Processes that Promote and Deplete the Exosphere of Mercury

It has been speculated that the composition of the exosphere is related to the composition of Mercury’s crustal materials. If this relationship is true, then inferences regarding the bulk chemistry of the planet might be made from a thorough exospheric study. The most vexing of all unsolved problems is the uncertainty in the source of each component. Historically, it has been believed that H and He come primarily from the solar wind (Goldstein, B.E., et al. in J. Geophys. Res. 86:5485–5499, 1981), Na and K come from volatilized materials partitioned between Mercury’s crust and meteoritic impactors (Hunten, D.M., et al. in Mercury, pp. 562–612, 1988; Morgan, T.H., et al. in Icarus 74:156–170, 1988; Killen, R.M., et al. in Icarus 171:1–19, 2004b). The processes that eject atoms and molecules into the exosphere of Mercury are generally considered to be thermal vaporization, photon-stimulated desorption (PSD), impact vaporization, and ion sputtering. Each of these processes has its own temporal and spatial dependence. The exosphere is strongly influenced by Mercury’s highly elliptical orbit and rapid orbital speed. As a consequence the surface undergoes large fluctuations in temperature and experiences differences of insolation with longitude. Because there is no inclination of the orbital axis, there are regions at extreme northern and southern latitudes that are never exposed to direct sunlight. These cold regions may serve as traps for exospheric constituents or for material that is brought in by exogenic sources such as comets, interplanetary dust, or solar wind, etc. The source rates are dependent not only on temperature and composition of the surface, but also on such factors as porosity, mineralogy, and space weathering. They are not independent of each other. For instance, ion impact may create crystal defects which enhance diffusion of atoms through the grain, and in turn enhance the efficiency of PSD. The impact flux and the size distribution of impactors affects regolith turnover rates (gardening) and the depth dependence of vaporization rates. Gardening serves both as a sink for material and as a source for fresh material. This is extremely important in bounding the rates of the other processes. Space weathering effects, such as the creation of needle-like structures in the regolith, will limit the ejection of atoms by such processes as PSD and ion-sputtering. Therefore, the use of laboratory rates in estimates of exospheric source rates can be helpful but also are often inaccurate if not modified appropriately. Porosity effects may reduce yields by a factor of three (Cassidy, T.A., and Johnson, R.E. in Icarus 176:499–507, 2005). The loss of all atomic species from Mercury’s exosphere other than H and He must be by non-thermal escape. The relative rates of photo-ionization, loss of photo-ions to the solar wind, entrainment of ions in the magnetosphere and direct impact of photo-ions to the surface are an area of active research. These source and loss processes will be discussed in this chapter.     

Comet Halley's Gas Composition and Extended Sources: Results from the Neutral Mass Spectrometer on Giotto

The Neutral Mass Spectrometer on the Giotto spacecraft established that H₂O is the dominant species in Comet Halley's volatiles and determined the abundance of more than 10 parent species. The instrument discovered strong extended H₂CO and CO sources in the coma of Comet Halley. Polymerized H₂CO associated with the cometary dust and evaporating slowly as the monomer is most likely the extended H₂CO source. Photodissociation of the H₂CO into CO fully accounts for the extended CO source. This revised version was published online in June 2006 with corrections to the Cover Date.     

Recent experiments in laser supported absorption waves

Recent experimental studies with laser supported absorption waves, arising from intense laser radiation incident upon various surface materials, are discussed. The propagation characteristics of both subsonic (laser supported combustion), intensity about 10⁵ W/cm², and supersonic (laser supported detonation), intensity greater than 10⁶ W/cm², waves are described, including the dependence of wave speed on laser intensity, beam diameter, gas density and laser wave length. Measurements of the plasma properties in such waves are described, and the analysis of these data allows conclusions identifying the dominant transport mechanism in such waves. It is also concluded that in the LSC (subsonic) case, radial flow ahead of and within the wave are dominant features of the wave structure. The equipment and laser facilities used in the experiments are also discussed.     

Quantification of spatial structure of human proximal tibial bone biopsies using 3D measures of complexity

Changes in trabecular bone composition during development of osteoporosis are used as a model for bone loss in microgravity conditions during a space flight. Symbolic dynamics and measures of complexity are proposed and applied to assess quantitatively the structural composition of bone tissue from 3D data sets of human tibia bone biopsies acquired by a micro-CT scanner. In order to justify the newly proposed approach, the measures of complexity of the bone architecture were compared with the results of traditional 2D bone histomorphometry. The proposed technique is able to quantify the structural loss of the bone tissue and may help to diagnose and to monitor changes in bone structure of patients on Earth as well as of the space-flying personnel.     

