Fluid inclusion studies of chemosynthetic carbonates: strategy for seeking life on Mars

Fluid inclusions in minerals hold the potential to provide important data on the chemistry of the ambient fluids during mineral precipitation. Especially interesting to astrobiologists are inclusions in low-temperature minerals that may have been precipitated in the presence of microorganisms. We demonstrate that it is possible to obtain data from inclusions in chemosynthetic carbonates that precipitated by the oxidation of organic carbon around methane-bearing seepages. Chemosynthetic carbonates have been identified as a target rock for astrobiological exploration. Other surficial rock types identified as targets for astrobiological exploration include hydrothermal deposits, speleothems, stromatolites, tufas, and evaporites, each of which can contain fluid inclusions. Fracture systems below impact craters would also contain precipitates of minerals with fluid inclusions. As fluid inclusions are sealed microchambers, they preserve fluids in regions where water is now absent, such as regions of the martian surface. Although most inclusions are < 5 microns, the possibility to obtain data from the fluids, including biosignatures and physical remains of life, underscores the advantages of technological advances in the study of fluid inclusions. The crushing of bulk samples could release inclusion waters for analysis, which could be undertaken in situ on Mars.     

The commercial challenge to Arianespace: the TCI affair

The question of how far rockets used for commercial launch services are subsidised by their respective governments remains highly topical. This article traces the history of the first legal challenge to be made on this basis by a US launch service provider against Arianespace, a case which also called into question the pricing of the Space Shuttle. The perceptions, deliberations and negotiations of both sides are traced and it is noted that their most important outcome was not settlement of the case itself but agreement to start serious consultations on defining ‘rules of the road’ regarding government support to the commercial launch industry.     

Approximate qualitative spatial reasoning

Qualitative relations between spatial regions play an importantrole in the representation and manipulation of spatial knowledge.The RCC5 and RCC8 systems of relations,used in the Region-Connection Calculus, are of fundamentalimportance. These two systems deal with ideal regions havingprecisely determined location. However,in many practical examples of spatial reasoning,regions are represented by finite approximations rather than known precisely.Approximations may be given by describing how a regionrelates to cells forming a partition of the space underconsideration. Although the RCC5 and RCC8 systems have beengeneralized to ``egg-yolk' regions, in order to modelcertain types of vagueness, their extension to regionsapproximated in this way has not been discussed before.This paper presents two methods, the syntactic and the semantic, by which the RCC5 and RCC8 systemsmay be defined for approximate regions. The syntactic uses algebraicoperations on approximate regions which generalize operations on preciseregions. The semantic method makes use of the set of preciseregions which could be the intended interpretation of anapproximate region. Relationships between these two methods arediscussed in detail.alternative to navigation training with a map.     

The potential for lithoautotrophic life on Mars: application to shallow interfacial water environments

We developed a numerical model to assess the lithoautotrophic habitability of Mars based on metabolic energy, nutrients, water availability, and temperature. Available metabolic energy and nutrient sources were based on a laboratory-produced Mars-analog inorganic chemistry. For this specific reference chemistry, the most efficient lithoautotrophic microorganisms would use Fe(2+) as a primary metabolic electron donor and NO(3)(-) or gaseous O(2) as a terminal electron acceptor. In a closed model system, biomass production was limited by the electron donor Fe(2+) and metabolically required P, and typically amounted to approximately 800 pg of dry biomass/ml ( approximately 8,500 cells/ml). Continued growth requires propagation of microbes to new fecund environments, delivery of fresh pore fluid, or continued reaction with the host material. Within the shallow cryosphere--where oxygen can be accessed by microbes and microbes can be accessed by exploration-lithoautotrophs can function within as little as three monolayers of interfacial water formed either by adsorption from the atmosphere or in regions of ice stability where temperatures are within some tens of degrees of the ice melting point. For the selected reference host material (shergottite analog) and associated inorganic fluid chemistry, complete local reaction of the host material potentially yields a time-integrated biomass of approximately 0.1 mg of dry biomass/g of host material ( approximately 10(9) cells/g). Biomass could also be sustained where solutes can be delivered by advection (cryosuction) or diffusion in interfacial water; however, both of these processes are relatively inefficient. Lithoautotrophs in near-surface thin films of water, therefore, would optimize their metabolism by deriving energy and nutrients locally. Although the selected chemistry and associated model output indicate that lithoautotrophic microbial biomass could accrue within shallow interfacial water on Mars, it is likely that these organisms would spend long periods in maintenance or survival modes, with instantaneous biomass comparable to or less than that observed in extreme environments on Earth.     

