Multifrequency electron spin resonance detection of solid-state organic free radicals in HCN polymer and a Titan tholin

Macromolecules derived from hydrogen cyanide (HCN) may be major components of the dark matter observed in bodies in the outer Solar System, which include comets and asteroids. HCN oligomers and polymers are readily formed at room temperature and react with water to produce polypeptides and alpha-amino acids or undergo pyrolysis to produce nitrogen heterocycles. Electron spin resonance (ESR) spectroscopy shows that HCN polymer mixtures contain a significant amount of long-lived organic free radicals that are primarily carbon-based. For comparison, we have also examined samples of tholins produced from experimental analogs of Titan aerosols, which has been shown by trace organic analysis to consist partly of HCN polymer. The "Titan tholin" exhibits at least two ESR signals that can be assigned to nitrogen- and carbon-centered radicals, although heating the sample eliminates the nitrogen centers and increases the signal from the carbon centers. This result suggests that the nitrogen-centered radicals may be thermodynamically less stable, but are kinetically trapped during the spark-discharge reactions that produce tholins from mixtures of gases such as methane and nitrogen. The results strongly support previous proposals of free radical mechanisms for HCN polymerization.     

Space power systems: Producing transportation (and other chemical) fuels as an alternative to electricity generation

While most studies on space power systems target electricity generation as the energy product, industrialized nations also have a need for chemicals to support transportation and other purposes. This paper therefore describes an alternative target for the application of space power systems: the production of chemical fuels based on radiant energy beamed or reflected from orbiting platforms. If cost and efficiency targets can be achieved, Solar Thermochemical Plants—occupying a few square kilometers each—can potentially generate substantial quantities of transportation fuels, therefore enabling reductions in the consumption of petroleum and the emission of carbon dioxide. The specifics of the approach that are described in this paper include the concentration of radiant energy within ground-based systems so that high temperature heat is provided for thermochemical process networks. This scoping study includes the evaluation of various feedstock chemicals as input to the Solar Thermochemical Plant: natural gas, biomass and zero-energy chemicals (water and carbon dioxide); and the production of either hydrogen or long-chain hydrocarbons (i.e., Fischer–Tropsch fuels) as the Solar Fuel product of the plant.     

Studies of radio frequency interference at Parkes Observatory

During 16 weeks of continuous SETI observing at the Parkes Observatory in New South Wales, Australia, a set of time-averaged data with 643 Hz resolution were recorded and returned to the SETI Institute for post-processing. These data are the 14 second (10 frame) average powers in each of 15,552 “subband” channels covering 10 MHz of the spectrum in both right and left circular polarizations that were used by the signal detection hardware to baseline and threshold the 1 Hz high resolution SETI spectra. The observations covered frequencies from 1.2 to 3 GHz, tracking 209 stellar targets across the sky. The data at each frequency were averaged over all directions and then interrogated to attempt to determine the prevalence of radio frequency interference (RFI). Estimates were made for the probability of encountering RFI at a particular frequency. Particular attention has been paid to those portions of the spectrum that are allocated as primary use status, or footnote protection for radioastronomy. This sixteen-week snapshot of the RFI situation at Parkes is by now out of date. Unfortunately, a year later, the situation has undoubtedly worsened.     

The Urey instrument: an advanced in situ organic and oxidant detector for Mars exploration

The Urey organic and oxidant detector consists of a suite of instruments designed to search for several classes of organic molecules in the martian regolith and ascertain whether these compounds were produced by biotic or abiotic processes using chirality measurements. These experiments will also determine the chemical stability of organic molecules within the host regolith based on the presence and chemical reactivity of surface and atmospheric oxidants. Urey has been selected for the Pasteur payload on the European Space Agency's (ESA's) upcoming 2013 ExoMars rover mission. The diverse and effective capabilities of Urey make it an integral part of the payload and will help to achieve a large portion of the mission's primary scientific objective: "to search for signs of past and present life on Mars." This instrument is named in honor of Harold Urey for his seminal contributions to the fields of cosmochemistry and the origin of life.     

Modularity and Spacecraft Cost

From computers to aeronautics, many industries have achieved great cost savings through the use of modular engineering approaches. In standardizing interfaces between elements and by reusing functional units, projects can achieve direct reductions in required development labor and secondary savings from enhanced reliability via improved process control from manufacturing identical units. Issues involved in the extension of modular design to the space industry are discussed. A cost model is developed to resolve some of the conflicting advantages and disadvantages between modular and customized designs. Key regimes are identified that represent the best opportunities for applying modular concepts.     

Why space science and exploration benefit everyone

As well as providing practical information on Earth-besetting problems, space science and exploration are vital tools for capturing the public imagination and encouraging young people's interest in space. The relatively small scale of some scientific instruments also allows mission participation by developing countries. Citing the work of the UN and various NGOs in promoting study and distribution of space science data, the authors recommend that it be given a higher profile and suggest a number of projects -- the Mars drill study in Egypt, refurbishment of a telescope facility in Sri Lanka -- involving developing countries that should be followed up, as well as listing ongoing successful projects. The UN is urged to continue its annual workshops on space science (apparently under threat) and to ensure its inclusion in the forthcoming UNISPACE III Conference.     

Human navigation ability: Tests of the encoding-error model of path integration

This paper tests the generality and implications of an encoding-error model (Fujita et al. 1993) of humans' ability to keep track of their position in space in the absence of visual cues (i.e., by nonvisual path integration). The model proposes that when people undergo nonvisually guided travel, they encode the distances and turns that they experience, and their errors reflect systematic inaccuracies in the encoding process. Thus when people try to return to the origin of travel, they base their response on mis-encoded values of the outbound distances and turns. The two experiments reported here addressed three issues related to the model: (i) whether path integration is context-dependent and if so, how rapidly it adapts to recently experienced distances and turns; (ii) whether effects of experience can be specifically attributed to changes in the encoding process, and if so, what changes; and (iii) whether the encoding process represents distances and turns in the individual paths without considering their spatial relationship to one another (i.e., an object-centered representation). Testing these issues allows us to evaluate and develop the model.Subjects who were blindfolded or had restricted vision were led through two legs of a triangle and the turn between, then tried to return to the origin. Paths varied in whether experienced legs and turns were small or large (Experiment 1) and in variability of return and outbound course (Experiment 2). Response turn, distance and course were determined. The assumption of immutable encoding functions was not supported; encoding processes were context dependent, although they did not adapt within a block of trials. Although effects of experience could be accounted for by the model, the affected parameters were not always as predicted, and in some cases additional parameters were necessary. Results of manipulating variability in return course were consistent with the model's assumption of object-centered representation.     

Expanding global access to civilian and commercial remote sensing data: implications and policy issues

Current and planned developments in the field of civilian and commercial² satellite imagery promise a major expansion in international accessibility to remote sensing data and technologies. This paper addresses the implications of the expanding global access to land remote sensing data and their derived products. While atmospheric, meteorological, and oceanographic data is also widely available at cost or free of charge, it is land remote sensing – specifically the unique systems with high-resolution and frequent revisit times – that are of primary concern for international and regional security issues. Military and intelligence satellites are not addressed in this discussion of expansion due to their inherently controlled access, unless such systems also provide commercially available imagery or products (as is the case with some Russian systems).