Geochemical Consequences of Widespread Clay Mineral Formation in Mars’ Ancient Crust

Clays form on Earth by near-surface weathering, precipitation in water bodies within basins, hydrothermal alteration (volcanic- or impact-induced), diagenesis, metamorphism, and magmatic precipitation. Diverse clay minerals have been detected from orbital investigation of terrains on Mars and are globally distributed, indicating geographically widespread aqueous alteration. Clay assemblages within deep stratigraphic units in the Martian crust include Fe/Mg smectites, chlorites and higher temperature hydrated silicates. Sedimentary clay mineral assemblages include Fe/Mg smectites, kaolinite, and sulfate, carbonate, and chloride salts. Stratigraphic sequences with multiple clay-bearing units have an upper unit with Al-clays and a lower unit with Fe/Mg-clays. The typical restriction of clay minerals to the oldest, Noachian terrains indicates a distinctive set of processes involving water-rock interaction that was prevalent early in Mars history and may have profoundly influenced the evolution of Martian geochemical systems. Current analyses of orbital data have led to the proposition of multiple clay-formation mechanisms, varying in space and time in their relative importance. These include near-surface weathering, formation in ice-dominated near-surface groundwaters, and formation by subsurface hydrothermal fluids. Near-surface, open system formation of clays would lead to fractionation of Mars’ crustal reservoir into an altered crustal reservoir and a sedimentary reservoir, potentially involving changes in the composition of Mars’ atmosphere. In contrast, formation of clays in the subsurface by either aqueous alteration or magmatic cooling would result in comparatively little geochemical fractionation or interaction of Mars’ atmospheric, crustal, and magmatic reservoirs, with the exception of long-term sequestration of water. Formation of clays within ice would have geochemical consequences intermediate between these endmembers. We outline the future analyses of orbital data, in situ measurements acquired within clay-bearing terrains, and analyses of Mars samples that are needed to more fully elucidate the mechanisms of martian clay formation and to determine the consequences for the geochemical evolution of the planet.     

The Genesis Solar Wind Concentrator: Flight and Post-Flight Conditions and Modeling of Instrumental Fractionation

The Genesis mission Solar Wind Concentrator was built to enhance fluences of solar wind by an average of 20x over the 2.3 years that the mission exposed substrates to the solar wind. The Concentrator targets survived the hard landing upon return to Earth and were used to determine the isotopic composition of solar-wind—and hence solar—oxygen and nitrogen. Here we report on the flight operation of the instrument and on simulations of its performance. Concentration and fractionation patterns obtained from simulations are given for He, Li, N, O, Ne, Mg, Si, S, and Ar in SiC targets, and are compared with measured concentrations and isotope ratios for the noble gases. Carbon is also modeled for a Si target. Predicted differences in instrumental fractionation between elements are discussed. Additionally, as the Concentrator was designed only for ions ≤22 AMU, implications of analyzing elements as heavy as argon are discussed. Post-flight simulations of instrumental fractionation as a function of radial position on the targets incorporate solar-wind velocity and angular distributions measured in flight, and predict fractionation patterns for various elements and isotopes of interest. A tighter angular distribution, mostly due to better spacecraft spin stability than assumed in pre-flight modeling, results in a steeper isotopic fractionation gradient between the center and the perimeter of the targets. Using the distribution of solar-wind velocities encountered during flight, which are higher than those used in pre-flight modeling, results in elemental abundance patterns slightly less peaked at the center. Mean fractionations trend with atomic mass, with differences relative to the measured isotopes of neon of +4.1±0.9 ‰/amu for Li, between ?0.4 and +2.8 ‰/amu for C, +1.9±0.7‰/amu for N, +1.3±0.4 ‰/amu for O, ?7.5±0.4 ‰/amu for Mg, ?8.9±0.6 ‰/amu for Si, and ?22.0±0.7 ‰/amu for S (uncertainties reflect Monte Carlo statistics). The slopes of the fractionation trends depend to first order only on the relative differential mass ratio, Δm/m. This article and a companion paper (Reisenfeld et al. 2012, this issue) provide post-flight information necessary for the analysis of the Genesis solar wind samples, and thus serve to complement the Space Science Review volume, The Genesis Mission (v. 105, 2003).     

