Titan and exobiological aspects of the Cassini-Huygens mission

Titan, the largest satellite of Saturn, has a dense N2-CH4 atmosphere rich in organic compounds, both in gas and in aerosol phases. Its surface is probably covered by oceans of liquid methane-ethane mixtures, with many dissolved organics. This quasi planet appears as a natural laboratory to study chemical evolution toward complex organic systems in a planetary environment over a long time scale. With the Cassini-Huygens mission NASA and ESA will jointly send an orbiter (Cassini) around Saturn and a probe (Huygens) in the atmosphere of Titan. This mission, currently planned to be launched in 1996-1997 for a Saturn - Titan arrival in 2004, offers a unique opportunity to study in detail extra-terrestrial organic processes. Consequently, it has important implications in the field of exobiology and the origins of life.     

Heterogeneous solid/gas chemistry of organic compounds related to comets,meteorites, Titan,and Mars: Laboratory and in lower Earth orbit experiments

To understand the evolution of organic molecules involved in extraterrestrial environments and with exobiological implications, many experimental programs in the laboratory are devoted to photochemical studies in the gaseous phase as well as in the solid state. The validity of such studies and their applications to extraterrestrial environments can be questioned as long as experiments conducted in space conditions, with the full solar spectrum, especially in the short wavelength domain, have not been implemented. The experiments that are described here will be carried out on a FOTON capsule, using the BIOPAN facility, and on the International Space Station, using the EXPOSE facility. Vented and sealed exposition cells will be used, which will allow us to study the chemical evolution in the gaseous phase as well as heterogeneous processes, such as the degradation of solid compounds and the release of gaseous fragments.     

Report of the COSPAR mars special regions colloquium

In this paper we present the findings of a COSPAR Mars Special Regions Colloquium held in Rome in 2007. We review and discuss the definition of Mars Special Regions, the physical parameters used to define Mars Special Regions, and physical features on Mars that can be interpreted as Mars Special Regions. We conclude that any region experiencing temperatures > −25 °C for a few hours a year and a water activity > 0.5 can potentially allow the replication of terrestrial microorganisms. Physical features on Mars that can be interpreted as meeting these conditions constitute a Mars Special Region. Based on current knowledge of the martian environment and the conservative nature of planetary protection, the following features constitute Mars Special regions: Gullies and bright streaks associated with them, pasted-on terrain, deep subsurface, dark streaks only on a case-by-case basis, others to be determined. The parameter definition and the associated list of physical features should be re-evaluated on a regular basis.     

Exploring The Saturn System In The Thermal Infrared: The Composite Infrared Spectrometer

The Composite Infrared Spectrometer (CIRS) is a remote-sensing Fourier Transform Spectrometer (FTS) on the Cassini orbiter that measures thermal radiation over two decades in wavenumber, from 10 to 1400 cm^{− 1} (1 mm to 7μ m), with a spectral resolution that can be set from 0.5 to 15.5 cm^{− 1}. The far infrared portion of the spectrum (10–600 cm^{− 1}) is measured with a polarizing interferometer having thermopile detectors with a common 4-mrad field of view (FOV). The middle infrared portion is measured with a traditional Michelson interferometer having two focal planes (600–1100 cm^{− 1}, 1100–1400 cm^{− 1}). Each focal plane is composed of a 1× 10 array of HgCdTe detectors, each detector having a 0.3-mrad FOV. CIRS observations will provide three-dimensional maps of temperature, gas composition, and aerosols/condensates of the atmospheres of Titan and Saturn with good vertical and horizontal resolution, from deep in their tropospheres to high in their mesospheres. CIRS’s ability to observe atmospheres in the limb-viewing mode (in addition to nadir) offers the opportunity to provide accurate and highly resolved vertical profiles of these atmospheric variables. The ability to observe with high-spectral resolution should facilitate the identification of new constituents. CIRS will also map the thermal and compositional properties of the surfaces of Saturn’s icy satellites. It will similarly map Saturn’s rings, characterizing their dynamical and spatial structure and constraining theories of their formation and evolution. The combination of broad spectral range, programmable spectral resolution, the small detector fields of view, and an orbiting spacecraft platform will allow CIRS to observe the Saturnian system in the thermal infrared at a level of detail not previously achieved.This revised version was published online in July 2005 with a corrected cover date.     

