Geochemical Reservoirs and Timing of Sulfur Cycling on Mars

Sulfate-dominated sedimentary deposits are widespread on the surface of Mars, which contrasts with the rarity of carbonate deposits, and indicates surface waters with chemical features drastically different from those on Earth. While the Earth’s surface chemistry and climate are intimately tied to the carbon cycle, it is the sulfur cycle that most strongly influences the Martian geosystems. The presence of sulfate minerals observed from orbit and in-situ via surface exploration within sedimentary rocks and unconsolidated regolith traces a history of post-Noachian aqueous processes mediated by sulfur. These materials likely formed in water-limited aqueous conditions compared to environments indicated by clay minerals and localized carbonates that formed in surface and subsurface settings on early Mars. Constraining the timing of sulfur delivery to the Martian exosphere, as well as volcanogenic H₂O is therefore central, as it combines with volcanogenic sulfur to produce acidic fluids and ice. Here, we reassess and review the Martian geochemical reservoirs of sulfur from the innermost core, to the mantle, crust, and surficial sediments. The recognized occurrences and the mineralogical features of sedimentary sulfate deposits are synthesized and summarized. Existing models of formation of sedimentary sulfate are discussed and related to weathering processes and chemical conditions of surface waters. We also review existing models of sulfur content in the Martian mantle and analyze how volcanic activities may have transferred igneous sulfur into the exosphere and evaluate the mass transfers and speciation relationships between volcanic sulfur and sedimentary sulfates. The sedimentary clay-sulfate succession can be reconciled with a continuous volcanic eruption rate throughout the Noachian-Hesperian, but a process occurring around the mid-Noachian must have profoundly changed the composition of volcanic degassing. A hypothetical increase in the oxidation state or in water content of Martian lavas or a decrease in atmospheric pressure is necessary to account for such a change in composition of volcanic gases. This would allow the pre mid-Noachian volcanic gases to be dominated by water and carbon-species but late Noachian and Hesperian volcanic gases to be sulfur-rich and characterized by high SO₂ content. Interruption of early dynamo and impact ejection of the atmosphere may have decreased the atmospheric pressure during the early Noachian whereas it remains unclear how the redox state or water content of lavas could have changed. Nevertheless, volcanic emission of SO₂ rich gases since the late Noachian can explain many features of Martian sulfate-rich regolith, including the mass of sulfate and the particular chemical features (i.e. acidity) of surface waters accompanying these deposits. How SO₂ impacted on Mars’s climate, with possible short time scale global warming and long time scale cooling effects, remains controversial. However, the ancient wet and warm era on Mars seems incompatible with elevated atmospheric sulfur dioxide because conditions favorable to volcanic SO₂ degassing were most likely not in place at this time.     

Numerical study of intrachamber processes dynamics at nozzleless solid propellant rocket engine actuation

The results of the comprehensive numerical analysis for dynamics of intrachamber processes that appear at nozzleless solid propellant rocket engine (SPRE) actuation are presented. A complete cycle of rocket engine operation is analyzed. We solve a conjugate problem involving the igniter actuation; heating, ignition and following combustion of a solid propellant charge; a combustion product flow in the combustion chamber; depressurization of the combustion chamber, and the subsequent motion of the rocket engine blank; variation of the combustion surface geometry at the expense of the gradual and nonuniform burnout of solid propellant web.     

Soft X-Ray and Extreme Ultraviolet Excess Emission from Clusters of Galaxies

An excess over the extrapolation to the extreme ultraviolet and soft X-ray ranges of the thermal emission from the hot intracluster medium has been detected in a number of clusters of galaxies. We briefly present each of the satellites (EUVE, ROSAT PSPC and BeppoSAX, and presently XMM-Newton, Chandra and Suzaku) and their corresponding instrumental issues, which are responsible for the fact that this soft excess remains controversial in a number of cases. We then review the evidence for this soft X-ray excess and discuss the possible mechanisms (thermal and non-thermal) which could be responsible for this emission.     

