Raman imagery: a new approach to assess the geochemical maturity and biogenicity of permineralized precambrian fossils

Laser-Raman imagery is a non-intrusive, non-destructive analytical technique, recently introduced to Precambrian paleobiology, that can be used to demonstrate a one-to-one spatial correlation between the optically discernible morphology and kerogenous composition of permineralized fossil microorganisms. Made possible by the submicron-scale resolution of the technique and its high sensitivity to the Raman signal of carbonaceous matter, such analyses can be used to determine the chemical-structural characteristics of organic-walled microfossils and associated sapropelic carbonaceous matter in acid-resistant residues and petrographic thin sections. Here we use this technique to analyze kerogenous microscopic fossils and associated carbonaceous sapropel permineralized in 22 unmetamorphosed or little-metamorphosed fine-grained chert units ranging from approximately 400 to approximately 2,100 Ma old. The lineshapes of the Raman spectra acquired vary systematically with five indices of organic geochemical maturation: (1) the mineral-based metamorphic grade of the fossil-bearing units; (2) the fidelity of preservation of the fossils studied; (3) the color of the organic matter analyzed; and both the (4) H/C and (5) N/C ratios measured in particulate kerogens isolated from bulk samples of the fossil-bearing cherts. Deconvolution of relevant spectra shows that those of relatively well-preserved permineralized kerogens analyzed in situ exhibit a distinctive set of Raman bands that are identifiable also in hydrated organic-walled microfossils and particulate carbonaceous matter freed from the cherts by acid maceration. These distinctive Raman bands, however, become indeterminate upon dehydration of such specimens. To compare quantitatively the variations observed among the spectra measured, we introduce the Raman Index of Preservation, an approximate measure of the geochemical maturity of the kerogens studied that is consistent both with the five indices of organic geochemical alteration and with spectra acquired from fossils experimentally heated under controlled laboratory conditions. The results reported provide new insight into the chemical-structural characteristics of ancient carbonaceous matter, the physicochemical changes that accompany organic geochemical maturation, and a new criterion to be added to the suite of evidence by which to evaluate the origin of minute fossil-like objects of possible but uncertain biogenicity.     

Thrust modulation of solid propellant rockets by a fluidic vortex valve with secondary combustion

An analytical model for calculation of the thrust and pressure modulation of a solid propellant rocket by means of a fluidic vortex valve with secondary combustion has been developed. Thrust control by the vortex valve method was found superior to the axial injection of control flow. Addition of oxygen in the injected flow improves the energetic performance of the system as well as the thrust modulation capability. Experiments have been conducted using a mixture of nitrogen and oxygen as the injection gas. The two main parameters investigated in a series of experiments were the oxygen percentage in the injection gas and the ratio between the mass flow rates of the control gas and the solid propellant combustion products. The results show an increase of thrust by a factor of 2 for a 25% addition in mass flow rate by secondary injection at optimal conditions.     

On the breakdown of wave fronts of characteristics in an ideal dissociating gas

Using the method of characteristics, the problem of breaking or non-breaking of waves is studied in a plane cylindrically or spherically symmetric flow of an ideal dissociating gas. It is investigated as to how the effects of dissociation and that of the wave front curvature influence the breaking or non-breaking of waves. In a symmetrical converging gas motion a remarkable difference between the behaviours of cylindrical and spherical waves is discovered.     

Mineralogical biosignatures and the search for life on Mars

If life ever existed, or still exists, on Mars, its record is likely to be found in minerals formed by, or in association with, microorganisms. An important concept regarding interpretation of the mineralogical record for evidence of life is that, broadly defined, life perturbs disequilibria that arise due to kinetic barriers and can impart unexpected structure to an abiotic system. Many features of minerals and mineral assemblages may serve as biosignatures even if life does not have a familiar terrestrial chemical basis. Biological impacts on minerals and mineral assemblages may be direct or indirect. Crystalline or amorphous biominerals, an important category of mineralogical biosignatures, precipitate under direct cellular control as part of the life cycle of the organism (shells, tests, phytoliths) or indirectly when cell surface layers provide sites for heterogeneous nucleation. Biominerals also form indirectly as by-products of metabolism due to changing mineral solubility. Mineralogical biosignatures include distinctive mineral surface structures or chemistry that arise when dissolution and/or crystal growth kinetics are influenced by metabolic by-products. Mineral assemblages themselves may be diagnostic of the prior activity of organisms where barriers to precipitation or dissolution of specific phases have been overcome. Critical to resolving the question of whether life exists, or existed, on Mars is knowing how to distinguish biologically induced structure and organization patterns from inorganic phenomena and inorganic self-organization. This task assumes special significance when it is acknowledged that the majority of, and perhaps the only, material to be returned from Mars will be mineralogical.     

