Haze aerosols in the atmosphere of early Earth: manna from heaven

An organic haze layer in the upper atmosphere of Titan plays a crucial role in the atmospheric composition and climate of that moon. Such a haze layer may also have existed on the early Earth, providing an ultraviolet shield for greenhouse gases needed to warm the planet enough for life to arise and evolve. Despite the implications of such a haze layer, little is known about the organic material produced under early Earth conditions when both CO(2) and CH(4) may have been abundant in the atmosphere. For the first time, we experimentally demonstrate that organic haze can be generated in different CH(4)/CO(2) ratios. Here, we show that haze aerosols are able to form at CH(4) mixing ratios of 1,000 ppmv, a level likely to be present on early Earth. In addition, we find that organic hazes will form at C/O ratios as low as 0.6, which is lower than the predicted value of unity. We also show that as the C/O ratio decreases, the organic particles produced are more oxidized and contain biologically labile compounds. After life arose, the haze may thus have provided food for biota.     

VLBI observations to the APOD satellite

The APOD (Atmospheric density detection and Precise Orbit Determination) is the first LEO (Low Earth Orbit) satellite in orbit co-located with a dual-frequency GNSS (GPS/BD) receiver, an SLR reflector, and a VLBI X/S dual band beacon. From the overlap statistics between consecutive solution arcs and the independent validation by SLR measurements, the orbit position deviation was below 10?cm before the on-board GNSS receiver got partially operational. In this paper, the focus is on the VLBI observations to the LEO satellite from multiple geodetic VLBI radio telescopes, since this is the first implementation of a dedicated VLBI transmitter in low Earth orbit. The practical problems of tracking a fast moving spacecraft with current VLBI ground infrastructure were solved and strong interferometric fringes were obtained by cross-correlation of APOD carrier and DOR (Differential One-way Ranging) signals. The precision in X-band time delay derived from 0.1?s integration time of the correlator output is on the level of 0.1?ns. The APOD observations demonstrate encouraging prospects of co-location of multiple space geodetic techniques in space, as a first prototype.     

The low and middle latitude semi-annual anomaly in NmF2 near noon: A statistical study

Hourly values of the F2-layer peak density, NmF2, measured by 99 ionosonde stations near noon from 1957 to 2010 at low and middle geomagnetic latitudes of the northern and southern geographic hemispheres are used in a statistical study of the F2-region semi-annual anomaly. The equinox/winter and equinox/summer geomagnetically quiet NmF2 ratios, X and Y, taken near noon over each ionosonde for approximately the same winter, equinox, and summer solar activity conditions are analyzed. The conditional probabilities of occurrences of X and Y in intervals of X and Y, the most frequent values of X and Y, the mean expected values of X and Y, and the conditional probability to observe the F2-region semi-annual anomaly are calculated and studied for the fist time for low, moderate, and high solar activity conditions. These statistical parameters are averaged over 5° geomagnetic latitude interval in the northern and southern geographic hemispheres, and the trends in these averaged statistical characteristics of the NmF2 semi-annual anomaly are calculated and studied for the fist time. It is shown that the median approach can produce the incorrect conclusions about the absence of the NmF2 semi-annual anomaly.     

Composition Measurements of a Comet from the Rosetta Orbiter Spacecraft

The European Space Agency (ESA) Rosetta Spacecraft, launched on March 2, 2004 toward Comet 67P/Churyumov-Gerasimenko (C-G), carries a complementary set of instruments on both the orbiter and lander (Philae) portions of the spacecraft, to measure the composition of the Comet C-G. The primary composition measuring instruments on the Orbiter are Alice, COSIMA, ICA, MIRO, OSIRIS, ROSINA and VIRTIS. These instruments collectively are capable of providing compositional information, including temporal and spatial distributions of important atomic, molecular, and ionic species, minerals, and ices in the coma and nucleus. The instruments utilize a variety of techniques and wavelength ranges to accomplish their objectives. This paper provides an overview of composition measurements that will be possible using the suite of orbiter composition measuring instruments. A table is provided that lists important species detectable (depending on abundances) with each instrument.     

Spherule beds 3.47-3.24 billion years old in the Barberton Greenstone Belt,South Africa: a record of large meteorite impacts and their influence on early crustal and biological evolution

Four layers, S1-S4, containing sand-sized spherical particles formed as a result of large meteorite impacts, occur in 3.47-3.24 Ga rocks of the Barberton Greenstone Belt, South Africa. Ir levels in S3 and S4 locally equal or exceed chondritic values but in other sections are at or only slightly above background. Most spherules are inferred to have formed by condensation of impact-produced rock vapor clouds, although some may represent ballistically ejected liquid droplets. Extreme Ir abundances and heterogeneity may reflect element fractionation during spherule formation, hydraulic fractionation during deposition, and/or diagenetic and metasomatic processes. Deposition of S1, S2, and S3 was widely influenced by waves and/or currents interpreted to represent impact-generated tsunamis, and S1 and S2 show multiple graded layers indicating the passage of two or more wave trains. These tsunamis may have promoted mixing within a globally stratified ocean, enriching surface waters in nutrients for biological communities. S2 and S3 mark the transition from the 300-million-year-long Onverwacht stage of predominantly basaltic and komatiitic volcanism to the late orogenic stage of greenstone belt evolution, suggesting that regional and possibly global tectonic reorganization resulted from these large impacts. These beds provide the oldest known direct record of terrestrial impacts and an opportunity to explore their influence on early life, crust, ocean, and atmosphere. The apparent presence of impact clusters at 3.26-3.24 Ga and approximately 2.65-2.5 Ga suggests either spikes in impact rates during the Archean or that the entire Archean was characterized by terrestrial impact rates above those currently estimated from the lunar cratering record.     

