Preservation of martian organic and environmental records: final report of the Mars biosignature working group

The Mars Science Laboratory (MSL) has an instrument package capable of making measurements of past and present environmental conditions. The data generated may tell us if Mars is, or ever was, able to support life. However, the knowledge of Mars' past history and the geological processes most likely to preserve a record of that history remain sparse and, in some instances, ambiguous. Physical, chemical, and geological processes relevant to biosignature preservation on Earth, especially under conditions early in its history when microbial life predominated, are also imperfectly known. Here, we present the report of a working group chartered by the Co-Chairs of NASA's MSL Project Science Group, John P. Grotzinger and Michael A. Meyer, to review and evaluate potential for biosignature formation and preservation on Mars. Orbital images confirm that layered rocks achieved kilometer-scale thicknesses in some regions of ancient Mars. Clearly, interplays of sedimentation and erosional processes govern present-day exposures, and our understanding of these processes is incomplete. MSL can document and evaluate patterns of stratigraphic development as well as the sources of layered materials and their subsequent diagenesis. It can also document other potential biosignature repositories such as hydrothermal environments. These capabilities offer an unprecedented opportunity to decipher key aspects of the environmental evolution of Mars' early surface and aspects of the diagenetic processes that have operated since that time. Considering the MSL instrument payload package, we identified the following classes of biosignatures as within the MSL detection window: organism morphologies (cells, body fossils, casts), biofabrics (including microbial mats), diagnostic organic molecules, isotopic signatures, evidence of biomineralization and bioalteration, spatial patterns in chemistry, and biogenic gases. Of these, biogenic organic molecules and biogenic atmospheric gases are considered the most definitive and most readily detectable by MSL.     

On the stabilization of ribose by silicate minerals

The RNA-world theory hypothesizes that early Earth life was based on the RNA molecule. However, the notion that ribose, the sugar in RNA, is unstable still casts a serious doubt over this theory. Recently, it has been found that the silicate-mediated formose reaction facilitates the stabilization of ribose. Using accurate quantum chemical calculations, we determined the relative stability of the silicate complexes of arabinose, lyxose, ribose, and xylose with the intent to determine which would form predominantly from a formose-like reaction. Five stereoisomers were investigated for each complex. The stereoisomers of 2:1 ribose-silicate are the more stable ones, to the extent that the least stable of these is even more stable than the most stable stereoisomer of the other 2:1 sugar-silicate complexes. Thus, thermodynamically, a formose-like reaction in the presence of silicate minerals should preferentially form the silicate complex of ribose over the silicate complex of arabinose, lyxose, and xylose.     

Deducing Electron Properties from Hard X-ray Observations

X-radiation from energetic electrons is the prime diagnostic of flare-accelerated electrons. The observed X-ray flux (and polarization state) is fundamentally a convolution of the cross-section for the hard X-ray emission process(es) in question with the electron distribution function, which is in turn a function of energy, direction, spatial location and time. To address the problems of particle propagation and acceleration one needs to infer as much information as possible on this electron distribution function, through a deconvolution of this fundamental relationship. This review presents recent progress toward this goal using spectroscopic, imaging and polarization measurements, primarily from the Reuven Ramaty High Energy Solar Spectroscopic Imager (RHESSI). Previous conclusions regarding the energy, angular (pitch angle) and spatial distributions of energetic electrons in solar flares are critically reviewed. We discuss the role and the observational evidence of several radiation processes: free-free electron-ion, free-free electron-electron, free-bound electron-ion, photoelectric absorption and Compton backscatter (albedo), using both spectroscopic and imaging techniques. This unprecedented quality of data allows for the first time inference of the angular distributions of the X-ray-emitting electrons and improved model-independent inference of electron energy spectra and emission measures of thermal plasma. Moreover, imaging spectroscopy has revealed hitherto unknown details of solar flare morphology and detailed spectroscopy of coronal, footpoint and extended sources in flaring regions. Additional attempts to measure hard X-ray polarization were not sufficient to put constraints on the degree of anisotropy of electrons, but point to the importance of obtaining good quality polarization data in the future.     

