Biomarker response to galactic cosmic ray-induced NOx and the methane greenhouse effect in the atmosphere of an Earth-like planet orbiting an M dwarf star

Planets orbiting in the habitable zone of M dwarf stars are subject to high levels of galactic cosmic rays (GCRs), which produce nitrogen oxides (NOx) in Earth-like atmospheres. We investigate to what extent these NO(Mx) species may modify biomarker compounds such as ozone (O3) and nitrous oxide (N2O), as well as related compounds such as water (H2O) (essential for life) and methane (CH4) (which has both abiotic and biotic sources). Our model results suggest that such signals are robust, changing in the M star world atmospheric column due to GCR NOx effects by up to 20% compared to an M star run without GCR effects, and can therefore survive at least the effects of GCRs. We have not, however, investigated stellar cosmic rays here. CH4 levels are about 10 times higher on M star worlds than on Earth because of a lowering in hydroxyl (OH) in response to changes in the ultraviolet. The higher levels of CH4 are less than reported in previous studies. This difference arose partly because we used different biogenic input. For example, we employed 23% lower CH4 fluxes compared to those studies. Unlike on Earth, relatively modest changes in these fluxes can lead to larger changes in the concentrations of biomarker and related species on the M star world. We calculate a CH4 greenhouse heating effect of up to 4K. O3 photochemistry in terms of the smog mechanism and the catalytic loss cycles on the M star world differs considerably compared with that of Earth.     

Urey: Mars Organic and Oxidant Detector

One of the fundamental challenges facing the scientific community as we enter this new century of Mars research is to understand, in a rigorous manner, the biotic potential both past and present of this outermost terrestrial-like planet in our solar system. Urey: Mars Organic and Oxidant Detector has been selected for the Pasteur payload of the European Space Agency’s (ESA’s) ExoMars rover mission and is considered a fundamental instrument to achieve the mission’s scientific objectives. The instrument is named Urey in recognition of Harold Clayton Urey’s seminal contributions to cosmochemistry, geochemistry, and the study of the origin of life. The overall goal of Urey is to search for organic compounds directly in the regolith of Mars and to assess their origin. Urey will perform a groundbreaking investigation of the Martian environment that will involve searching for organic compounds indicative of life and prebiotic chemistry at a sensitivity many orders of magnitude greater than Viking or other in situ organic detection systems. Urey will perform the first in situ search for key classes of organic molecules using state-of-the-art analytical methods that provide part-per-trillion sensitivity. It will ascertain whether any of these molecules are abiotic or biotic in origin and will evaluate the survival potential of organic compounds in the environment using state-of-the-art chemoresistor oxidant sensors.     

Phobos regolith simulants PGI-1 and PCA-1

The Martian moon Phobos is the target of the upcoming JAXA Martian Moons eXploration (MMX) mission. There are currently no known samples of Phobos, so spacecraft hardware testing and scientific studies require Phobos regolith simulants. Here, we present two new Phobos regolith simulants: Phobos Captured Asteroid-1 (PCA-1) and Phobos Giant Impact (PGI-1). These two simulants reflect the two hypotheses for Phobos’s formation, and thus the two broad possibilities for composition. This work follows previous efforts to document the development of mineralogically accurate simulants, in an effort to overcome past pitfalls with inappropriate uses of simulants. We report physical and geotechnical properties of PCA-1 and PGI-1, including their reflectance spectra, grain size distributions, abrasivity, cohesion, strength, and hardness. Our intent is for PCA-1 and PGI-1 to be open standards for Phobos simulants, and we present the simulant recipes and production methodology for use and modification by the community.     

Experimental Investigation to Evaluate LiFePO4 Batteries Anode and Cathode Elastic Properties under Cyclic Temperature Loading Conditions

Experimental investigations and associated methods are provided to characterize the mechanical properties of a lithium-ion battery accounting for operating temperature variation and thermal effects. Material properties for LiFeP04 cathode and anode samples taken from an off-the-shelf battery are evaluated in new and fatigued （subjec- ted to charging and discharging cycles） conditions.     

Did evolution select a nonrandom "alphabet" of amino acids?

