Raman imagery: a new approach to assess the geochemical maturity and biogenicity of permineralized precambrian fossils

Laser-Raman imagery is a non-intrusive, non-destructive analytical technique, recently introduced to Precambrian paleobiology, that can be used to demonstrate a one-to-one spatial correlation between the optically discernible morphology and kerogenous composition of permineralized fossil microorganisms. Made possible by the submicron-scale resolution of the technique and its high sensitivity to the Raman signal of carbonaceous matter, such analyses can be used to determine the chemical-structural characteristics of organic-walled microfossils and associated sapropelic carbonaceous matter in acid-resistant residues and petrographic thin sections. Here we use this technique to analyze kerogenous microscopic fossils and associated carbonaceous sapropel permineralized in 22 unmetamorphosed or little-metamorphosed fine-grained chert units ranging from approximately 400 to approximately 2,100 Ma old. The lineshapes of the Raman spectra acquired vary systematically with five indices of organic geochemical maturation: (1) the mineral-based metamorphic grade of the fossil-bearing units; (2) the fidelity of preservation of the fossils studied; (3) the color of the organic matter analyzed; and both the (4) H/C and (5) N/C ratios measured in particulate kerogens isolated from bulk samples of the fossil-bearing cherts. Deconvolution of relevant spectra shows that those of relatively well-preserved permineralized kerogens analyzed in situ exhibit a distinctive set of Raman bands that are identifiable also in hydrated organic-walled microfossils and particulate carbonaceous matter freed from the cherts by acid maceration. These distinctive Raman bands, however, become indeterminate upon dehydration of such specimens. To compare quantitatively the variations observed among the spectra measured, we introduce the Raman Index of Preservation, an approximate measure of the geochemical maturity of the kerogens studied that is consistent both with the five indices of organic geochemical alteration and with spectra acquired from fossils experimentally heated under controlled laboratory conditions. The results reported provide new insight into the chemical-structural characteristics of ancient carbonaceous matter, the physicochemical changes that accompany organic geochemical maturation, and a new criterion to be added to the suite of evidence by which to evaluate the origin of minute fossil-like objects of possible but uncertain biogenicity.     

On the breakdown of wave fronts of characteristics in an ideal dissociating gas

Using the method of characteristics, the problem of breaking or non-breaking of waves is studied in a plane cylindrically or spherically symmetric flow of an ideal dissociating gas. It is investigated as to how the effects of dissociation and that of the wave front curvature influence the breaking or non-breaking of waves. In a symmetrical converging gas motion a remarkable difference between the behaviours of cylindrical and spherical waves is discovered.     

Individual differences in susceptibility to motion sickness among six Skylab astronauts

One of the Skylab experiments dealt with motion sickness, comparing susceptibility in the workshop aloft with susceptibility preflight and postflight. Tests were conducted on and after mission-day 8 (MD 8) by which time the astronauts were adapted to working conditions. Stressful accelerations were generated by requiring the astronauts, with eyes covered, to execute standardized head movements (front, back, left, and right) while in a chair that could be rotated at angular velocities up to 30 rpm. The selected endpoint was either 150 discrete head movements or a very mild level of motion sickness. In all rotation experiments aloft, the five astronauts tested (astronaut 1 did not participate) were virtually symptom free, thus demonstrating lower susceptibility aloft than in preflight and postflight tests on the ground when symptoms were always elicited. Inasmuch as the eyes were covered and the canalicular stimuli were the same aloft as on the ground, it would appear that lifting the stimulus to the otolith organs due to gravity was an important factor in reducing susceptibility to motion sickness even though the transient stimuli generated under the test conditions were substantial and abnormal in pattern. Some of the astronauts experienced motion sickness under operational conditions aloft or after splashdown, but attention is centered chiefly on symptoms manifested in zero gravity. None of the Skylab-II crew (astronauts 1 to 3) was motion sick aloft. Astronaut 6 of the Skylab-III crew (astronauts 4 to 6) experienced motion sickness within an hour after transition into orbit; this constitutes the earliest such diagnosis on record under orbital flight conditions. The eliciting stimuli were associated with head and body movements, and astronaut 6 obtained relief by avoiding such movements and by one dose of the drug combination 1-scopolamine 0.35 mg + d-amphetamine 5.0 mg. All three astronauts of Skylab-III experienced motion sickness in the workshop where astronaut 6 was most susceptible and astronaut 4, least susceptible. The higher susceptibility of SL-III crewmen in the workshop, as compared with SL-II crewmen, may be attributable to the fact that they were based in the command module less than one-third as long as SL-II crewmen. The unnatural movements, often resembling acrobatics, permitted in the open spaces of the workshop revealed the great potentialities in weightlessness for generating complex interactions of abnormal or unusual vestibular and visual stimuli. Symptoms were controlled by body restraint and by drugs, but high susceptibility to motion sickness persisted for 3 days and probably much longer; restoration was complete on MD 7. From the foregoing statements it is clear that on and after MD 8 the susceptibility of SL-II and SL-III crewmen to motion sickness under experimental conditions was indistinguishable. The role played by the acquisition of adaptation effects prior to MD 8 is less clear and is a subject to be discussed.     