Neutron measurements in space

The experimental measurements of the neutron flux and energy spectrum in space since 1964 are reviewed and related to the theoretical predictions. A discussion of the neutron sources is presented. The difficulties associated with neutron measurements of both the atmospheric neutron leakage flux and solar neutrons are included. Particular emphasis is placed upon the neutron leakage flux and energy measurements at energies greater than about 1 MeV. The possibilities of CRAND as a source for the energetic trapped protons are discussed in light of recent measurements of the 10–100 MeV neutron flux. The current status of the solar neutron flux observations is also presented.The primary purposes of neutron measurements in space have been to determine the neutron leakage flux from the atmosphere of the Earth and the solar neutron flux. As a consequence of the inefficient methods for neutron detection and the difficulties of conducting the measurements in the presence of the galactic and solar cosmic-ray backgrounds, the experimental results are very conflicting. It is the purpose of this review to interpret and discuss recent neutron measurements. In order to understand these results the theoretical predictions of the neutron fluxes and energy spectra from possible neutron sources will be briefly presented. Since comparisons of the different neutron measurements depend critically upon the experimental techniques, we will briefly discuss neutron detection methods applicable to space measurements. The emphasis will be upon measurements since 1964 made outside the Earth's atmosphere, but considerable reference will be made to high energy neutron experiments conducted within the Earth's atmosphere at < 10g cm^-2 altitude. A review of earlier neutron measurements of terrestrial and solar neutrons has been made by Haymes (1965).     

Chemistry of the solar nebula

The composition, mineralogy and texture of chondritic meteorites suggest they are relatively unaltered relicts of the condensation and accretion processes which took place in the primitive solar nebula. Chondrites thus are thought to contain a unique record of the physico-chemical conditions which prevailed at the time and place (asteroid belt) of their origin. Elemental abundance patterns are an important clue to the events and processes. Most elements can be placed in one of four groups according to their observed fractionation behavior in chondritic material: refractory, siderophile, normally depleted and strongly depleted. This grouping can be explained in terms of four events which presumably took place during cooling, condensation and accretion in the nebula. In order of inferred occurrence these are: (1) partial loss of the initial condensates rich in refractory elements at T > 1300K, (2) partial loss of metallic Fe-Ni grains, perhaps because they were magnetic, at 1000 to 700K, (3) partial remelting and outgassing of the condensate (chondrule formation) at 600 to 350K, and (4) accretion, when the P-T conditions controlled the volatile content (500 to 350K). Total gas pressure at the time and place of accretion is estimated to fall between 10^-–6 and 10^–-4 atm.Contribution No. 80, Center for Meteorite Studies.     

Temperature effects in the ATIC BGO calorimeter

The Advanced Thin Ionization Calorimeter (ATIC) Balloon Experiment had a successful test flight and a science flight in 2000–01 and 2002–03 and an unsuccessful launch in 2005–06 from McMurdo, Antarctica, returning 16 and 19 days of flight data. ATIC is designed to measure the spectra of cosmic rays (protons to iron). The instrument is composed of a Silicon matrix detector followed by a carbon target interleaved with scintillator tracking layers and a segmented BGO calorimeter composed of 320 individual crystals totaling 18 radiation lengths to determine the particle energy. BGO (Bismuth Germanate) is an inorganic scintillation crystal and its light output depends not only on the energy deposited by particles but also on the temperature of the crystal. The temperature of balloon instruments during flight is not constant due to sun angle variations as well as differences in albedo from the ground. The change in output for a given energy deposit in the crystals in response to temperature variations was determined.