Molecular Biosignatures

Life, as we know it, is based on carbon chemistry operating in an aqueous environment. Living organisms process chemicals, make copies of themselves, are autonomous and evolve in concert with the environment. All these characteristics are driven by, and operate through, carbon chemistry. The carbon chemistry of living systems is an exact branch of science and we have detailed knowledge of the basic metabolic and reproductive machinery of living organisms. We can recognise the residual biochemicals long after life has expired and otherwise lost most life-defining features. Carbon chemistry provides a tool for identifying extant and extinct life on Earth and, potentially, throughout the Universe. In recognizing that certain distinctive compounds isolable from living systems had related fossil derivatives, organic geochemists coined the term biological marker compound or biomarker (e.g. Eglinton et al. in Science 145:263–264, 1964) to describe them. In this terminology, biomarkers are metabolites or biochemicals by which we can identify particular kinds of living organisms as well as the molecular fossil derivatives by which we identify defunct counterparts. The terms biomarker and molecular biosignature are synonymous. A defining characteristic of terrestrial life is its metabolic versatility and adaptability and it is reasonable to expect that this is universal. Different physiologies operate for carbon acquisition, the garnering of energy and the storage and processing of information. As well as having a range of metabolisms, organisms build biomass suited to specific physical environments, habitats and their ecological imperatives. This overall ‘metabolic diversity’ manifests itself in an enormous variety of accompanying product molecules (i.e. natural products). The whole field of organic chemistry grew from their study and now provides tools to link metabolism (i.e. physiology) to the occurrence of biomarkers specific to, and diagnostic for, particular kinds of metabolism. Another characteristic of living things, also likely to be pervasive, is that an enormous diversity of large molecules are built from a relatively small subset of universal precursors. These include the four bases of DNA, 20 amino acids of proteins and two kinds of lipid building blocks. Third, life exploits the specificity inherent in the spatial, that is, the three-dimensional qualities of organic chemicals (stereochemistry). These characteristics then lead to some readily identifiable and measurable generic attributes that would be diagnostic as biosignatures. Measurable attributes of molecular biosignatures include:

1. Enantiomeric excess
2. Diastereoisomeric preference
3. Structural isomer preference
4. Repeating constitutional sub-units or atomic ratios
5. Systematic isotopic ordering at molecular and intramolecular levels
6. Uneven distribution patterns or clusters (e.g. C-number, concentration, δ ¹³C) of structurally related compounds.

In this paper we address details of the chemical and biosynthetic basis for these features, which largely arise as a consequence of construction from small, recurring sub-units. We also address how these attributes might become altered during diagenesis and planetary processing. Finally, we discuss the instrumental techniques and further developments needed to detect them.     

Mars Science Laboratory Mission and Science Investigation

Scheduled to land in August of 2012, the Mars Science Laboratory (MSL) Mission was initiated to explore the habitability of Mars. This includes both modern environments as well as ancient environments recorded by the stratigraphic rock record preserved at the Gale crater landing site. The Curiosity rover has a designed lifetime of at least one Mars year (～23?months), and drive capability of at least 20?km. Curiosity’s science payload was specifically assembled to assess habitability and includes a gas chromatograph-mass spectrometer and gas analyzer that will search for organic carbon in rocks, regolith fines, and the atmosphere (SAM instrument); an x-ray diffractometer that will determine mineralogical diversity (CheMin instrument); focusable cameras that can image landscapes and rock/regolith textures in natural color (MAHLI, MARDI, and Mastcam instruments); an alpha-particle x-ray spectrometer for in situ determination of rock and soil chemistry (APXS instrument); a?laser-induced breakdown spectrometer to remotely sense the chemical composition of rocks and minerals (ChemCam instrument); an active neutron spectrometer designed to search for water in rocks/regolith (DAN instrument); a weather station to measure modern-day environmental variables (REMS instrument); and a sensor designed for continuous monitoring of background solar and cosmic radiation (RAD instrument). The various payload elements will work together to detect and study potential sampling targets with remote and in situ measurements; to acquire samples of rock, soil, and atmosphere and analyze them in onboard analytical instruments; and to observe the environment around the rover. The 155-km diameter Gale crater was chosen as Curiosity’s field site based on several attributes: an interior mountain of ancient flat-lying strata extending almost 5?km above the elevation of the landing site; the lower few hundred meters of the mountain show a progression with relative age from clay-bearing to sulfate-bearing strata, separated by an unconformity from overlying likely anhydrous strata; the landing ellipse is characterized by a mixture of alluvial fan and high thermal inertia/high albedo stratified deposits; and a number of stratigraphically/geomorphically distinct fluvial features. Samples of the crater wall and rim rock, and more recent to currently active surface materials also may be studied. Gale has a well-defined regional context and strong evidence for a progression through multiple potentially habitable environments. These environments are represented by a stratigraphic record of extraordinary extent, and insure preservation of a rich record of the environmental history of early Mars. The interior mountain of Gale Crater has been informally designated at Mount Sharp, in honor of the pioneering planetary scientist Robert Sharp. The major subsystems of the MSL Project consist of a single rover (with science payload), a Multi-Mission Radioisotope Thermoelectric Generator, an Earth-Mars cruise stage, an entry, descent, and landing system, a launch vehicle, and the mission operations and ground data systems. The primary communication path for downlink is relay through the Mars Reconnaissance Orbiter. The primary path for uplink to the rover is Direct-from-Earth. The secondary paths for downlink are Direct-to-Earth and relay through the Mars Odyssey orbiter. Curiosity is a scaled version of the 6-wheel drive, 4-wheel steering, rocker bogie system from the Mars Exploration Rovers (MER) Spirit and Opportunity and the Mars Pathfinder Sojourner. Like Spirit and Opportunity, Curiosity offers three primary modes of navigation: blind-drive, visual odometry, and visual odometry with hazard avoidance. Creation of terrain maps based on HiRISE (High Resolution Imaging Science Experiment) and other remote sensing data were used to conduct simulated driving with Curiosity in these various modes, and allowed selection of the Gale crater landing site which requires climbing the base of a mountain to achieve its primary science goals. The Sample Acquisition, Processing, and Handling (SA/SPaH) subsystem is responsible for the acquisition of rock and soil samples from the Martian surface and the processing of these samples into fine particles that are then distributed to the analytical science instruments. The SA/SPaH subsystem is also responsible for the placement of the two contact instruments (APXS, MAHLI) on rock and soil targets. SA/SPaH consists of a robotic arm and turret-mounted devices on the end of the arm, which include a drill, brush, soil scoop, sample processing device, and the mechanical and electrical interfaces to the two contact science instruments. SA/SPaH also includes drill bit boxes, the organic check material, and an observation tray, which are all mounted on the front of the rover, and inlet cover mechanisms that are placed over the SAM and CheMin solid sample inlet tubes on the rover top deck.     