Hands-on education system using water rocket

Trial of hands-on education of rocket technology for university students using water rocket, which consists of structural study, propulsion system study, aerodynamic study, stability study, and flight trajectory study, has been performed. Integrating each subject into a group of tasks, a hands-on education system of aerospace technology will become feasible. Advantage of the system is that students can verify the theory by hands-on practice. Development of recovery mechanism for water rocket will be a good subject of hands-on innovative design. Although the system has been developed mostly for university students, it can easily be converted to hands-on education system for school children and high school students.     

Cyanobacterial emergence at 2.8 gya and greenhouse feedbacks

Apparent cyanobacterial emergence at about 2.8 Gya coincides with the negative excursion in the organic carbon isotope record, which is the first strong evidence for the presence of atmospheric methane. The existence of weathering feedbacks in the carbonate-silicate cycle suggests that atmospheric and oceanic CO2 concentrations would have been high prior to the presence of a methane greenhouse (and thus the ocean would have had high bicarbonate concentrations). With the onset of a methane greenhouse, carbon dioxide concentrations would decrease. Bicarbonate has been proposed as the preferred reductant that preceded water for oxygenic photosynthesis in a bacterial photosynthetic precursor to cyanobacteria; with the drop of carbon dioxide level, Archean cyanobacteria emerged using water as a reductant instead of bicarbonate (Dismukes et al., 2001). Our thermodynamic calculations, with regard to this scenario, give at least a tenfold drop in aqueous CO2 levels with the onset of a methane-dominated greenhouse, assuming surface temperatures of about 60 degrees C and a drop in the level of atmospheric carbon dioxide from about 1 to 0.1 bars. The buildup of atmospheric methane could have been triggered by the boost in oceanic organic productivity that arose from the emergence of pre-cyanobacterial oxygenic phototrophy at about 2.8-3.0 Gya; high temperatures may have precluded an earlier emergence. A greenhouse transition timescale on the order of 50-100 million years is consistent with results from modeling the carbonate-silicate cycle. This is an alternative hypothesis to proposals of a tectonic driver for this apparent greenhouse transition.     

Estimated errors in a global gravity wave climatology from GPS radio occultation temperature profiles

In a previous paper by Schmidt et al. (2008), from CHAllenging Minisatellite Payload (CHAMP) Global Positioning System (GPS) radio occultation data, a comparison was made between a Gaussian filter applied to the “complete” temperature profile and to its “separate” tropospheric and stratospheric height intervals, for gravity wave analyses. It was found that the separate filtering method considerably reduces a wave activity artificial enhancement near the tropopause, presumably due to the isolation process of the wave component. We now propose a simple approach to estimate the uncertainty in the calculation of the mean specific wave potential energy content, due exclusively to the filtering process of vertical temperature profiles, independently of the experimental origin of the data. The approach is developed through a statistical simulation, built up from the superposition of synthetic wave perturbations. These are adjusted by a recent gravity wave (GW) climatology and temperature profiles from reanalyses. A systematic overestimation of the mean specific wave potential energy content is detected and its variability with latitude, altitude, season and averaging height interval is highlighted.     

Use of halophytic plants for recycling NaCl in human liquid waste in a bioregenerative life support system

The purpose of this work was to develop technology for recycling NaCl containing in human liquid waste as intrasystem matter in a bioregenerative life support system (BLSS). The circulation of Na⁺ and Cl⁻ excreted in urine is achieved by inclusion of halophytes, i.e. plants that naturally inhabit salt-rich soils and accumulate NaCl in their organs. A model of Na⁺ and Cl⁻ recycling in a BLSS was designed, based on the NaCl turnover in the human–urine–nutrient solution–halophytic plant–human cycle. The study consisted of (i) selecting a halophyte suitable for inclusion in a BLSS, and (ii) determining growth conditions supporting maximal Na⁺ and Cl⁻ accumulation in the shoots of the halophyte growing in a nutrient solution simulating mineralized urine. For the selected halophytic plant, Salicornia europaea, growth rate under optimal conditions, biomass production and quantities of Na⁺ and Cl⁻ absorbed were determined. Characteristics of a plant production conveyor consisting of S.europaea at various ages, and allowing continuity of Na⁺ and Cl⁻ turnover, were estimated. It was shown that closure of the NaCl cycle in a BLSS can be attained if the daily ration of fresh Salicornia biomass for a BLSS inhabitant is approximately 360 g.