Raman imagery: a new approach to assess the geochemical maturity and biogenicity of permineralized precambrian fossils

Laser-Raman imagery is a non-intrusive, non-destructive analytical technique, recently introduced to Precambrian paleobiology, that can be used to demonstrate a one-to-one spatial correlation between the optically discernible morphology and kerogenous composition of permineralized fossil microorganisms. Made possible by the submicron-scale resolution of the technique and its high sensitivity to the Raman signal of carbonaceous matter, such analyses can be used to determine the chemical-structural characteristics of organic-walled microfossils and associated sapropelic carbonaceous matter in acid-resistant residues and petrographic thin sections. Here we use this technique to analyze kerogenous microscopic fossils and associated carbonaceous sapropel permineralized in 22 unmetamorphosed or little-metamorphosed fine-grained chert units ranging from approximately 400 to approximately 2,100 Ma old. The lineshapes of the Raman spectra acquired vary systematically with five indices of organic geochemical maturation: (1) the mineral-based metamorphic grade of the fossil-bearing units; (2) the fidelity of preservation of the fossils studied; (3) the color of the organic matter analyzed; and both the (4) H/C and (5) N/C ratios measured in particulate kerogens isolated from bulk samples of the fossil-bearing cherts. Deconvolution of relevant spectra shows that those of relatively well-preserved permineralized kerogens analyzed in situ exhibit a distinctive set of Raman bands that are identifiable also in hydrated organic-walled microfossils and particulate carbonaceous matter freed from the cherts by acid maceration. These distinctive Raman bands, however, become indeterminate upon dehydration of such specimens. To compare quantitatively the variations observed among the spectra measured, we introduce the Raman Index of Preservation, an approximate measure of the geochemical maturity of the kerogens studied that is consistent both with the five indices of organic geochemical alteration and with spectra acquired from fossils experimentally heated under controlled laboratory conditions. The results reported provide new insight into the chemical-structural characteristics of ancient carbonaceous matter, the physicochemical changes that accompany organic geochemical maturation, and a new criterion to be added to the suite of evidence by which to evaluate the origin of minute fossil-like objects of possible but uncertain biogenicity.     

Surreal estate: addressing the issue of ‘Immovable Property Rights on the Moon’

At a time when scientific and commercial interest in the Moon is being reinvigorated it is becoming fashionable for ordinary individuals to ‘buy’ plots on the lunar surface, with the ‘vendors’ arguing that an absence of specific prohibition of individual private activity in space makes such action legal. It is therefore time for the legal community to address this situation by investigating just how legal such activity is—and bringing their findings to the attention of governments. This can be done through an examination of the relationship between national law and international space law, of the provisions of international space law—especially Article 2 of the Outer Space Treaty—and by answering any claims to private ownership of immovable property. Aside from the fact that individuals appear to be being duped, the pursuit of property claims on the Moon could impede future activities aimed at benefiting society.     

On the breakdown of wave fronts of characteristics in an ideal dissociating gas

Using the method of characteristics, the problem of breaking or non-breaking of waves is studied in a plane cylindrically or spherically symmetric flow of an ideal dissociating gas. It is investigated as to how the effects of dissociation and that of the wave front curvature influence the breaking or non-breaking of waves. In a symmetrical converging gas motion a remarkable difference between the behaviours of cylindrical and spherical waves is discovered.     

Mineralogical biosignatures and the search for life on Mars

If life ever existed, or still exists, on Mars, its record is likely to be found in minerals formed by, or in association with, microorganisms. An important concept regarding interpretation of the mineralogical record for evidence of life is that, broadly defined, life perturbs disequilibria that arise due to kinetic barriers and can impart unexpected structure to an abiotic system. Many features of minerals and mineral assemblages may serve as biosignatures even if life does not have a familiar terrestrial chemical basis. Biological impacts on minerals and mineral assemblages may be direct or indirect. Crystalline or amorphous biominerals, an important category of mineralogical biosignatures, precipitate under direct cellular control as part of the life cycle of the organism (shells, tests, phytoliths) or indirectly when cell surface layers provide sites for heterogeneous nucleation. Biominerals also form indirectly as by-products of metabolism due to changing mineral solubility. Mineralogical biosignatures include distinctive mineral surface structures or chemistry that arise when dissolution and/or crystal growth kinetics are influenced by metabolic by-products. Mineral assemblages themselves may be diagnostic of the prior activity of organisms where barriers to precipitation or dissolution of specific phases have been overcome. Critical to resolving the question of whether life exists, or existed, on Mars is knowing how to distinguish biologically induced structure and organization patterns from inorganic phenomena and inorganic self-organization. This task assumes special significance when it is acknowledged that the majority of, and perhaps the only, material to be returned from Mars will be mineralogical.     

