Preliminary calibration results of VEGA 1 and 2 SIGMA-3 gas chromatograph

SIGMA - 3 gas chromatograph on board VEGA 1 and 2 landing probes has been operated successfully in the 60 - 50 km altitude range, providing several in - situ chemical analysis of the gas and the aerosols of Venus cloud layers. Post flight calibration required to derive atmospheric abundancies from gas chromatograms were carried out using the SIGMA - 3 spare model. A Venus atmospheric aerosol simulation chamber was used in which sulfuric acid droplets were generated. Preliminary results of these calibration experiments indicate that the concentration of sulfuric acid in the upper part of the clouds ( 60 to 55 km) is about 1 mg/m³ and suggest that an additional constituant must be present in noticeable amount in the aerosols. From these experiments the mixing ratio upper limits of SO₂ is 100 ppmV and of H₂S and COS is few 10 ppmV.     

Influences of Form and Function on the Acceptability of Projective Prepositions in Swedish

Abstract

Projective prepositions express the relation between two objects by referring to a direction in space and have traditionally been regarded as expressing purely geometric relations. Recent studies have shown that the appropriateness of English and Spanish projectives also depends on functional relations between objects. This study investigates if the acceptability of the Swedish projectives över, under, ovanför and nedanför are influenced by functional factors as well, and whether över and under are differentially influenced by function than ovanför and nedanför, as has been shown for their English cognates. It also investigates how the shape and parts of the related objects influence their functional interaction, and thereby the acceptability of the prepositions. This is done with respect to the predictions of the AVS-model, a model of the perceptual processes underlying the apprehension of projectives, which takes both the geometric and the functional relation between objects into account. It was found that acceptability judgments about the prepositions are influenced by function as their corresponding English and Spanish prepositions. The acceptability of över was more sensitive to function than ovanför, whereas under and nedanför were not differentially influenced by function, as has been shown for Spanish. It was further found that the shape and parts of both of the related objects influence acceptability regions associated with the prepositions in predictable ways, as functional interactions between objects largely depend on their parts. The results finally show that the AVS-model needs to be further developed in order to account for the form and function of the located object.     

Mercury’s Weather-Beaten Surface: Understanding Mercury in the Context of Lunar and Asteroidal Space Weathering Studies

Mercury’s regolith, derived from the crustal bedrock, has been altered by a set of space weathering processes. Before we can interpret crustal composition, it is necessary to understand the nature of these surface alterations. The processes that space weather the surface are the same as those that form Mercury’s exosphere (micrometeoroid flux and solar wind interactions) and are moderated by the local space environment and the presence of a global magnetic field. To comprehend how space weathering acts on Mercury’s regolith, an understanding is needed of how contributing processes act as an interactive system. As no direct information (e.g., from returned samples) is available about how the system of space weathering affects Mercury’s regolith, we use as a basis for comparison the current understanding of these same processes on lunar and asteroidal regoliths as well as laboratory simulations. These comparisons suggest that Mercury’s regolith is overturned more frequently (though the characteristic surface time for a grain is unknown even relative to the lunar case), more than an order of magnitude more melt and vapor per unit time and unit area is produced by impact processes than on the Moon (creating a higher glass content via grain coatings and agglutinates), the degree of surface irradiation is comparable to or greater than that on the Moon, and photon irradiation is up to an order of magnitude greater (creating amorphous grain rims, chemically reducing the upper layers of grains to produce nanometer-scale particles of metallic iron, and depleting surface grains in volatile elements and alkali metals). The processes that chemically reduce the surface and produce nanometer-scale particles on Mercury are suggested to be more effective than similar processes on the Moon. Estimated abundances of nanometer-scale particles can account for Mercury’s dark surface relative to that of the Moon without requiring macroscopic grains of opaque minerals. The presence of nanometer-scale particles may also account for Mercury’s relatively featureless visible–near-infrared reflectance spectra. Characteristics of material returned from asteroid 25143 Itokawa demonstrate that this nanometer-scale material need not be pure iron, raising the possibility that the nanometer-scale material on Mercury may have a composition different from iron metal [such as (Fe,Mg)S]. The expected depletion of volatiles and particularly alkali metals from solar-wind interaction processes are inconsistent with the detection of sodium, potassium, and sulfur within the regolith. One plausible explanation invokes a larger fine fraction (grain size <45 μm) and more radiation-damaged grains than in the lunar surface material to create a regolith that is a more efficient reservoir for these volatiles. By this view the volatile elements detected are present not only within the grain structures, but also as adsorbates within the regolith and deposits on the surfaces of the regolith grains. The comparisons with findings from the Moon and asteroids provide a basis for predicting how compositional modifications induced by space weathering have affected Mercury’s surface composition.     