Economy of modular low-technology launch vehicles

The paper comprises an assessment of the design and the economics of so-called “low-cost” simple modular launch vehicles. It is shown that the performance is very marginal and that the cost per launch cannot compete with technically more advanced fully reusable vehicles. Especially a private-funded development cannot be amortized economically in case of an expendable launch vehicle.     

Gravitational Interaction of Celestial Bodies and neutron flux bursts from Their Surfaces

The gravitational interaction between the Sun and the planetary solar system gives rise to the well-known tidal waves at the planets. The tidal wave originating in the Earth's crust perpetually transforms the microstructure of the Earth's crust leading to a variation of the concentration of natural radioactive gases in the terrestrial air and to changed conditions of their leakage to the Earth's atmosphere. These variations give rise to bursts of thermal and slow neutrons in the vicinity of the Earth's crust, because the radioactive gases are sources of energetic alpha particles that induce neutron production upon the interaction with the nuclei of elements of the Earth's crust and atmosphere. In this work, the idea of neutron production in the ground coat is extended to the other celestial bodies interacting with one another.     

Dynamics and control of variable-geometry truss structures

Variable-geometry truss structures are likely to be used extensively in the future for in-orbit space construction. This paper considers dynamics formulation and vibration control of such structures. The truss system is modelled as a collection of sub-structures consisting of truss booms, prismatic actuator elements, and in some cases a manipulator at the end. Each truss boom is treated as a separate ‘link’ and its flexibility is modelled using the finite element method. Equations of motion for individual sub-structures are obtained which are then assembled. The non-working constraint forces are eliminated to obtain the equations governing the constrained dynamics of the entire system. For vibration control, the singular perturbation method is employed to construct two reduced-order models, for quasi-static motion and for modal co-ordinates, respectively. Computed torque with PD control is applied to maintain the quasi-static motion, while an optimal LQR method is used for vibration control. Typical simulation results are presented for the planar case.     

Production of neutrons from interactions of GCR-like particles

In order to help assess the risk to astronauts due to the long-term exposure to the natural radiation environment in space, an understanding of how the primary radiation field is changed when passing through shielding and tissue materials must be obtained. One important aspect of the change in the primary radiation field after passing through shielding materials is the production of secondary particles from the breakup of the primary. Neutrons are an important component of the secondary particle field due to their relatively high biological weighting factors, and due to their relative abundance, especially behind thick shielding scenarios. Because of the complexity of the problem, the estimation of the risk from exposure to the secondary neutron field must be handled using calculational techniques. However, those calculations will need an extensive set of neutron cross section and thicktarget neutron yield data in order to make an accurate assessment of the risk. In this paper we briefly survey the existing neutron-production data sets that are applicable to the space radiation transport problem, and we point out how neutron production from protons is different than neutron production from heavy ions. We also make comparisons of one the heavy-ion data sets with Boltzmann-Uehling-Uhlenbeck (BUU) calculations.     

Radial velocity search for low mass companions of nearby stars

The detection of substellar companions of nearby stars is very difficult, because these objects are very faint and are located close to their bright parent stars. One way to attack this problem is to look for small periodic motion of the bright star, induced by the gravitational attraction exerted by the unseen small companion. Over the past decade stellar spectroscopy has been used by a few teams to monitor the radial velocities of several samples of stars, with a threshold for detection of companions well below the substellar limit of about 0.08 M. So far, only a few possible spectroscopic binaries have been identified where the unseen companions might be substellar.Recently, radio observers discovered that the millisecond pulsar PSR B1257+12 displays periodic variations in the pulse arrival times, indicating the existence of at least three unseen companions in circular orbits around the pulsar. This is the first convincing case for an extra-solar planetary system. This discovery suggests that planetary systems can form in very different situations, and therefore may prove to be common.