Aqueous corrosion of phosphide minerals from iron meteorites: a highly reactive source of prebiotic phosphorus on the surface of the early Earth

We present the results of an experimental study of aqueous corrosion of Fe-phosphide under conditions relevant to the early Earth. The results strongly suggest that iron meteorites were an important source of reactive phosphorus (P), a requirement for the formation of P-based life. We further demonstrate that iron meteorites were an abundant source of phosphide minerals early in Earth history. Phosphide corrosion was studied in five different solutions: deionized water, deionized water buffered with sodium bicarbonate, deionized water with dissolved magnesium and calcium chlorides, deionized water containing ethanol and acetic acid, and deionized water containing the chlorides, ethanol, and acetic acid. Experiments were performed in the presence of both air and pure Ar gas to evaluate the effect of atmospheric chemistry. Phosphide corrosion in deionized water results in a metastable mixture of mixed-valence, P-bearing ions including pyrophosphate and triphosphate, key components for metabolism in modern life. In a pH-buffered solution of NaHCO(3), the condensed and reduced species diphosphonate is an abundant corrosion product. Corrosion in ethanol- and acetic acid-containing solutions yields additional P-bearing organic molecules, including acetyl phosphonate and a cyclic triphosphorus molecule. Phosphonate is a major corrosion product of all experiments and is the only P-bearing molecule that persists in solutions with high concentrations of magnesium and calcium chlorides, which suggests that phosphonate may have been a primitive oceanic source of P. The stability and reactivity of phosphonate and hypophosphite in solution were investigated to elucidate reaction mechanisms and the role of mineral catalysts on P-solution chemistry. Phosphonate oxidation is rapid in the presence of Fe metal but negligible in the presence of magnetite and in the control sample. The rate of hypophosphite oxidation is independent of reaction substrate.     

Generating requirements for complex embedded systems using State Analysis

It has become clear that spacecraft system complexity is reaching a threshold where customary methods of control are no longer affordable or sufficiently reliable. At the heart of this problem are the conventional approaches to systems and software engineering based on subsystem-level functional decomposition, which fail to scale in the tangled web of interactions typically encountered in complex spacecraft designs. Furthermore, there is a fundamental gap between the requirements on software specified by systems engineers and the implementation of these requirements by software engineers. Software engineers must perform the translation of requirements into software code, hoping to accurately capture the systems engineer's understanding of the system behavior, which is not always explicitly specified. This gap opens up the possibility for misinterpretation of the systems engineer's intent, potentially leading to software errors. This problem is addressed by a systems engineering methodology called State Analysis, which provides a process for capturing system and software requirements in the form of explicit models. This paper describes how requirements for complex aerospace systems can be developed using State Analysis, using representative spacecraft examples.     

Australia''s space heritage

An overview is provided of Australian space activities and their legacy, including the Woomera launch centre, tracking stations, space science, technology and applications. The military basis for many of the larger activities is discussed and the importance of using space-based remote sensing to deal with mounting global problems is emphasized.     

The InSight Mars Lander and Its Effect on the Subsurface Thermal Environment

The 2018 InSight (Interior Exploration using Seismic Investigations, Geodesy and Heat Transport) Mission has the mission goal of providing insitu data for the first measurement of the geothermal heat flow of Mars. The Heat Flow and Physical Properties Package (HP³) will take thermal conductivity and thermal gradient measurements to approximately 5 m depth. By necessity, this measurement will be made within a few meters of the lander. This means that thermal perturbations from the lander will modify local surface and subsurface temperature measurements. For HP³’s sensitive thermal gradient measurements, this spacecraft influence will be important to model and parameterize. Here we present a basic 3D model of thermal effects of the lander on its surroundings. Though lander perturbations significantly alter subsurface temperatures, a successful thermal gradient measurement will be possible in all thermal conditions by proper (\(>3~\mbox{m}\) depth) placement of the heat flow probe.     

A glimpse from the inside of a space suit: What is it really like to train for an EVA?

