采用一种超支化聚硅氧烷改性二烯丙基双酚A改性双马来酰亚胺体系,对固化树脂的增韧效果进行了研究,并通过DSC分析了改性树脂体系的固化反应及其动力学。结果表明,当超支化聚硅氧烷的添加量为10%时,浇注体冲击强度达到最大,比未改性体系提高了62.8%;采用非等温DSC研究体系的固化动力学,该体系固化反应分为两步,表观活化能分别为ΔE1=81.14 k J/mol,ΔE2=89.40 k J/mol;固化反应级数分别为n1=0.91,n2=0.91。 相似文献
The effects of isothermal heat treatment on the semi-solid microstructure evolution of VW63Z (Mg-6Gd-3Y-0.4Zr, wt.%) alloy are studied. It shows that the microstructure of VW63Z alloy could transform from equiaxed crystal to semi-solid spherical crystal after isothermal heat treatment above 620 ºC. With the heating temperature elevating from 620 ºC to 635 ºC and the holding time prolonging from 10 min to 35 min, the liquid fraction increases gradually. The semi-solid microstructure evolution of VW63Z alloy can be divided into three stages, i.e., particle coarsening and spheroidization;particle necking, coalescence, and Ostwald ripening;and dynamic equilibrium. The semi-solid process window of VW63Z alloy ranges from 620 ºC to 635 ºC, where the best process parameters are holding at 635 ºC for 20 min?30 min. The solid fraction, the average particle size, and the shape factor are 41.1%?53.8%, 81.5 μm?83.2 μm, and 0.70?0.75, respectively. The maximum relative deviations of the solid fraction, the particle size, and the shape factor at different heights of the same billet are 44.6%, 17.4%, and 16.6%, respectively, which means that it should pay attention to the uniformity of edge and core of VW63Z alloy during isothermal heat treatment. The driving force of microstructure is supposed to be the reduction of solid-liquid interface free energy. 相似文献