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621.
BAMO-THF叠氮型热塑性聚氨酯弹性体的合成与表征 总被引:1,自引:0,他引:1
为了研究叠氮型热塑性含能粘合剂的合成方法及反应条件对其力学性能的影响,通过熔融预聚二步法合成了以3,3-双(叠氮甲基)环氧丁烷-四氢呋喃共聚醚(BAMO-THF)为软段、异佛尔酮二异氰酸酯(IPDI)及1,4-丁二醇(BDO)为硬段的叠氮型热塑性聚氨酯弹性体(ATPE)。采用傅立叶变换红外光谱(FTIR)对所制备的ATPE的结构进行了表征。通过二正丁胺滴定法确定了最佳的预聚反应时间。研究比较了固化参数R和硬段含量对ATPE力学性能的影响。利用差示扫描量热(DSC)测定了ATPE的玻璃化转变温度,计算了硬段溶于软段的百分数。研究结果表明,所合成的ATPE具有典型的叠氮聚醚聚氨酯特征;确定了预聚反应时间为2 h;当R=1.02时,ATPE的拉伸强度最大,约为4 MPa;硬段含量为40%的ATPE的拉伸强度最大,为3.54 MPa;当硬段含量超过40%以后,硬段溶入软段的百分数小于10%,ATPE体现出良好的微相分离。 相似文献
622.
We investigate the behavior of mean values of the solar wind’s and interplanetary magnetic field’s (IMF) parameters and their
absolute and relative variations during the magnetic storms generated by various types of the solar wind. In this paper, which
is a continuation of paper [1], we, on the basis of the OMNI data archive for the period of 1976–2000, have analyzed 798 geomagnetic
storms with D
st
≤ −50 nT and their interplanetary sources: corotating interaction regions CIR, compression regions Sheath before the interplanetary
CMEs; magnetic clouds MC; “Pistons” Ejecta, and an uncertain type of a source. For the analysis the double superposed epoch
analysis method was used, in which the instants of the magnetic storm onset and the minimum of the D
st
index were taken as reference times. It is shown that the set of interplanetary sources of magnetic storms can be sub-divided
into two basic groups according to their slowly and fast varying characteristics: (1) ICME (MC and Ejecta) and (2) CIR and
Sheath. The mean values, the absolute and relative variations in MC and Ejecta for all parameters appeared to be either mean
or lower than the mean value (the mean values of the electric field E
y
and of the B
z
component of IMF are higher in absolute value), while in CIR and Sheath they are higher than the mean value. High values
of the relative density variation sN/〈N〉 are observed in MC. At the same time, the high values for relative variations of the velocity, B
z
component, and IMF magnitude are observed in Sheath and CIR. No noticeable distinctions in the relationships between considered
parameters for moderate and strong magnetic storms were observed. 相似文献
623.
The advantages of a constant volume combustion cycle as compared to constant pressure combustion in terms of thermodynamic efficiency has focused the search for advanced propulsion on detonation engines. Detonation of acetylene mixed with oxygen in various proportions is studied using mathematical modeling. Simplified kinetics of acetylene burning includes 11 reactions with 9 components. Deflagration to detonation transition (DDT) is obtained in a cylindrical tube with a section of obstacles modeling a Shchelkin spiral; the DDT takes place in this section for a wide range of initial mixture compositions. A modified ka-omega turbulence model is used to simulate flame acceleration in the Shchelkin spiral section of the system. The results of numerical simulations were compared with experiments, which had been performed in the same size detonation chamber and turbulent spiral ring section, and with theoretical data on the Chapman–Jouguet detonation parameters. 相似文献
624.
In this paper, the results of calculating the processes of two fuel mixture combustion in different proportions are presented.
The values of temperature, thermal capacity, specific gas constant and isentropic expansion ratio of combustion products are
given. Also shown is the distinction of thermodynamic properties from the additivity law. 相似文献
625.
626.
Current projects of manned missions to Mars are aimed to their realization in the second-third decades of this century. The purpose of this paper is to determine and review the main biomedical problems, that require a first and foremost decision for safety support of extravehicular activity (EVA) carried out by crewmembers of the Mars expedition. To a number of such problems the authors of the paper attribute a creation of adequate EVA equipment intended, first, for assembly of interplanetary spacecraft on the Earth orbit, performance of maintenance operations and scientific researches on the external surface of spacecraft during interplanetary flight and, secondly, for work on the Mars surface. New generation of space suits with low weight, high mobility and acceptable risk of decompression sickness must be as a central component of EVA equipment. The program for preparation to a Mars expedition also has to include special investigations in order to design the means and methods for a reliable protection of crew against space radiation, to elaborate the approach to medical monitoring and primary medical care during autonomous space mission, to maintain good health condition of crewmembers during EVA under the Mars gravity (0.38 g) after super long-term flight in weightlessness. 相似文献
627.
温度对液体中超声速度的影响 总被引:4,自引:0,他引:4
本文导出了超声波速度同液体压缩系数及密度关系,研究了压缩系数及密度与温度的关系,进而研究了温度对声速及声时的影响,用实验测量了不同的液体成份下的声时同温度的关系,从而提出了进行液体成份分析所必需的参量,对用超声波分析液体成份提供了理论依据,对提高产品质量及实现工业在线检测有一定的实用价值。 相似文献
628.
轴编C/C复合材料组分材料有效性能 总被引:2,自引:0,他引:2
利用光学显微镜观测和测量轴编C/C复合材料细观编织结构及其尺寸,建立轴编C/C复合材料有限元模型,通过给出组分材料有效性能的变化区间,构造组分材料性能与轴编C/C复合材料宏观有效性能的对应关系,利用径向基函数(RBF)人工神经网络(ANN)方法,对该高度非线性的对应关系进行训练,通过轴编C/C复合材料宏观实验结果,预报其组分材料的有效性能。结果表明,轴编C/C复合材料面内弹性性能基本相同,在测量时可忽略面内纤维束铺设方向的影响;人工神经网络对训练样本有一定的依赖性,但通过多次随机构造样本训练网络,可得到理想的预测结果,且人工神经网络方法具有很好的容错性,能很好地预报轴编C/C复合材料组分材料的有效性能。 相似文献
629.
630.