Mineralogical biosignatures and the search for life on Mars

If life ever existed, or still exists, on Mars, its record is likely to be found in minerals formed by, or in association with, microorganisms. An important concept regarding interpretation of the mineralogical record for evidence of life is that, broadly defined, life perturbs disequilibria that arise due to kinetic barriers and can impart unexpected structure to an abiotic system. Many features of minerals and mineral assemblages may serve as biosignatures even if life does not have a familiar terrestrial chemical basis. Biological impacts on minerals and mineral assemblages may be direct or indirect. Crystalline or amorphous biominerals, an important category of mineralogical biosignatures, precipitate under direct cellular control as part of the life cycle of the organism (shells, tests, phytoliths) or indirectly when cell surface layers provide sites for heterogeneous nucleation. Biominerals also form indirectly as by-products of metabolism due to changing mineral solubility. Mineralogical biosignatures include distinctive mineral surface structures or chemistry that arise when dissolution and/or crystal growth kinetics are influenced by metabolic by-products. Mineral assemblages themselves may be diagnostic of the prior activity of organisms where barriers to precipitation or dissolution of specific phases have been overcome. Critical to resolving the question of whether life exists, or existed, on Mars is knowing how to distinguish biologically induced structure and organization patterns from inorganic phenomena and inorganic self-organization. This task assumes special significance when it is acknowledged that the majority of, and perhaps the only, material to be returned from Mars will be mineralogical.     

On the structure of the floating zone in melting

Floating zone melting is used in crystal growth and purification of high melting materials. The use of a reduced gravity environment will remove the constraint imposed on the length of the zone by the hydrostatic pressure. The equilibrium of the floating zone may involve, (1) Hydrostatic forces, when the zone rotates as a whole. (2) Convective driving forces, when the zone is stationary but fluid property gradients appear. (3) Hydrodynamic forces, when some parts of the zone are set into motion with respect to others. The last effects are considered in this paper. The flow pattern of a floating zone held between two discs in relative motion is complicated, and thence the solution of the problem is difficult even assuming a constant property-newtonian liquid. Nevertheless, when a small parameter appears in the problem, the complete flow field can be split into zones where simple solutions are found. To illustrate this approach, the spin-up from rest of an initially cylindrical floating zone is considered with detail. Here the small parameter is the time elapsed from the impulsive starting of motion. Since the problem which has been considered, as well as some others which can be tackled by use of similar methods, concern the viscous layer close to either plate, they can be simulated experimentally in the ground laboratory with short floating zones. Procedures to produce these zones are indicated.     

The evolution of a serviceable EURECA

Within the European space platform program the EURECA is being established as a ground-based platform for short microgravity missions. The development towards a serviceable platform for longer, scientific missions is described. The plan of an advanced space-based platform for increasing payload demands is outlined. The platform design and the adaptation to scientific missions and servicing operations are investigated. The cost-effective utilization of the different platform types using new operational concepts is analyzed in parametric life cycle cost calculations for different payloads and mission scenarios.     