Surface Composition of Vesta: Issues and Integrated Approach

The instruments on the Dawn spacecraft are exceptionally well suited to characterize and map the surface composition of Vesta in an integrated manner. These include a framing camera with multispectral capabilities, a high spectral resolution near-infrared imaging spectrometer, and a gamma-ray and neutron spectrometer. Three examples of issues addressed at Vesta are: (1) What is the composition of Vesta??s interior and differentiation state as exposed by the Great South Crater? (2) How has space weathering affected Vesta, both globally and at a local scale? and (3) Are volatiles or hydrated material present on Vesta??s surface? We predict that Dawn finds many surprises, such as an olivine-bearing mantle exposed near the south-pole, a weakly or un-weathered surface that has been relatively recently resurfaced, and a very thin layer of surficial volatiles derived from interaction with the solar wind.     

Structural health management technologies for inflatable/deployable structures: Integrating sensing and self-healing

Inflatable/deployable structures are under consideration as habitats for future Lunar surface science operations. The use of non-traditional structural materials combined with the need to maintain a safe working environment for extended periods in a harsh environment has led to the consideration of an integrated structural health management system for future habitats, to ensure their integrity. This article describes recent efforts to develop prototype sensing technologies and new self-healing materials that address the unique requirements of habitats comprised mainly of soft goods. A new approach to detecting impact damage is discussed, using addressable flexible capacitive sensing elements and thin film electronics in a matrixed array. Also, the use of passive wireless sensor tags for distributed sensing is discussed, wherein the need for on-board power through batteries or hardwired interconnects is eliminated. Finally, the development of a novel, microencapuslated self-healing elastomer with applications for inflatable/deployable habitats is reviewed.     

On the Optimum Design of PCM Signals with System Constraints

This paper considers the design of PCM signals with system constraints using Pontryagin's maximum principle. The transmitter signal as well as the correlation signal are determined while maximizing the output signal-to-noise ratio. Both the single and three-pole transmitter filters are considered. An upper bound has been obtained on the performance of PCM signals with constraints.     

Magnetospheric Models and Trajectory Computations

The calculation of particle trajectories in the Earth's magnetic field has been a subject of interest since the time of Störmer. The fundamental problem is that the trajectory-tracing process involves using mathematical equations that have `no solution in closed form'. This difficulty has forced researchers to use the `brute force' technique of numerical integration of many individual trajectories to ascertain the behavior of trajectory families or groups. As the power of computers has improved over the decades, the numerical integration procedure has grown more tractable and while the problem is still formidable, thousands of trajectories can be computed without the expenditure of excessive resources. As particle trajectories are computed and the characteristics analyzed we can determine the cutoff rigidity of a specific location and viewing direction and direction and deduce the direction in space of various cosmic ray anisotropies. Unfortunately, cutoff rigidities are not simple parameters due to the chaotic behavior of the cosmic-ray trajectories in the cosmic ray penumbral region. As the computational problem becomes more manageable, there is still the issue of the accuracy of the magnetic field models. Over the decades, magnetic field models of increasing complexity have been developed and utilized. The accuracy of trajectory calculations employing contemporary magnetic field models is sufficient that cosmic ray experiments can be designed on the basis of trajectory calculations. However, the Earth's magnetosphere is dynamic and the most widely used magnetospheric models currently available are static. This means that the greatest uncertainly in the application of charged particle trajectories occurs at low energies.     

