The reactions of nitrogen heterocycles with acrolein: scope and prebiotic significance

It has been suggested that life began with a self-replicating RNA molecule. However, after much research into the prebiotic synthesis of RNA, the difficulties encountered have lead some to hypothesize that RNA was preceded by a simpler molecule, one more easily synthesized prebiotically. Many of the proposed alternative molecules are based on acrolein, since it reacts readily with nucleophiles, such as the nucleobases, via Michael addition and is readily synthesized from formaldehyde and acetaldehyde. Reports regarding the reactions of nucleobases with concentrated acrolein solutions suggest that this is a plausible reaction mechanism, though there are also reports that the "incorrect" isomers are obtained. The scope and kinetics of the reaction of acrolein with various nitrogen heterocycles are reported here. Reactions of pyrimidines often give N(1) adducts as the major products. Reactions of purines often give N(9) adducts in good yield. The reactions are rapid under neutral to slightly alkaline conditions, and proceed at low temperatures and dilutions. The implications of these findings for the origin of life are discussed.     

Certain approaches to the development of on-board automated training system

Perspectives of long-term space programs make it necessary to develop autonomous computer expert system for crew-members physical state control. The purpose of the work--to develop a set of objective formalizable physiological indices of working capacity suitable for reliable algorithmization of physical state control. Investigations were performed in on-earth microgravity simulation (3- and 7-day dry immersion, 6 subjects; 4-month antiorthostatic hypokinesy, 10 subjects) with volunteers' participation as well with 34 members of MIR-station expeditions during flights. Model exercise investigations were made also with 20 young male volunteers to evaluate the validity of different physical state indices. A set of indices was found which, being simple enough for measuring, performs to get satisfactory adequate evaluations of current organism physical state in long-term real or simulated microgravity. It was proved that some ergometric indices along with heart rate derivatives could reflect real working ability even better than traditional characteristics of organism energy systems state.     

Gated Phase-Locked Loop Study

The objectives of this paper are threefold. The first is to obtain a sampled data model of a gated phase-locked loop. Data from measurements made on an actual loop constructed in the laboratory are included, and the good agreement between measured and calculated results serves as a verification of the model. Second, with the aid of the model, some of the basic operating properties of the system will be presented. Third, comparisons will be made between gated and continuous loop operation.     

Modeling and simulation of spacecraft power systems

Modeling of a complete spacecraft power processing system is presented, using the Boeing EASYS software. Component models are developed, and several system models including a solar array switching system, a partially shunted solar system, and cosmic background explorer (COBE) system are simulated. The modes of operation of the power system, such as shunt mode, battery-charge mode, and battery-discharge mode, are simulated for a complete orbit cycle     

Probability Density of the Maximum Likelihood Elevation Estimate of Radar Targets

The probability density of the maximum likelihood estimate of elevation angle of a radar target in the presence of multipath is calculated. For detectable signals that have low signal-to-noise ratios, the density is a mixture of a Gaussian density and a delta function at the horizon.     

Cold resistance and metabolic activity of lichens below 0°C

Laboratory measurements show that lichens are extremely tolerant of freezing stress and of low-temperature exposure. Metabolic activity recovered quickly after severe and extended cold treatment. Experimental results demonstrate also that CO₂ exchange is already active at around −20°C. The psychrophilic character of polar lichen species is demonstrated by optimum temperatures for net photosynthesis between 0 and 15°C. In situ measurements show that lichens begin photosynthesizing below 0°C if the dry thalli receive fresh snow. The lowest temperature measured in active lichens was −17°C at a continental Antarctic site. The fine structure and the hydration state of photobiont and mycobiont cells were studied by low-temperature scanning electron microscopy (LTSEM) of frozen hydrated specimens. Water potentials of the frozen system are in the range of or even higher than those allowing dry lichens to start photosynthesis by water vapor uptake at +10°C. The great success of lichens in polar and high alpine regions gives evidence of their physiological adaptation to low temperatures. In general lichens are able to persist through glacial periods, but extended snow cover and glaciation are limiting factors.     