Application of the parameter-averaging method to calculations of gas ejectors with cylindrical mixing chambers

In this paper, one of the most possible methods for calculations of ejector devices equipped with the cylindrical mixing chambers is considered; the method is based on averaging the flow parameters at the chamber inlet. We present the calculation results and their comparison with the earlier published data, as well as the quantitative assessment of this method and feasibilities of its use for different technical devices embodying the concept of ejection.     

Optimization of a tool kit for machining by methods of graph theory

Some methods of optimizing a cutting tool kit by the minimum labour content criterion in milling of an article are considered. Their advantages and disadvantages are given.     

Heat transfer at various methods of thermal protection in the systems of power-driven gas turbine plants (GTP)

The scheme variants of implementing the thermal protection against heat flows being generated by the body of a high-temperature stationary gas turbine engine (GTE) are presented. The scheme of the experimental bench with a working section is given. Methodical approaches to the heat transfer calculation at different variants of forced and natural convection organization and under various operating conditions are described. The generalized results of the experiments carried out using a heat curtain being generated by porous injection are presented.     

Potential of salt-accumulating and salt-secreting halophytic plants for recycling sodium chloride in human urine in bioregenerative life support systems

This study addresses the possibility of growing different halophytic plants on mineralized human urine as a way to recycle NaCl from human wastes in a bioregenerative life support system (BLSS). Two halophytic plant species were studied: the salt-accumulating Salicornia europaea and the salt-secreting Limonium gmelinii. During the first two weeks, plants were grown on Knop’s solution, then an average daily amount of urine produced by one human, which had been preliminarily mineralized, was gradually added to the experimental solutions. Nutrient solutions simulating urine mineral composition were gradually added to control solutions. NaCl concentrations in the stock solutions added to the experimental and control solutions were 9 g/L in the first treatment and 20 g/L in the second treatment. The mineralized human urine showed some inhibitory effects on S. europaea and L. gmelinii. The biomass yield of experimental plants was lower than that of control ones. If calculated for the same time period (120 d) and area (1 m²), the amount of sodium chloride taken up by S. europaea plants would be 11.7 times larger than the amount taken up by L. gmelinii plants (486 g/m² vs. 41 g/m²). Thus, S. europaea is the better choice of halophyte for recycling sodium chloride from human wastes in BLSS.     

Normalized ionization yield function for various nuclei obtained with full Monte Carlo simulations

Several recent results important for production of ion pairs in the Earth atmosphere by various primary cosmic ray nuclei are presented. The direct ionization by various primary cosmic ray nuclei is explicitly obtained. The longitudinal profile of atmospheric cascades is sensitive to the energy and mass (charge) of the primary particle. In this study different cosmic ray nuclei are considered as primaries, namely Helium, Oxygen and Iron nuclei. The cosmic ray induced ionization is obtained on the basis of CORSIKA 6.52 code simulations using FLUKA 2006 and QGSJET II hadronic interaction models. The energy of the primary particles is normalized to GeV per nucleon. In addition, the ionization yield function Y is normalized as ion pair production per nucleon. The obtained ionization yield functions Y for various primaries are compared. The presented results and their application are discussed.     

Ionization effect of solar protons in the Earth atmosphere – Case study of the 20 January 2005 SEP event

The cosmic ray ground level enhancement on January 20, 2005 is among the largest recorded events in the history of cosmic ray measurements. The solar protons of MeV energies cause an excess of ionization in the atmosphere, specifically over polar caps following major solar disturbances. The ionization effect in the Earth atmosphere is obtained for various latitudes on the basis of solar proton energy spectra, reconstructed from GOES 11 measurements and subsequent full Monte Carlo simulation of cosmic ray induced atmospheric cascade. The estimation of ionization rates is based on a numerical model for cosmic ray induced ionization. The evolution of atmospheric cascade is performed with the CORSIKA 6.52 code using FLUKA 2006b and QGSJET II hadron interaction models. The atmospheric ion rate ionization is explicitly obtained for 40°N, 60°N and 80°N latitudes. The time evolution of obtained ion rates is presented. It is demonstrated that ionization effect is negative for 40°N and small for 60°N, because of accompanying Forbush decrease. The ionization effect is significant only in sub-polar and polar atmosphere during the major ground level enhancement of 20 January 2005.