X-ray induced alterations in the differentiation and mineralization potential of murine preosteoblastic cells

To evaluate the effects of ionizing radiation (IR) on murine preosteoblastic cell differentiation, we directed OCT-1 cells to the osteoblastic lineage by treatment with a combination of β-glycerophosphate (β-GP), ascorbic acid (AA), and dexamethasone (Dex). In vitro mineralization was evaluated based on histochemical staining and quantification of the hydroxyapatite content of the extracellular bone matrix. Expression of mRNA encoding Runx2, transforming growth factor β1 (TGF-β1), osteocalcin (OCN), and p21^CDKN1A was analyzed. Exposure to IR reduced the growth rate and diminished cell survival of OCT-1 cells under standard conditions. Notably, calcium content analysis revealed that deposition of mineralized matrix increased significantly under osteogenic conditions after X-ray exposure in a time-dependent manner. In this study, higher radiation doses exert significant overall effects on TGF-β1, OCN, and p21^CDKN1A gene expression, suggesting that gene expression following X-ray treatment is affected in a dose-dependent manner. Additionally, we verified that Runx2 was suppressed within 24 h after irradiation at 2 and 4 Gy. Although further studies are required to verify the molecular mechanism, our observations strongly suggest that treatment with IR markedly alters the differentiation and mineralization process of preosteoblastic cells.     

Ceres: Its Origin, Evolution and Structure and Dawn��s Potential Contribution

Ceres appears likely to be differentiated and to have experienced planetary evolution processes. This conclusion is based on current geophysical observations and thermodynamic modeling of Ceres?? evolution. This makes Ceres similar to a small planet, and in fact it is thought to represent a class of objects from which the inner planets formed. Verification of Ceres?? state and understanding of the many steps in achieving it remains a major goal. The Dawn spacecraft and its instrument package are on a mission to observe Ceres from orbit. Observations and potential results are suggested here, based on number of science questions.     

On The 53Mn Heterogeneity In The Early Solar System

It is well established that the prolonged and thorough mixing of numerous nucleosynthetic components that constitutes the matter in the solar nebula resulted in an essential isotopic homogeneity of the solar system material. This may or may not be true for the short-lived radionuclides which were injected into or formed within the solar nebula just prior to or during solar system formation. Distinguishing between their heterogeneous or homogeneous distribution is important because the short- lived radionuclides are now widely used for the relative chronology of various objects and processes in the early solar system and as constraints for models of nucleosynthesis. The recent studies of the ⁵³Mn-⁵³Cr isotope system (half life of ⁵³Mn is 3.7 Ma) in various solar system objects have shown that the relative abundance of radiogenic ⁵³Cr is consistent with essentially homogeneous distribution of ⁵³Mn in the asteroid belt. Thus, the relative ⁵³Mn-⁵³Cr chronometer can be directly used for dating samples which originated in the asteroid belt. Importantly, however, all meteorite groups studied so far indicate a clear excess of ⁵³Cr as compared to Earth and to a lunar sample, which exhibits also a terrestrial ⁵³Cr/⁵²Cr ratio. The results from the Martian (SNC) meteorites show that their ⁵³Cr excesses are less than half of those found in the asteroid belt bodies. Thus, the characteristic ⁵³Cr/⁵²Cr ratio of Mars is intermediate between that of the Earth-Moon system and those of the other meteorites. If these ⁵³Cr variations are viewed as a function of the heliocentric distance, the radial dependence of the relative abundances of radiogenic ⁵³Cr is indicated. This observed gradient can be explained by either an early, volatility controlled, Mn/Cr fractionation within the nebula or by an initial radial heterogeneous distribution of ⁵³Mn. Although model calculations of the Mn/Cr ratios in the bulk terrestrial planets seem to be inconsistent with the volatility driven scenario, the precision of these calculations is inadequate for eliminating this possibility. In contrast, recent studies of the ⁵³Mn-⁵³Cr system in the enstatite chondrites indicate that, while their bulk Mn/Cr ratios are essentially the same as in ordinary chondrites, the ⁵³Cr excess in bulk enstatite chondrites is three times lower than that in the bulk ordinary chondrites. This difference cannot be explained by a Mn/Cr fractionation and, thus, strongly suggests that a radial heterogeneous distribution of ⁵³Mn must have existed in at least the early inner solar system. Using the observed gradient and the ⁵³Cr/⁵²Cr ratio of the bulk enstatite chondrites, their parent body(ies) formed at ∼1.4 AU or somewhat closer to the Sun. This revised version was published online in June 2006 with corrections to the Cover Date.