模型预测固体推进剂火箭发动机的侵蚀燃烧特性。用取决于不同燃烧速率的速度来表示固体推进剂的侵蚀燃烧。数值积分控制偏微分方程就可得到分析结果。使用非定常公式预测固体推进剂侵蚀燃烧特性。计算了各种不同药形的复合推进剂和双基推进剂的侵蚀燃烧特性。测出了各种不同药形装填密度(药柱初始通孔面积与喉面积之比)对压力时间曲线的影响。现有分析指出,装填密度是确定某一特定药形及化学成分的推进剂侵蚀燃烧特性的最重要参数之一。研究表明低燃速推进剂比高燃速推进剂反映出具有较大的侵蚀燃烧效应。同时也表明长方药形与圆柱药形相比具有较大的初始压力峰,相反压力很快就稳定到一般与装填密度无关的平衡压力。     

Lick Observatory Optical SETI: targeted search and new directions

Lick Observatory's Optical SETI (search for extraterrestrial intelligence) program has been in regular operation for 4.5 years. We have observed 4,605 stars of spectral types F-M within 200 light-years of Earth. Occasionally, we have appended objects of special interest, such as stars with known planetary systems. We have observed 14 candidate signals ("triple coincidences"), all but one of which are explained by transient local difficulties. Additional observations of the remaining candidate have failed to confirm arriving pulse events. We now plan to proceed in a more economical manner by operating in an unattended drift scan mode. Between operational and equipment modifications, efficiency will more than double.     

A search for narrow band signals with SERENDIP II: a progress report

Commensal programs for the Search for Extraterrestrial Intelligence (SETI), carried out concurrently with conventional radio astronomical observing programs, can be an attractive and cost-effective means of exploring the large multidimensional search space intrinsic to this effort. Our automated commensal system, SERENDIP II, is a high resolution 131,072 channel spectrometer. It searches for 0.49 Hz signals in sequential 64,700 Hz bands of the IF signal from a radio telescope being used for an astronomical observation. Upon detection of a narrow band signal with power above a preset threshold, the frequency, power, time, and telescope direction are recorded for later study. The system has been tested at the Hat Creek Radio Astronomy Observatory 85 ft telescope and the NASA-JPL Deep Space Station (DSS 14) 64 m telescope. It is currently collecting data at the National Radio Astronomy Observatory 300 ft telescope.