The last universal common ancestor of contemporary biology (LUCA) used a precise set of 20 amino acids as a standard alphabet with which to build genetically encoded protein polymers. Considerable evidence indicates that some of these amino acids were present through nonbiological syntheses prior to the origin of life, while the rest evolved as inventions of early metabolism. However, the same evidence indicates that many alternatives were also available, which highlights the question: what factors led biological evolution on our planet to define its standard alphabet? One possibility is that natural selection favored a set of amino acids that exhibits clear, nonrandom properties-a set of especially useful building blocks. However, previous analysis that tested whether the standard alphabet comprises amino acids with unusually high variance in size, charge, and hydrophobicity (properties that govern what protein structures and functions can be constructed) failed to clearly distinguish evolution's choice from a sample of randomly chosen alternatives. Here, we demonstrate unambiguous support for a refined hypothesis: that an optimal set of amino acids would spread evenly across a broad range of values for each fundamental property. Specifically, we show that the standard set of 20 amino acids represents the possible spectra of size, charge, and hydrophobicity more broadly and more evenly than can be explained by chance alone.     

Thin Film Lithium-Ionbatteries Crack Initiation Due to Thermal and Electric Effects

The transient and thermo-electric finite element analysis （FEA） of a 2D lithium-on （Li-ion） battery is presented. The process of recharging and discharging of thin film lithium-ion （LiFePO4） battery in the presence of a transversal crack is numerically investigated. During this process significant temperature load influences the be- havior of the battery and thermal fields can affect the way crack propagates into the thin film media. The simula- tions infer about relationship between temperature and electric field and their effect on crack propagation. A Li-ion battery model suitable for this investigation is implemented in the multi-physics software package by COMSOL Inc. , and it is extended to include the thermal and electrical effects. Results and discussion are accompanied with pertinent conclusions.     

Design Considerations for Differential Low-Level Junction FET Commutators

The many advantages of junction field-effect transistors (FET) in commutation applications have prompted a serious effort to extend the technology without sacrificing performance and, in many areas, to realize an improvement over low-level commutator performance attainable by more conventional electronic means (especially Bright switches), so that these devices may be employed in general application, high-accuracy, low-level commutation. This paper is devoted to a generalization of knowledge recently gained during the development of such equipment, which will aid potential designers and users in their understanding and application of low-level FET commutators. A discussion of device characteristics is offered as the starting point of design. A number of topics are then discussed, including offset drift and scatter, gain drift and scatter, source and amplifier loading, crosstalk, and common-mode rejection. Also, several useful design guidelines, in the form of generalized expressions, are derived or furnished for the reader's use. Finally, in order to lend veracity to the design techniques suggested, the performance data of a low-level FET commutator developed following these techniques are offered for consideration.     

Integrated micro-electro-mechanical sensor development for inertialapplications

Electronic sensing circuitry and micro-electro-mechanical sense elements can be integrated to produce inertial instruments for applications unheard of a few years ago. This paper describes the Sandia M³EMS fabrication process, inertial instruments that have been fabricated, and the results of initial characterization tests of micro-machined accelerometers     

Cosima – High Resolution Time-of-Flight Secondary Ion Mass Spectrometer for the Analysis of Cometary Dust Particles onboard Rosetta

The ESA mission Rosetta, launched on March 2nd, 2004, carries an instrument suite to the comet 67P/Churyumov-Gerasimenko. The COmetary Secondary Ion Mass Anaylzer – COSIMA – is one of three cometary dust analyzing instruments onboard Rosetta. COSIMA is based on the analytic measurement method of secondary ion mass spectrometry (SIMS). The experiment’s goal is in-situ analysis of the elemental composition (and isotopic composition of key elements) of cometary grains. The chemical characterization will include the main organic components, present homologous and functional groups, as well as the mineralogical and petrographical classification of the inorganic phases. All this analysis is closely related to the chemistry and history of the early solar system. COSIMA covers a mass range from 1 to 3500 amu with a mass resolution m/Δm @ 50% of 2000 at mass 100 amu. Cometary dust is collected on special, metal covered, targets, which are handled by a target manipulation unit. Once exposed to the cometary dust environment, the collected dust grains are located on the target by a microscopic camera. A pulsed primary indium ion beam (among other entities) releases secondary ions from the dust grains. These ions, either positive or negative, are selected and accelerated by electrical fields and travel a well-defined distance through a drift tube and an ion reflector. A microsphere plate with dedicated amplifier is used to detect the ions. The arrival times of the ions are digitized, and the mass spectra of the secondary ions are calculated from these time-of-flight spectra. Through the instrument commissioning, COSIMA took the very first SIMS spectra of the targets in space. COSIMA will be the first instrument applying the SIMS technique in-situ to cometary grain analysis as Rosetta approaches the comet 67P/Churyumov-Gerasimenko, after a long journey of 10 years, in 2014.