The Gas Chromatograph Mass Spectrometer for the Huygens Probe

The Gas Chromatograph Mass Spectrometer (GCMS) on the Huygens Probe will measure the chemical composition of Titan's atmosphere from 170 km altitude (∼1 hPa) to the surface (∼1500 hPa) and determine the isotope ratios of the major gaseous constituents. The GCMS will also analyze gas samples from the Aerosol Collector Pyrolyser (ACP) and may be able to investigate the composition (including isotope ratios) of several candidate surface materials. The GCMS is a quadrupole mass filter with a secondary electron multiplier detection system and a gas sampling system providing continuous direct atmospheric composition measurements and batch sampling through three gas chromatographic (GC) columns. The mass spectrometer employs five ion sources sequentially feeding the mass analyzer. Three ion sources serve as detectors for the GC columns and two are dedicated to direct atmosphere sampling and ACP gas sampling respectively. The instrument is also equipped with a chemical scrubber cell for noble gas analysis and a sample enrichment cell for selective measurement of high boiling point carbon containing constituents. The mass range is 2 to 141 Dalton and the nominal detection threshold is at a mixing ratio of 10^{− 8}. The data rate available from the Probe system is 885 bit/s. The weight of the instrument is 17.3 kg and the energy required for warm up and 150 minutes of operation is 110 Watt-hours. This revised version was published online in August 2006 with corrections to the Cover Date.     

Detection of martian amino acids by chemical derivatization coupled to gas chromatography: in situ and laboratory analysis.

If there is, or ever was, life in our solar system beyond the Earth, Mars is the most likely place to search for. Future space missions will have then to take into account the detection of prebiotic molecules or molecules of biological significance such as amino acids. Techniques of analysis used for returned samples have to be very sensitive and avoid any chemical or biological contamination whereas in situ techniques have to be automated, fast and low energy consuming. Several possible methods could be used for in situ amino acid analyses on Mars, but gas chromatography would likely be the most suitable. Returned samples could be analyzed by any method in routine laboratory use such as gas chromatography, already successfully performed for analyses of organic matter including amino acids from martian meteorites. The derivatization step, which volatilizes amino acids to perform both in situ and laboratory analysis by gas chromatography, is discussed here.     

Exobiology and Planetary Protection of icy moons

The outer solar system is an important area of investigation for exobiology, the study of life in the universe. Several moons of the outer planets involve processes and structures comparable to those thought to have played an important role in the emergence of life on Earth, such as the formation and exchange of organic materials between different reservoirs. The study of these prebiotic processes on, and in, outer solar system moons is a key goal for exobiology, together with the question of habitability and the search for evidence of past or even present life. This chapter reviews the aspects of prebiotic chemistry and potential presence of life on Europa, Enceladus and Titan, based on the most recent data obtained from space missions as well as theoretical and experimental laboratory models. The habitability of these extraterrestrial environments, which are likely to include large reservoirs of liquid water in their internal structure, is discussed as well as the particular case of Titan’s hydrocarbon lakes. The question of planetary protection, especially in the case of Europa, is also presented.     

Radiolysis and Photolysis of Icy Satellite Surfaces: Experiments and Theory

The transport and exchange of material between bodies in the outer solar system is often facilitated by their exposure to ionizing radiation. With this in mind we review the effects of energetic ions, electrons and UV photons on materials present in the outer solar system. We consider radiolysis, photolysis, and sputtering of low temperature solids. Radiolysis and photolysis are the chemistry that follows the bond breaking and ionization produced by incident radiation, producing, e.g., O₂ and H₂ from irradiated H₂O ice. Sputtering is the ejection of molecules by incident radiation. Both processes are particularly effective on ices in the outer solar system. Materials reviewed include H₂O ice, sulfur-containing compounds (such as SO₂ and S₈), carbon-containing compounds (such as CH₄), nitrogen-containing compounds (such as NH₃ and N₂), and mixtures of those compounds. We also review the effects of ionizing radiation on a mixture of N₂ and CH₄ gases, as appropriate to Titan’s upper atmosphere, where radiolysis and photolysis produce complex organic compounds (tholins).