Medium-scale traveling ionospheric disturbances (MSTID) modeling using a dense German GPS network

The MSTIDs are wave-like perturbations of the ionospheric plasma, which cause the most common ionospheric disturbances in mid-latitude regions. Generally the MSTIDs have velocities of several hundred meters per second and wavelengths of several hundred kilometers. The wave-like effect of the MSTID is one of the main obstacles for accurate interpolation of ionospheric corrections in a medium-scale reference GPS network. In this paper we show a new method of detecting and modeling MSTIDs using dense German GPS network. The between-epoch single difference ionospheric delays from a medium scale dense GPS network are used to estimate the parameter of the MSTID e.g. amplitude, wavelength and velocity. The efficiency of the approach is tested with data from about 320 GPS stations in and near Germany. A MSTID wave moving from east to west across Germany was observed at September 27 in 2009. Its wavelength is about 302 km, with a period of ∼7 min and velocity of about 700 m/s.     

The lunar dust pendulum

An analytic model for the motion of a positively charged lunar dust grain in the presence of a shadowed crater at a negative potential in vacuum is presented. It is shown that the dust grain executes oscillatory trajectories, and an expression is derived for the period of oscillation. Simulations used to verify the analytic expression also show that because the trajectories are unstable, dust grains are either ejected from the crater’s vicinity or deposited into the crater forming “dust ponds.” The model also applies to other airless bodies in the solar system, such as asteroids, and predicts that under certain conditions, particularly near lunar sunset, oscillating dust “canopies” or “swarms” will form over negatively charged craters.     

Energy release in double layers

A Double layer (DL) in a current carrying plasma sustains a localised net potential difference and acts as an impedance converting electrical energy to directed particle energy determined by the DL potential. DL's accelerate equal numbers of ions and electrons for relativistic energies, otherwise electron energisation predominates. Their time independent structure may be described as a BGK (Bernstein-Greene-Kruskal) state analogous to that for laminar shocks, and certain existence criteria must be satisfied. The generalised Langmuir criterion requires total particle pressure balance over the DL and may imply propagation in the plasma reference frame. The Bohm criteria require sufficiently large current densities and are closely related to the local stability condition at the edges of the DL. The DL potential must be sustained externally, for example by the release of stored magnetic energy. A steady state is also possible where (externally maintained) mass motions drive a dynamo region connected by currents to the DL which acts as an electrical load.     

The Emirates Mars Mission (EMM) Emirates Mars InfraRed Spectrometer (EMIRS) Instrument

Space Science Reviews - Modern observatories have revealed the ubiquitous presence of magnetohydrodynamic waves in the solar corona. The propagating waves (in contrast to the standing waves) are...     

液氧/甲烷同轴喷雾及火焰稳定的试验

介绍了液氧和气态甲烷的低温同轴喷雾燃烧试验,试验使用了光学诊断方法如阴影法和火焰分光光谱法记录了试验中的喷雾和火焰信息,讨论了不同燃烧室压力和喷注无量纲数如韦伯数(We)和气液动量流率比下的雾化和火焰稳定情况。试验结果表明,燃烧室压力对射流雾化和火焰稳定有显著影响,增加燃烧室压力有利于火焰稳定于靠近喷注器面的地方,研究中没有发现火焰吹离距离和韦伯数之间有明显的关系式。液氧射流核心长度随气液动量流率比的增大而下降。雾化质量对液氧/甲烷同轴喷雾的火焰稳定性有明显的影响。     

Interactivity in map learning: The effect of cognitive load

The hypothesis that active learning is beneficial relative to passive observation was assessed in the context of spatial knowledge derived from maps. Active and passive participants studied a map either while performing a simultaneous spatial tapping task (high cognitive load) or in the absence of this task (low cognitive load). Active participants controlled how the map was learned, with passive participants observing map learning without exercising control. Spatial recall was assessed in two tests, directional judgements and map drawing. Map drawing and directional judgments showed a similar pattern of results, with performance detrimentally affected by a high load for active participants, but not for passive participants. The results indicate that activity and cognitive load interact, suggesting that active learning can be detrimental to spatial learning in cognitively demanding tasks.     

感知"角秒"——ERA 4000系列角度编码器

高效的驱动系统需要精确的位置信息.一种特殊的光栅鼓栅线制造工艺和独特的扫描原理使海德汉新系列的角度编码器具有很高的精度.