The European Astronaut Centre prepares for International Space Station operations

The European Space Agency (ESA) contribution to the International Space Station (ISS) goes much beyond the delivery of hardware like the Columbus Laboratory, its payloads and the Automated Transfer Vehicles. ESA Astronauts will be members of the ISS crew. ESA, according to its commitments as ISS international partner, will be responsible to provide training on its elements and payloads to all ISS crewmembers and medical support for ESA astronauts. The European Astronaut Centre (EAC) in Cologne has developed over more than a decade into the centre of expertise for manned space activities within ESA by contributing to a number of important co-operative spaceflight missions. This role will be significantly extended for ISS manned operations. Apart from its support to ESA astronauts and their onboard operations, EAC will have a key role in training all ISS astronauts on ESA elements and payloads. The medical support of ISS crew, in particular of ESA astronauts has already started. This paper provides an overview on status and further plans in building up this homebase function for ESA astronauts and on the preparation towards Training Readiness for ISS crew training at EAC, Cologne. Copyright 2001 by the European Space Agency. Published by the American Institute of Aeronautics and Astronautics, Inc., with permission. Released to IAF/IAA/AIAA to publish in all forms.     

Energy Spectrum of Galactic 10–100 MeV Protons in Quiet Sun Periods

The dynamics of the proton energy spectrum during the solar cycle is studied. The spectra were determined by 1–100 MeV particle fluxes measured by different instruments mounted aboard the Earth's IMP-8 satellite for more than one hundred quiet-time intervals in the period between 1974 and 1991. The galactic branch of the spectra (E _p > 10 MeV) constructed for every quiet interval was fitted by a power law function, J =CE . The theory predicts that in the 1–100 MeV energy range, where the adiabatic cooling of particles is dominant, = 1, while we have derived a double-peak distribution. The main maximum has the mean value = 1.35. The mean value of the second, much weaker maximum, is = 0.95. Within the main maximum, values are distributed in accordance with the Gaussian law with a standard deviation D/ = 0.12. The substantial difference of from unity requires the elaboration of a new model of modulation processes in the inner heliosphere. The values corresponding to the second maximum show that modulation processes correspond sometimes to theoretical conceptions. It is shown that correlates weakly with parameters A and describing the solar branch of the spectrum (J(E) = AE ^–). At the same time, a more significant correlation is observed between and the solar activity index, R _z, the counting rate of the Deep River neutron monitor, and the energy value in the minimum of the energy spectrum flux, E _min.     

Promoting research and education in basic space science: the approach of the UN/ESA workshops

UN-affiliated regional centres for space science and technology education are being established or are in operation in Africa (Morocco, Nigeria), Asia and the Pacific (India), Latin America and the Caribbean (Brazil, Mexico), and Western Asia (Jordan). Education curricula at the university level, embracing remote sensing, satellite communications, satellite meteorology, and space science have been developed for these centres. This article briefly reports on the structure of the most recent updated education curricula in the four disciplines that have been made available for implementation in 2002 and 2003, in the six official languages of the United Nations. This is also an effort to bridge the gap between such education curricula as they vary significantly between nations and among educational institutions in nations.     

Dynamics and control of variable-geometry truss structures

Variable-geometry truss structures are likely to be used extensively in the future for in-orbit space construction. This paper considers dynamics formulation and vibration control of such structures. The truss system is modelled as a collection of sub-structures consisting of truss booms, prismatic actuator elements, and in some cases a manipulator at the end. Each truss boom is treated as a separate ‘link’ and its flexibility is modelled using the finite element method. Equations of motion for individual sub-structures are obtained which are then assembled. The non-working constraint forces are eliminated to obtain the equations governing the constrained dynamics of the entire system. For vibration control, the singular perturbation method is employed to construct two reduced-order models, for quasi-static motion and for modal co-ordinates, respectively. Computed torque with PD control is applied to maintain the quasi-static motion, while an optimal LQR method is used for vibration control. Typical simulation results are presented for the planar case.