Geochemistry of Carbonates on Mars: Implications for Climate History and Nature of Aqueous Environments

Ongoing research on martian meteorites and a new set of observations of carbonate minerals provided by an unprecedented series of robotic missions to Mars in the past 15 years help define new constraints on the history of martian climate with important crosscutting themes including: the CO₂ budget of Mars, the role of Mg-, Fe-rich fluids on Mars, and the interplay between carbonate formation and acidity. Carbonate minerals have now been identified in a wide range of localities on Mars as well as in several martian meteorites. The martian meteorites contain carbonates in low abundances (<1 vol.%) and with a wide range of chemistries. Carbonates have also been identified by remote sensing instruments on orbiting spacecraft in several surface locations as well as in low concentrations (2–5 wt.%) in the martian dust. The Spirit rover also identified an outcrop with 16 to 34 wt.% carbonate material in the Columbia Hills of Gusev Crater that strongly resembled the composition of carbonate found in martian meteorite ALH 84001. Finally, the Phoenix lander identified concentrations of 3–6 wt.% carbonate in the soils of the northern plains. The carbonates discovered to date do not clearly indicate the past presence of a dense Noachian atmosphere, but instead suggest localized hydrothermal aqueous environments with limited water availability that existed primarily in the early to mid-Noachian followed by low levels of carbonate formation from thin films of transient water from the late Noachian to the present. The prevalence of carbonate along with evidence for active carbonate precipitation suggests that a global acidic chemistry is unlikely and a more complex relationship between acidity and carbonate formation is present.     

Digisonde observations of TIDs with frequency and angular sounding technique

A technique for studying ionospheric wavelike phenomena, primarily AGW/TID events, is developed based on the solution of the problem of radio wave propagation in ionospheric plasma disturbed by wavelike processes. A perfectly reflecting surface model is used for representing TIDs propagating at ionospheric heights. This technique is a generalization of the Frequency-and-Angular Sounding (FAS) method developed earlier for oblique TID diagnostics using transmitters of opportunity. Trial measurements were made in November 2003 with two DPS-4 systems at Millstone Hill Observatory, providing experimental validation of the developed method by comparing the results of disturbance diagnostics to those simultaneously obtained with the original (oblique) FAS method. The TID parameters recovered during the November 2003 campaign suggest that the observed disturbances predominately propagated equatorward which likely indicates their sources to be in the auroral region. The equatorward propagating AGW/TIDs are typical for disturbed geomagnetic conditions which were observed during the campaign. Implementation of the generalized FAS technique in the DPS sounder allowed development of a dedicated data acquisition system for ionospheric disturbance diagnostics. Routine measurements with the developed technique using the existing world-wide network of Digisondes (GIRO) will make it possible to conduct large-scale studies of the AGW/TID phenomena.     

Thermoelastic problem for a physically orthotropic cylindrical shell at localized temperature

Numerical results obtained based on the equations for the general theory of physically orthotropic shells are presented. These results illustrate the influence of anisotropy for mechanical and physical characteristics of material on stressed state.     

Zinc-air batteries for forward field charging

In order to realize the operational and service cost savings through the use of rechargeable batteries, the dismounted soldier is burdened with the weight, volume and/or charging logistics of the batteries. By providing the soldier with a high energy density source and a lightweight compact battery charger, the burden imposed by rechargeable batteries in the forward field can be minimized. Zinc-air batteries have the potential for meeting the energy demands of forward battlefield charging. They are attitude insensitive, have a high specific energy and are inherently inexpensive, lightweight and safe     

Source processes in the high-latitude ionosphere

Space Science Reviews -     

Evaluation and modification of commercial infra-red transducers for leaf temperature measurement.

Accurate measurement of the leaf to air temperature gradient is crucial for the determination of stomatal conductance and other plant responses in both single leaves and in plant canopies. This gradient is often less than 1 degree C, which means that leaf temperature must be known to within about +/- 0.1 degree C. This is a challenging task, but new, miniature infra-red transducers from Exergen Corporation (Newton, MA) and Everest Interscience (Tucson, AZ) can be modified and calibrated to achieve this accuracy. The sensors must be modified to add thermal mass and the Exergen sensor requires a measurement of sensor body temperature. Significant error is caused by the discharge of a capacitor in the standard Exergen sensor, but we tested it without the capacitor. The sensors respond rapidly to changes in target temperature, but require 2 to 10 minutes to respond to changes in sensor body temperature, which is often the largest source of error. A new, sensitive method for measuring field of view indicates substantial peripheral vision for both sensors and a wider field of view than specified by the manufacturers. Here we describe sensor output as a function of target and sensor body temperatures, and provide a generic (sensor independent) equation that can be used to achieve +/- 0.2 C accuracy with Exergen sensors. The equation was developed and verified using two black body calibrators.     

Analytical solution of discrete colored noise ECA tracking filter

New analytical solutions of steady-state Kalman gains are presented for a discrete-time tracking filter with correlation in both the measurement noise and the target maneuver. The measurement noise model is a first-order discrete Markov process characterized by a correlation coefficient ρ. The target motion is examined for an exponentially correlated acceleration maneuver type in which the vehicle oscillation such as wind-induced-bending is also considered. The present solution method is based on factorizing the observed spectral density matrix Ψ(z) in frequency domain. The algorithm proposed here gives the Kalman gain matrix directly. For a case when the steady-state error covariance matrix is desired, such gains can be incorporated with the algebraic Riccati equation     

Lunar Exploration Neutron Detector for the NASA Lunar Reconnaissance Orbiter

The design of the Lunar Exploration Neutron Detector (LEND) experiment is presented, which was optimized to address several of the primary measurement requirements of NASA’s Lunar Reconnaissance Orbiter (LRO): high spatial resolution hydrogen mapping of the Moon’s upper-most surface, identification of putative deposits of appreciable near-surface water ice in the Moon’s polar cold traps, and characterization of the human-relevant space radiation environment in lunar orbit. A comprehensive program of LEND instrument physical calibrations is discussed and the baseline scenario of LEND observations from the primary LRO lunar orbit is presented. LEND data products will be useful for determining the next stages of the emerging global lunar exploration program, and they will facilitate the study of the physics of hydrogen implantation and diffusion in the regolith, test the presence of water ice deposits in lunar cold polar traps, and investigate the role of neutrons within the radiation environment of the shallow lunar surface.     

The Balloon Array for RBSP Relativistic Electron Losses (BARREL)

BARREL is a multiple-balloon investigation designed to study electron losses from Earth’s Radiation Belts. Selected as a NASA Living with a Star Mission of Opportunity, BARREL augments the Radiation Belt Storm Probes mission by providing measurements of relativistic electron precipitation with a pair of Antarctic balloon campaigns that will be conducted during the Austral summers (January-February) of 2013 and 2014. During each campaign, a total of 20 small (～20 kg) stratospheric balloons will be successively launched to maintain an array of ～5 payloads spread across ～6 hours of magnetic local time in the region that magnetically maps to the radiation belts. Each balloon carries an X-ray spectrometer to measure the bremsstrahlung X-rays produced by precipitating relativistic electrons as they collide with neutrals in the atmosphere, and a DC magnetometer to measure ULF-timescale variations of the magnetic field. BARREL will provide the first balloon measurements of relativistic electron precipitation while comprehensive in situ measurements of both plasma waves and energetic particles are available, and will characterize the spatial scale of precipitation at relativistic energies. All data and analysis software will be made freely available to the scientific community.