The beauty of the view from the office of a spacewalking astronaut gives the impression of simplicity, but few beyond the astronauts, and those who train them, know what it really takes to get there. Extravehicular Activity (EVA) training is an intense process that utilizes NASA’s Neutral Buoyancy Laboratory (NBL) to develop a very specific skill set needed to safely construct and maintain the orbiting International Space Station. To qualify for flight assignments, astronauts must demonstrate the ability to work safely and efficiently in the physically demanding environment of the space suit, possess an acute ability to resolve unforeseen problems, and implement proper tool protocols to ensure no tools will be lost in space. Through the insights and the lessons learned by actual EVA astronauts and EVA instructors, this paper will take you on a journey through an astronaut’s earliest experiences working in the space suit, termed the Extravehicular Mobility Unit (EMU), in the underwater training environment of the NBL. This work details an actual Suit Qualification NBL training event, outlines the numerous challenges the astronauts face throughout their initial training, and the various ways they adapt their own abilities to overcome them. The goal of this paper is to give everyone a small glimpse into what it is really like to work in a space suit.     

The Ultraviolet Spectrograph on NASA’s Juno Mission

The ultraviolet spectrograph instrument on the Juno mission (Juno-UVS) is a long-slit imaging spectrograph designed to observe and characterize Jupiter’s far-ultraviolet (FUV) auroral emissions. These observations will be coordinated and correlated with those from Juno’s other remote sensing instruments and used to place in situ measurements made by Juno’s particles and fields instruments into a global context, relating the local data with events occurring in more distant regions of Jupiter’s magnetosphere. Juno-UVS is based on a series of imaging FUV spectrographs currently in flight—the two Alice instruments on the Rosetta and New Horizons missions, and the Lyman Alpha Mapping Project on the Lunar Reconnaissance Orbiter mission. However, Juno-UVS has several important modifications, including (1) a scan mirror (for targeting specific auroral features), (2) extensive shielding (for mitigation of electronics and data quality degradation by energetic particles), and (3) a cross delay line microchannel plate detector (for both faster photon counting and improved spatial resolution). This paper describes the science objectives, design, and initial performance of the Juno-UVS.     

Speech Data Rate Reduction Part I: Applicability of Modern Estimation Theory

Efficient coding of continuous speech signals for digital representation has attracted much interest in recent years. The underlying aim of efficient coding methods is to reduce the channel capacity required to represent a signal to meet a specific reconstruction fidelity criterion. To achieve this objective, modern speech data compression techniques rely on two very similar procedures. One procedure uses predictive deconvolution which subtracts from the current signal value that portion which can be predicted from its past and thus removes redundancy in the speech by removing sequential correlation. The signal thus requires fewer bits for equivalent quantization error. The second procedure involves identification of a complete mathematical model of the speech producing mechanism. This involves determination of the characteristics of the source that drives this transfer function. Data reduction is again achieved since the rate of change of the parameters of the speech model is much smaller than the rate of change of the speech waveform. This paper develops these data reduction procedures in terms of modern estimation theory, specifically a Kalman filter model, and illustrates the utility of this model as an analysis tool by means of an example based on a uniform tube which provides a qualitative assessment of the potential of the technique for application to real speech signals.     

