The organic aerosols of Titan

A dark reddish organic solid, called tholin, is synthesized from simulated Titanian atmospheres by irradiation with high energy electrons in a plasma discharge. The visible reflection spectrum of this tholin is found to be similar to that of high altitude aerosols responsible for the albedo and reddish color of Titan. The real (n) and imaginary (k) parts of the complex refractive index of thin films of Titan tholin prepared by continuous D.C. discharge through a 0.9 N₂/0.1 CH₄ gas mixture at 0.2 mb is determined from x-ray to microwave frequencies. Values of n (1.65) and k (0.004 to 0.08) in the visible are consistent with deductions made by ground-based and spaceborne observations of Titan. Many infrared absorption features are present in k(λ), including the 4.6 μm nitrile band. Molecular analysis of the volatile component of this tholin was performed by sequential and non-sequential pyrolytic gas chromatography/mass spectrometry. More than one hundred organic compounds are released; tentative identifications include saturated and unsaturated aliphatic hydrocarbons, substituted polycyclic aromatics, nitriles, amines, pyrroles, pyrazines, pyridines, pyrimidines, and the purine, adenine. In addition, acid hydrolysis produces a racemic mixture of biological and non-biological amino acids. Many of these molecules are implicated in the origin of life on Earth, suggesting Titan as a contemporary laboratory environment for prebiological organic chemistry on a planetary scale.     

Localization performance of arrays subject to phase errors

The passive localisation of radiating sources using an array subject to random perturbations in sensor phases is presented. All source signals as well as additive noises observed at the sensors are assumed to be independent identically distributed zero-mean Gaussian random processes. Cramer-Rao bounds are derived for source bearings and ranges for the phase errors at each sensor. It is shown that accurate phase calibration can be achieved when the number of sources exceeds a certain minimum. The locations of the calibrating sources need not be known a priori and need only satisfy mild regularity conditions. A calibration procedure is proposed which uses maximum-likelihood techniques     

Computational fluid dynamics and material processing (buoyancy and thermocapillary convections in melts during directional crystallization)

Modelisation and solution of heat and mass transfer problems relevant for material processing are generally hard to be handled, as they often involve 3D unsteady flows, viscous mixtures, phase changes, moving liquid-solid fronts, deforming liquid-gas interfaces, etc.… For space applications, material processing benefits of reduced buoyancy convection but can be faced to a strongly increased complexity due to variable g, mainly in manned flight.

Computational techniques used to analyse fluid motions in material processing, accounting for free surface, crystallization front and bulk convection in melt, are reviewed with emphasis to directional crystallization. Hydrodynamics stability and bifurcation analysis are shown to be useful complementary tools for correlating data, and for a better understanding of the physical laws. This last point will be illustrated in the case of the onset of oscillations in metallic melts.     

Marangoni convection in a liquid layer under the simultaneous action of a transverse magnetic field and rotation

Asymptotic stability characteristics with respect to the onset of Marangoni convection in a liquid layer under the simultaneous action of a large transverse magnetic field and a large rate of rotation are investigated. In certain parameter ranges there is a decrease in critical Marangoni number for increasing magnetic field and rotation depending on the coupling between interfacial perturbations and rotation.     

Determination of aerodynamic forces on satellites by theory and wind tunnel experiments

Theoretical and experimental aspects of satellite aerodynamics in free molecular flow have been studied. A FORTRAN-program package has been developed to calculate free molecular aerodynamic force and moment coefficients of general and special convex shapes, using an approximation of the surfaces by plane triangular elements.As a special case for concave bodies, the drag of a satellite of TD1A-similar shape has been investigated by an approximate theory and by wind tunnel experiments. Comparisons are made between experimental results, the approximate theory and exact theory.     

IR-spectroscopy of ionosphere from stratospheric balloons

The radiation spectra of the ionosphere in the 4–5 μm region have been determined from stratospheric balloons by means of the specially elaborated method of the registration of angular and spectral distribution of the radiation. The radiation bands of 4.4 μm and 4.8 μm which have 0.1–0.2 erg cm^?2 sr^?1s^?1. brightness obtained in two flights, are identified with the vibration-rotation transitions of the ion NO⁺ (0 - 1) and the molecules N¹⁴N¹⁵ (0 - 1) and CO (0 - 1) and (3 - 2) from altitudes between 120 and 500 km.     

50–200 GV cosmic rays at various heliolatitudes

We consider regular motion of 50 – 200 GV particles in a large-scale interplanetary magnetic field model which contains a wavy neutral sheet responsible for the sector-structure. Numerical calculations based upon energy losses along various trajectories are carried out to obtain the predicted omni-directional density and anisotropy of cosmic rays at various solar latitudes. A marked difference is found between odd and even solar cycles. The post-1969 field configuration gives small radial and large latitudinal gradient: cosmic ray density increases toward the poles. The latitudinal gradient turns out smaller and of opposite sense for the pre-1969 epoch. Anisotropy changes dramatically as we move off the solar equator: corotation appears to be restricted to low latitudes.     

Vertical profiles of halocarbons in the stratosphere

Stratospheric air samples collected between 10 and 35 km altitude my means of a cryogenic sampler were analyzed by gaschromatography. Thus vertical profiles of source gases for halogen radicals were derived, such as CCl₄, CCl₃F, CCl₂F₂, CClF₃, CF₄, C₂F₃Cl₃, C₂F₄Cl₂, C₂F₅Cl, C₂F₆, CH₃Cl, CH₃CCl₃, CHF₂Cl, CH₃Br, CBrF₃, and CBrCl₂F. Systematic discrepancies between measured and modelled halocarbon profiles point to deficiencies of present one- and two-dimensional models. Measurements of fully halogenated hydrocarbons provide a tool for systematically studying these deficiencies and thus improving the models.