铁基航空合金的新要求

进入新世纪,民用与军用飞机合金的选择设计标准发生了巨大变化。过去的设计标准主张追求更高、更快和更远的目标而不计成本,已不适应时代的发展。新的设计要求包括:一是减少瑕疵、增加使用寿命和降低维修和飞行成本;二是寻求更廉价的零件与部件,以降低产品生命周期成本;三是对更环保的“绿色”部件的需求,如淘汰需要以铬和镉进行表面处理的部件。这些要求使得H-11和300M等一些标准合金失宠,尽管这些合金异常坚硬,但却易产生应力腐蚀断裂。本文介绍了五种新型合金,这五种合金具有延长使用寿命和降低寿命周期成本的优点。它们可用作曾用于起…     

The Voyager infrared spectroscopy and radiometry investigation

The infrared investigation on Voyager uses two interferometers covering the spectral ranges 60–600 cm^–1 (17–170 m) and 1000–7000 cm^–1 (1.4–10 m), and a radiometer covering the range 8000–25 000 cm^–1 (0.4–1.2 m). Two spectral resolutions (approximately 6.5 and 2.0 cm^–1) are available for each of the interferometers. In the middle of the thermal channel (far infrared interferometer) the noise level is equivalent to the signal from a target at 50 K; in the middle of the reflected sunlight channel (near infrared interferometer) the noise level is equivalent to the signal from an object of albedo 0.2 at the distance of Uranus.For planets and satellites with substantial atmospheres, the data will be used to investigate cloud and gas composition (including isotopic ratios), haze scale height, atmospheric vertical thermal structure, local and planetary circulation and dynamics, and planetary energy balance. For satellites with tenuous atmospheres, data will be gathered on surface and atmospheric composition, surface temperature and thermal properties, local and global phase functions, and surface structure. For Saturn's rings, the composition and radial structure, particle size and thermal characteristics will be investigated. Comparative studies of the planets and their satellite systems will be carried out.Paris Observatory.Cornell University.Jet Propulsion Laboratory.University of Maryland.     

Observations of substorm-associated particle-flux variations at 6⩽L⩽8 with GEOS-1

Measurements made with the charged particle spectrometer of the Max-Planck-Institut für Aeronomie onboard GEOS-1 were used to investigate the behaviour of energetic electrons and ions in the dusk sector of the magnetosphere. During substorms the integral ion flux ( 24 KeV) increased whereas the integral electron flux ( 20 KeV) first decreased and later on also increased. The dependences of these flux variations on pitch-angle and particle energy are described and discussed in terms of particle drift in the geomagnetic and geoelectric fields and adiabatic energy variations. The results also provide some information on the source region of the drifting particles.     

The elemental composition in energetic particle events at high heliospheric latitudes

The relative abundances of low energy ions (0.6–2.0 MeV/n) in solar energetic particle (SEP) and corotating interaction region (CIR) events have been measured by the EPAC experiment aboard Ulysses since launch in October 1990 until the present time. We give an overview of the abundances of heavy ions (He, C, Ne, Fe) relative to oxygen during energetic particle events lasting longer than 5 days during the in- and out-of-ecliptic phase of the mission. While the period Oct. 1990 to Aug. 1992 was dominated by high solar activity the Ulysses out of ecliptic passage at solar latitudes up to 45° went parallel to the declining phase of solar activity. Thus a very clear structure of corotating interaction regions was observed. While the in-ecliptic composition is in general agreement with measurements made near the Earth, the development of the CIR-composition shows two phases: From Aug. 1992 to May 1993 the C/O-ratio is 0.55–0.70, afterwards it increases to 0.8–0.9. This increase is correlated to the disappearance of the current sheet at 30° solar latitude reported by Smithet al. (1993).