A study of chemical systems using signal flow graph theory.

Photochemistry of giant planets and their satellites is characterized by numerous reactions involving a lot of chemical species. In the present paper, chemical systems are modeled by signal flow graphs. Such a technique evaluates the transmission of any input into the system (solar flux, electrons ... ) and gives access to the identification of the most important mechanisms in the chemical system. This method is applied to the production of hydrocarbons in the atmospheres of giant planets. In particular, the production of C2H6 in the atmosphere of Neptune from the photodissociation of CH4 is investigated. Different pathways of dissociation of CH4 are possible from L alpha radiation. A chemical system containing 14 species and 30 reactions including these different pathways of dissociation is integrated. The main mechanism of production of C2H6 is identified and evaluated for each model of dissociation. The importance of various reaction pathways as a function of time is presented.     

Statistical study of inverted-V events: A comparison between experiment and theory

We present a detailed study of the distribution and of the internal structure of the inverted-V electron precipitation commonly detected in the 500 – 2000 km altitude range aboard the AUREOL-3 satellite. These structured precipitations are statistically observed inside the auroral oval with a maximum occurence in the nightside sector. They correspond to primary electron fluxes peaked at energies generally below 10 keV. It is shown that, as predicted by kinetic theories, most inverted-V structures present a clear relationship between the field-aligned current density carried by the 1 – 20 keV primary electrons and the potential drop inferred from particle distribution functions. Furthermore the study demonstrates the existence of strong electron heating, related to the energy gain, when the current density exceeds some threshold of about 1 – 5 μA(m)^?2.     

Selection of sterilization methods for planetary return missions.

Two tasks must be accomplished to provide planetary protection for Mars return missions: (1) sterilization of the scientific module to be landed on Mars and (2) reliable sterilization of all material returned to Earth, while ensuring the scientific integrity of martian samples. This paper examines similarity and differences between these two tasks, and includes a discussion of technological implementation conditions and the nature of terrestrial and hypothesized martian microflora. The feasibility of a number of chemical and physical (ultraviolet and ionizing radiation and heating) methods of sterilization for use on the ground and onboard are discussed and compared. A combination of different methods will probably be selected as the most appropriate for ensuring planetary protection on the return mission.     

Photometric calibration and first results obtained with the UFT experiment on board the astron satellite

The UV telescope of 30 cm diameter equipped with a three channel scanner spectrometer aboard the highly eccentric orbit space station “ASTRON” is describedAbsolute calibration of the whole device is performed using spectra of standard stars, of which absolute values were obtained by TDI or IUE experiments. Several photometric controls have been made on the stability of the equipment after one year of operation which demonstrate reliability of some first results obtained by the UFT.The sensitivity curve of the spectrophotometric system has been observed with a reproducibility of 2σ = 10% or better.The repeated observation of one star (139 Tau) indicates that the overall performance exhibits the same quality after one year in orbit. The low resolution mode ($\text{Δ λ = 28}\text{A}\text{?}$) leads to a powerful new investigation of faint extended sources.     

Measurements of trace contaminants in closed-type plant cultivation chambers.

Trace contaminants generated in closed facilities can cause abnormal plant growth. We present measurement data of trace contaminants released from soils, plants, and construction materials. We mainly used two closed chambers, a Closed-type Plant and Mushroom Cultivation Chamber (PMCC) and Closed-type Plant Cultivation Equipment (CPCE). Although trace gas budgets from soils obtained in this experiment are only one example, the results indicate that the budgets of trace gases, as well as CO2 and O2, change greatly with the degree of soil maturation and are dependent on the kind of substances in the soil. Both in the PMCC and in the CPCE, trace gases such as dioctyl phthalate (DOP), dibutyl phthalate (DBP), toluene and xylene were detected. These gases seemed to be released from various materials used in the construction of these chambers. The degree of increase in these trace gas levels was dependent on the relationship between chamber capacity and plant quantity. Results of trace gas measurement in the PMCC, in which lettuce and shiitake mushroom were cultivated, showed that ethylene was released both from lettuce and from the mushroom culture bed. The release rates were about 90 ng bed-1 h-1 for the shiitake mushroom culture bed (volume is 1700 cm3) and 4.1 approximately 17.3 ng dm-2 h-1 (leaf area basis) for lettuce. Higher ethylene release rates per plant and per unit leaf area were observed in mature plants than in young plants.     

Hemispheric differences in the earth radiation budget derived from Nimbus-7 related to climate studies

Earth Radiation Budget (ERB) data from Nimbus-7 over the period November 1978 – June 1980 has consistently shown strong hemispheric differences when analyzed over different temporal and spatial scales. Hemispheric variations in time latitude cross sections of net and emitted radiation were found to be caused by changes in the Earth-Sun distance and continental effects.Maps of annual range for the entire Earth calculated from monthly averages showed areas of high and low variability of the different ERB parameters. The ERB of these regional areas were examined and most of the variability was found to lay in the large amplitude of the annual solar cycle. Variations in the global annual cycle of albedo /1/ are studied with respect to differences in latitudinal averaged albedo. The anomaly in the annual cycle of global averaged albedo was found to be caused by tropical albedo changes.     

The cometary contribution to prebiotic chemistry.

Different estimates based on dynamical considerations, lunar cratering rates, Solar System chemical abundances, and the single-impact theory on the origin of the Earth-Moon system suggest that comets and other related small, volatile-rich primitive minor bodies captured by the Earth during the early Archean must have been a major source of volatiles on our planet. It is likely that a substantial fraction of the organic molecules present in the colliding cometary nuclei, which may have included nitrogen bases and the precursors of amino acids, were destroyed due to the high temperatures and shock wave energy associated with the collision. However, the presence of H2O, CN, CH, CO, CO2 and other carbon-bearing molecules and radicals in the atmosphere of the Sun and in circumstellar shells around carbon-rich stars suggests that at least simple carbon species could have survived the cometary collisions. Under the anoxic conditions thought to prevail in the prebiotic terrestrial paleoatmosphere, the post-collisional formation of a large number of excited molecules and radicals, and the rapid quenching of the expanding gaseous ball may have led, upon rapid cooling, to the formation of molecules of biogenic elements and to their eventual deposition in localized environments where complex organic compounds of biochemical significance may have been produced and accumulated.     

Spacecraft on-orbit deployment anomalies: What can be done?

On-orbit anomalies related to the deployment of spacecraft appendage and possible causes of such failures are considered. The discussion covers mechanical launch loading, on-orbit thermal and solar concerns, reliability of spacecraft pyrotechnics, and practical limitations of ground-based deployment testing. Lessons learned from the successful recovery of the Telesat Canada Anik-E2 satellite in 1991 are examined