Economy of modular low-technology launch vehicles

The paper comprises an assessment of the design and the economics of so-called “low-cost” simple modular launch vehicles. It is shown that the performance is very marginal and that the cost per launch cannot compete with technically more advanced fully reusable vehicles. Especially a private-funded development cannot be amortized economically in case of an expendable launch vehicle.     

An Analysis of the Low-Frequency Component in Measurements of Angular Velocity and Microacceleration onboard the Foton-12 Satellite

We compare the results of two methods used to determine the angular velocity of the Foton-12 satellite and the low-frequency component of microaccelerations onboard it. The first method is based on reconstruction of the satellite's rotational motion using the data of onboard measurements of the strength of the Earth's magnetic field. The motion (time dependence of the orientation parameters and angular velocity) was found from the condition of best approximation of the measurement data by the functions calculated along the solutions to equations of attitude motion of the satellite. The solutions found were used to calculate the quasistatic component of microaccelerations at certain points of the satellite, in particular, at the point of location of an accelerometer of the QSAM system. Filtration of the low-frequency component of the angular velocity and microacceleration from the data of measurements by a sensor of angular velocity and by the accelerometer of this system served as a second method. The filtration was made using the discrete Fourier series. A spectral analysis of the functions representing the results of determining the angular velocity and microacceleration by both methods is performed. Comparing the frequencies and amplitudes of the harmonic component of these functions allowed us to estimate the accuracy of measurements made by the QSAM system in the low-frequency range.     

Production of neutrons from interactions of GCR-like particles

In order to help assess the risk to astronauts due to the long-term exposure to the natural radiation environment in space, an understanding of how the primary radiation field is changed when passing through shielding and tissue materials must be obtained. One important aspect of the change in the primary radiation field after passing through shielding materials is the production of secondary particles from the breakup of the primary. Neutrons are an important component of the secondary particle field due to their relatively high biological weighting factors, and due to their relative abundance, especially behind thick shielding scenarios. Because of the complexity of the problem, the estimation of the risk from exposure to the secondary neutron field must be handled using calculational techniques. However, those calculations will need an extensive set of neutron cross section and thicktarget neutron yield data in order to make an accurate assessment of the risk. In this paper we briefly survey the existing neutron-production data sets that are applicable to the space radiation transport problem, and we point out how neutron production from protons is different than neutron production from heavy ions. We also make comparisons of one the heavy-ion data sets with Boltzmann-Uehling-Uhlenbeck (BUU) calculations.     

Radial velocity search for low mass companions of nearby stars

The detection of substellar companions of nearby stars is very difficult, because these objects are very faint and are located close to their bright parent stars. One way to attack this problem is to look for small periodic motion of the bright star, induced by the gravitational attraction exerted by the unseen small companion. Over the past decade stellar spectroscopy has been used by a few teams to monitor the radial velocities of several samples of stars, with a threshold for detection of companions well below the substellar limit of about 0.08 M. So far, only a few possible spectroscopic binaries have been identified where the unseen companions might be substellar.Recently, radio observers discovered that the millisecond pulsar PSR B1257+12 displays periodic variations in the pulse arrival times, indicating the existence of at least three unseen companions in circular orbits around the pulsar. This is the first convincing case for an extra-solar planetary system. This discovery suggests that planetary systems can form in very different situations, and therefore may prove to be common.     

Electrostatic Instability and Plasma Irregularities in the Topside Ionosphere above the South-Atlantic Geomagnetic Anomaly

The data of measuring the plasma density in the topside ionosphere for the South-Atlantic geomagnetic anomaly region are presented. It is shown that irregular plasma structures with a wide spectrum of irregularity scale (including large-scale structures with a dimension of order of some hundred kilometers) can be generated in the fields of electrostatic turbulence in inhomogeneous plasma.