Particle Acceleration Mechanisms

In this paper we review the possible mechanisms for production of non-thermal electrons which are responsible for the observed non-thermal radiation in clusters of galaxies. Our primary focus is on non-thermal Bremsstrahlung and inverse Compton scattering, that produce hard X-ray emission. We first give a brief review of acceleration mechanisms and point out that in most astrophysical situations, and in particular for the intracluster medium, shocks, turbulence and plasma waves play a crucial role. We also outline how the effects of the turbulence can be accounted for. Using a generic model for turbulence and acceleration, we then consider two scenarios for production of non-thermal radiation. The first is motivated by the possibility that hard X-ray emission is due to non-thermal Bremsstrahlung by nonrelativistic particles and attempts to produce non-thermal tails by accelerating the electrons from the background plasma with an initial Maxwellian distribution. For acceleration rates smaller than the Coulomb energy loss rate, the effect of energising the plasma is to primarily heat the plasma with little sign of a distinct non-thermal tail. Such tails are discernible only for acceleration rates comparable or larger than the Coulomb loss rate. However, these tails are accompanied by significant heating and they are present for a short time of <10⁶ years, which is also the time that the tail will be thermalised. A longer period of acceleration at such rates will result in a runaway situation with most particles being accelerated to very high energies. These more exact treatments confirm the difficulty with this model, first pointed out by Petrosian (Astrophys. J. 557:560, 2001). Such non-thermal tails, even if possible, can only explain the hard X-ray but not the radio emission which needs GeV or higher energy electrons. For these and for production of hard X-rays by the inverse Compton model, we need the second scenario where there is injection and subsequent acceleration of relativistic electrons. It is shown that a steady state situation, for example arising from secondary electrons produced from cosmic ray proton scattering by background protons, will most likely lead to flatter than required electron spectra or it requires a short escape time of the electrons from the cluster. An episodic injection of relativistic electrons, presumably from galaxies or AGN, and/or episodic generation of turbulence and shocks by mergers can result in an electron spectrum consistent with observations but for only a short period of less than one billion years.     

Non-Thermal Processes in Cosmological Simulations

Non-thermal components are key ingredients for understanding clusters of galaxies. In the hierarchical model of structure formation, shocks and large-scale turbulence are unavoidable in the cluster formation processes. Understanding the amplification and evolution of the magnetic field in galaxy clusters is necessary for modelling both the heat transport and the dissipative processes in the hot intra-cluster plasma. The acceleration, transport and interactions of non-thermal energetic particles are essential for modelling the observed emissions. Therefore, the inclusion of the non-thermal components will be mandatory for simulating accurately the global dynamical processes in clusters. In this review, we summarise the results obtained with the simulations of the formation of galaxy clusters which address the issues of shocks, magnetic field, cosmic ray particles and turbulence.     

A cost driven predictive maintenance policy for structural airframe maintenance

Airframe maintenance is traditionally performed at scheduled maintenance stops.The decision to repair a fuselage panel is based on a fixed crack size threshold,which allows to ensure the aircraft safety until the next scheduled maintenance stop.With progress in sensor technology and data processing techniques,structural health monitoring (SHM) systems are increasingly being considered in the aviation industry.SHM systems track the aircraft health state continuously,lead ing to the possibility of planning maintenance based on an actual state of aircraft rather than on a fixed schedule.This paper builds upon a model-based prognostics framework that the authors developed in their previous work,which couples the Extended Kalman filter (EKF) with a first order perturbation (FOP) method.By using the information given by this prognostics method,a novel cost driven predictive maintenance (CDPM) policy is proposed,which ensures the aircraft safety while minimizing the maintenance cost.The proposed policy is formally derived based on the trade-off between probabilities of occurrence of scheduled and unscheduled maintenance.A numerical case study simulating the maintenance process of an entire fleet of aircrafts is imple mented.Under the condition of assuring the same safety level,the CDPM is compared in terms of cost with two other maintenance policies:scheduled maintenance and threshold based SHM maintenance.The comparison results show CDPM could lead to significant cost savings.     

Boundary discontinuous Fourier analysis of thick beams with clamped and simply supported edges via CUF

This paper presents an analytical solution for static analysis of thick rectangular beams with different boundary conditions.Carrera's Unified Formulation (CUF) is used in order to consider shear deformation theories of arbitrary order.The novelty of the present work is that a boundary discontinuous Fourier approach is used to consider clamped boundary conditions in the analytical solution,unlike Navier-type solutions which are restricted to simply supported beams.Governing equations are obtained by employing the principle of virtual work.The numerical accuracy of results is ascertained by studying the convergence of the solution and comparing the results to those of a 3D finite element solution.Beams subjected to bending due to a uniform pressure load and subjected to torsion due to opposite linear forces are considered.Overall,accurate results close to those of 3D finite element solutions are obtained,which can be used to validate finite element results or other approximate methods.     

Numerical scheme of the second order of accuracy for vortex methods for incompressible flow simulation around airfoils

A high-accuracy numerical scheme is proposed for vortex methods of flow simulation around airfoils of arbitrary shape including airfoils with sharp edges, because it does not require the solution continuity on the airfoil.