Biological implications of the Viking mission to Mars

A central purpose of Viking was to search for evidence that life exists on Mars or may have existed in the past. The missions carried three biology experiments the prime purpose of which was to seek for existing microbial life. In addition the results of a number of the other experiments have biological implications: (1) The elemental analyses of the atmosphere and the regolith showed or implied that the elements generally considered essential to terrestrial biology are present. (2) But unexpectedly, no organic compounds were detected in Martian samples by an instrument that easily detected organic materials in the most barren of terrestrial soils. (3) Liquid water is believed to be an absolute requisite for life. Viking obtained direct evidence for the presence of water vapor and water ice, and it obtained strong inferential evidence for the existence of large amounts of subsurface permafrost now and in the Martain past. However it obtained no evidence for the current existence of liquid water possessing the high chemical potential required for at least terrestrial life, a result that is consistent with the known pressure-temperature relations on the planet's surface. On the other hand, the mission did obtain strong indications from both atmospheric analyses and orbital photographs that large quantities of liquid water flowed episodically on the Martian surface 0.5 to 2.5 G years ago.The three biology experiments produced clear evidence of chemical reactivity in soil samples, but it is becoming increasingly clear that the chemical reactions were nonbiological in origin. The unexpected release of oxygen by soil moistened with water vapor in the Gas Exchange experiment together with the negative findings of the organic analysis experiment lead to the conclusion that the surface contains powerful oxidants. This conclusion is consistent with models of the atmosphere. The oxidants appear also to have been responsible for the decarboxylation of the organic nutrients that were introduced in the Label Release experiment. The major results of the GEX and LR experiments have been simulated at least qualitatively on Earth. The third, Pyrolytic Release, experiment obtained evidence for organic synthesis by soil samples. Although the mechanism of the synthesis is obscure, the thermal stability of the reaction makes a biological explanation most unlikely. Furthermore, the response of soil samples in all three experiments to the addition of water is not consistent with a biological interpretation.The conditions now known to exist at and below the Martian surface are such that no known terrestrial organism could grow and function. Although the evidence does not absolutely rule out the existence of favourable oases, it renders their existence extremely unlikely. The limiting conditions for the functioning of terrestrial organisms are not the limits for conceivable life elsewhere, and accordingly one cannot exclude the possibility that indigenous life forms may currently exist somewhere on Mars or may have existed sometime in the past. Nevertheless, the available information about the present Martian environment puts severe constraints and presents formidable challenges to any putative Martian organisms. The Martian environment in the past, on the other hand, appears to have been considerably less hostile biologically, and it might possibly have permitted the origin and transient establishment of a biota.     

An X-ray survey of flat spectrum radio sources

Flat spectrum radio sources from the MPIfR north pole radio survey at 5 GHz (Kühret al. 1981) were observed with the Einstein X-ray observatory, at optical, mm, and radio wavelengths. The sources show rather extreme properties in all wavelength regions. Here we review the results for the first six sources from the survey (Kühret al. 1981, Biermannet al. 1981a, b, c, Biermann and Schlickeiser 1981, Frickeet al. 1981, Eckartet al. 1981).     

The mass and speed dependence of meteor air plasma temperatures

The speed and mass dependence of meteor air plasma temperatures is perhaps the most important data needed to understand how small meteoroids chemically change the ambient atmosphere in their path and enrich the ablated meteoric organic matter with oxygen. Such chemistry can play an important role in creating prebiotic compounds. The excitation conditions in various air plasma emissions were measured from high-resolution optical spectra of Leonid storm meteors during NASA's Leonid Multi-Instrument Aircraft Campaign. This was the first time a sufficient number and range of temperature measurements were obtained to search for meteoroid mass and speed dependencies. We found slight increases in temperature with decreasing altitude, but otherwise nearly constant values for meteoroids with speeds between 35 and 72 km/s and masses between 10(-5) g and 1 g. We conclude that faster and more massive meteoroids produce a larger emission volume, but not a higher air plasma temperature. We speculate that the meteoric plasma may be in multiphase equilibrium with the ambient atmosphere, which could mean lower plasma temperatures in a CO(2)-rich early Earth atmosphere.     

A culture-independent survey of the bacterial community in a radon hot spring

Paralana is an active, radon-containing hot spring situated in a region of South Australia's Flinders Ranges with a long history of hydrothermal activity. Our aim was to determine the bacterial composition of Paralana using a culture-independent, 16S rRNA-based technique. The presence of a diverse bacterial community was strongly suggested by the large number (approximately 180) of different ribotypes obtained upon analysis of nine hot spring samples. DNA sequencing of Paralana 16S rRNA genes corroborated this observation, identifying representatives of seven confirmed and two candidate divisions of the domain Bacteria. These included Cyanobacteria, Proteobacteria (both beta and delta subdivisions), the Cytophaga-Flexibacter-Bacteroides group, Low G + C Gram-positives, Nitrospira, green non-sulfur bacteria, green sulfur bacteria, OP8, and OP12. No known ionizing radiation-resistant Bacteria were identified. Only one Paralana 16S rRNA sequence type (recombinant B5D) was homologous to a sequence previously identified from a radioactive environment.