Geophysical Constraints on the Evolution of Mars

The evolution of Mars is discussed using results from the recent Mars Global Surveyor (MGS) and Mars Pathfinder missions together with results from mantle convection and thermal history models and the chemistry of Martian meteorites. The new MGS topography and gravity data and the data on the rotation of Mars from Mars Pathfinder constrain models of the present interior structure and allow estimates of present crust thickness and thickness variations. The data also allow estimates of lithosphere thickness variation and heat flow assuming that the base of the lithosphere is an isotherm. Although the interpretation is not unambiguous, it can be concluded that Mars has a substantial crust. It may be about 50 km thick on average with thickness variations of another ±50 km. Alternatively, the crust may be substantially thicker with smaller thickness variations. The former estimate of crust thickness can be shown to be in agreement with estimates of volcanic production rates from geologic mapping using data from the camera on MGS and previous missions. According to these estimates most of the crust was produced in the Noachian, roughly the first Gyr of evolution. A substantial part of the lava generated during this time apparently poured onto the surface to produce the Tharsis bulge, the largest tectonic unit in the solar system and the major volcanic center of Mars. Models of crust growth that couple crust growth to mantle convection and thermal evolution are consistent with an early 1 Gyr long phase of vigorous volcanic activity. The simplest explanation for the remnant magnetization of crustal units of mostly the southern hemisphere calls for an active dynamo in the Noachian, again consistent with thermal history calculations that predict the core to become stably stratified after some hundred Myr of convective cooling and dynamo action. The isotope record of the Martian meteorites suggest that the core formed early and rapidly within a few tens of Myr. These data also suggest that the silicate rock component of the planet was partially molten during that time. The isotope data suggest that heterogeneity resulted from core formation and early differentiation and persisted to the recent past. This is often taken as evidence against vigorous mantle convection and early plate tectonics on Mars although the latter assumption can most easily explain the early magnetic field. The physics of mantle convection suggests that there may be a few hundred km thick stagnant, near surface layer in the mantle that would have formed rapidly and may have provided the reservoirs required to explain the isotope data. The relation between the planform of mantle convection and the tectonic features on the surface is difficult to entangle. Models call for long wavelength forms of flow and possibly a few strong plumes in the very early evolution. These plumes may have dissolved with time as the core cooled and may have died off by the end of the Noachian.     

The Rotation and Interior Structure Experiment on the InSight Mission to Mars

The Rotation and Interior Structure Experiment (RISE) on-board the InSight mission will use the lander’s X-band (8 GHz) radio system in combination with tracking stations of the NASA Deep Space Network (DSN) to determine the rotation of Mars. RISE will measure the nutation of the Martian spin axis, detecting for the first time the effect of the liquid core of Mars and providing in turn new constraints on the core radius and density. RISE will also measure changes in the rotation rate of Mars on seasonal time-scales thereby constraining the atmospheric angular momentum budget. Finally, RISE will provide a superb tie between the cartographic and inertial reference frames. This paper describes the RISE scientific objectives and measurements, and provides the expected results of the experiment.     

Influence of Body Waves,Instrumentation Resonances,and Prior Assumptions on Rayleigh Wave Ellipticity Inversion for Shallow Structure at the InSight Landing Site

Based on an updated model of the regolith’s elastic properties, we simulate the ambient vibrations background wavefield recorded by InSight’s Seismic Experiment for Interior Structure (SEIS) on Mars to characterise the influence of the regolith and invert SEIS data for shallow subsurface structure. By approximately scaling the synthetics based on seismic signals of a terrestrial dust devil, we find that the high-frequency atmospheric background wavefield should be above the self-noise of SEIS’s SP sensors, even if the signals are not produced within 100–200 m of the station. We compare horizontal-to-vertical spectral ratios and Rayleigh wave ellipticity curves for a surface-wave based simulation on the one hand with synthetics explicitly considering body waves on the other hand and do not find any striking differences. Inverting the data, we find that the results are insensitive to assumptions on density. By contrast, assumptions on the velocity range in the upper-most layer have a strong influence on the results also at larger depth. Wrong assumptions can lead to results far from the true model in this case. Additional information on the general shape of the curve, i.e. single or dual peak, could help to mitigate this effect, even if it cannot directly be included into the inversion. We find that the ellipticity curves can provide stronger constraints on the minimum thickness and velocity of the second layer of the model than on the maximum values. We also consider the effect of instrumentation resonances caused by the lander flexible modes, solar panels, and the SEIS levelling system. Both the levelling system resonances and the lander flexible modes occur at significantly higher frequencies than the expected structural response, i.e. above 35 Hz and 20 Hz, respectively. While the lander and solar panel resonances might be too weak in amplitude to be recorded by SEIS, the levelling system resonances will show up clearly in horizontal spectra, the H/V and ellipticity curves. They are not removed by trying to extract only Rayleigh-wave dominated parts of the data. However, they can be distinguished from any subsurface response by their exceptionally low damping ratios of 1% or less as determined by random decrement analysis. The same applies to lander-generated signals observed in actual data from a Moon analogue experiment, so we expect this analysis will be useful in identifying instrumentation resonances in SEIS data.