Statistical properties of the IMF clock angle in the solar wind with northward and southward interplanetary magnetic field based on ACE observation from 1998 to 2009: Dependence on the temporal scale of the solar wind

Utilizing ACE satellite observations from 1998 to 2009, we performed the elaborate study on the properties of the clock angle θ_CA (arctan(By/Bz) (?90° to 90°) of the interplanetary magnetic field (IMF) in the solar wind at 1?AU. The solar wind with northward IMF (NW-IMF) and southward IMF (SW-IMF) are analyzed, independently. Statistical analysis shows that the solar wind with SW-IMF and NW-IMF has similar properties in general, including their durations, the IMF Bz and By components, and the IMF θ_CA. Then, the solar wind with NW-IMF (SW-IMF) is classified into five different temporal scales according to the duration of the NW-IMF (SW-IMF), i.e., very-short wind of 10–30?min, short-scale wind of 0.5–1?h, moderate-scale wind of 1–3?h, long-scale wind of 3–5?h, and super-long wind >5?h. Our analysis reveals that the IMF θ_CA has a distinct decrease with increase of the temporal scale of the solar wind. Next, the solar wind is classified into two groups, i.e., the high-speed solar wind (>450?km/s) and the low-speed solar wind (<450?km/s). Our analysis indicates that the IMF θ_CA depends highly on the solar wind speed. Statistically, high-speed solar wind tends to have larger IMF θ_CA than low-speed solar wind. The evolutions of the solar wind and IMF with the solar activity are further studied, revealing no clear solar variation of the IMF θ_CA. Finally, we analyze the monthly variation of the IMF θ_CA. Superposed epoch result strongly suggests the seasonal variation of the IMF θ_CA.     

Effects observed in the equatorial and low latitude ionospheric F-region in the Brazilian sector during low solar activity geomagnetic storms and comparison with the COSMIC measurements

The main objective of the present investigation has been to compare the ionospheric parameters (NmF2 and hmF2) observed by two ground-based ionospheric sounders (one at PALMAS- located near the magnetic equator and the other at Sao Jose dos Campos-located in the low-latitude region) in the Brazilian sector with that by the satellite FORMOSAT-3/COSMIC radio occultation (RO) measurements during two geomagnetic storms which occurred in December 2006 and July 2009. It should be pointed out that in spite of increasing the latitude (to 10°) and longitude (to 20°) around the stations; we had very few common observations. It has been observed that both the peak electron density (NmF2) and peak height (hmF2) observed by two different techniques (space-borne COSMIC and ground-based ionosondes) during both the geomagnetic storm events compares fairly well (with high correlation coefficients) at the two stations in the Brazilian sector. It should be pointed out that due to equatorial spread F (ESF) in the first storm (December 2006) and no-reflections from the ionosphere during nighttime in the second storm (July 2009), we had virtually daytime data from the two ionosondes.     

Is there an instrumental drift in the counting rate of some high latitude neutron monitors?

For the last six decades the neutron monitors have provided a continuous string of very reliable data to the heliophysics community. Although neutron monitors are not the primary source of data for the galactic cosmic rays, these data serve as a baseline reference for the data collected by the detectors on board the satellites and deep space probes, far away from earth orbit. The pressure corrected hourly data are available from the World Data Centers. These data have been used to derive deep insights pertaining to the electromagnetic states of the heliosphere and the modes of transport of energetic charged particles in the tangled interplanetary magnetic fields. We present evidence that some of the high latitude neutron monitors are undergoing long-term drifts in their baselines. In particular, we argue that there is no physical basis to justify the observed long-term downward trend in the baseline of the South Pole neutron monitor. The real reason may have to do with its maintenance at a distant location with challenging logistics and an improper normalization of its data after the 26 months break in the 1970s.     

Computational methods for the HZETRN code.

Asymptotic expansion has been used to simplify the transport of high charge and energy ions for broad beam applications in the laboratory and space. The solution of the lowest order asymptotic term is then related to a Green's function for energy loss and straggling coupled to nuclear attenuation providing the lowest order term in a rapidly converging Neumann series for which higher order collisions terms are related to the fragmentation events including energy dispersion and downshift. The first and second Neumann corrections were evaluated numerically as a standard for further analytic approximation. The first Neumann correction is accurately evaluated over the saddle point whose width is determined by the energy dispersion and located at the downshifted ion collision energy. Introduction of the first Neumann correction leads to significant simplification of the second correction term allowing application of the mean value theorem and a second saddle point approximation. The regular dependence of the second correction spectral dependence lends hope to simple approximation to higher corrections. At sufficiently high energy nuclear cross-section variations are small allowing non-perturbative methods to all orders and renormalization of the second corrections allow accurate evaluation of the full Neumann series.