Prebiotic significance of extraterrestrial ice photochemistry: detection of hydantoin in organic residues

The delivery of extraterrestrial organic materials to primitive Earth from meteorites or micrometeorites has long been postulated to be one of the origins of the prebiotic molecules involved in the subsequent apparition of life. Here, we report on experiments in which vacuum UV photo-irradiation of interstellar/circumstellar ice analogues containing H(2)O, CH(3)OH, and NH(3) led to the production of several molecules of prebiotic interest. These were recovered at room temperature in the semi-refractory, water-soluble residues after evaporation of the ice. In particular, we detected small quantities of hydantoin (2,4-imidazolidinedione), a species suspected to play an important role in the formation of poly- and oligopeptides. In addition, hydantoin is known to form under extraterrestrial, abiotic conditions, since it has been detected, along with various other derivatives, in the soluble part of organic matter of primitive carbonaceous meteorites. This result, together with other related experiments reported recently, points to the potential importance of the photochemistry of interstellar "dirty" ices in the formation of organics in Solar System materials. Such molecules could then have been delivered to the surface of primitive Earth, as well as other telluric (exo-) planets, to help trigger first prebiotic reactions with the capacity to lead to some form of primitive biomolecular activity.     

Global Properties of Solar Flares

This article broadly reviews our knowledge of solar flares. There is a particular focus on their global properties, as opposed to the microphysics such as that needed for magnetic reconnection or particle acceleration as such. Indeed solar flares will always remain in the domain of remote sensing, so we cannot observe the microscales directly and must understand the basic physics entirely via the global properties plus theoretical inference. The global observables include the general energetics—radiation in flares and mass loss in coronal mass ejections (CMEs)—and the formation of different kinds of ejection and global wave disturbance: the type II radio-burst exciter, the Moreton wave, the EIT “wave”, and the “sunquake” acoustic waves in the solar interior. Flare radiation and CME kinetic energy can have comparable magnitudes, of order 10³² erg each for an X-class event, with the bulk of the radiant energy in the visible-UV continuum. We argue that the impulsive phase of the flare dominates the energetics of all of these manifestations, and also point out that energy and momentum in this phase largely reside in the electromagnetic field, not in the observable plasma.     

Asymmetric precipitation in a coronal loop as explanation of a singular observed spectrum

Almost 10 years of solar submillimeter observations have shown new aspects of solar activity, such as the presence of rapid solar spikes associated with the launch of coronal mass ejections and an increasing submillimeter spectral component in flares. We analyse the singular microwave–submillimeter spectrum of an M class solar flare on 20 December, 2002. Flux density observations measured by Sun patrol telescopes and the Solar Submillimeter Telescope are used to build the radio spectrum, which is fitted using Ramaty’s code. At submillimeter frequencies the spectrum shows a component different from the microwave classical burst. The fitting is achieved proposing two homogeneous sources of emission. This theoretical fitting is in agreement with differential precipitation through a magnetically asymmetric loop or set of loops. From a coronal magnetic field model we infer an asymmetric magnetic structure at the flare location. The model proposed to quantify the differential precipitation rates due to the asymmetry results in a total precipitation ratio Q₂/Q₁≈10⁴–10⁵, where Q₁(Q₂) represents the total precipitation in the loop foot with the high (low) magnetic field intensity. This ratio agrees with the electron total number ratio of the two sources proposed to fit the radio spectrum.     

Determination of <Emphasis Type="Italic">Foton M-2</Emphasis> satellite attitude motion by the data of microacceleration measurements

The results of reconstruction of uncontrolled attitude motion of the Foton M-2 satellite using measurements with the accelerometer TAS-3 are presented. The attitude motion of this satellite has been previously determined by the measurement data of the Earth’s magnetic field and the angular velocity. The TAS-3 data for this purpose are used for the first time. These data contain a well-pronounced additional component which made impossible their direct employment for the reconstruction of the attitude motion and whose origin was unknown several years ago. Later it has become known that the additional component is caused by the influence of the Earth’s magnetic field. The disclosure of this fact allowed us to take into account a necessary correction in processing of TAS-3 data and to use them for the reconstruction of the attitude motion of Foton M-2. Here, a modified method of processing TAS-3 data is described, as well as results of its testing and employing. The testing consisted in the direct comparison of the motion reconstructed by the new method with the motion constructed by the magnetic measurements. The new method allowed us to find the actual motion of Foton M-2 in the period June 9, 2005–June 14, 2005, when no magnetic measurements were carried out.     

Optimization of transfers under constraints on the thrust direction: II

This paper completes the study of optimal transfers with constraints imposed on the thrust vector direction that was opened by paper [1]. The linear inhomogeneous and homogeneous constraints on the thrust direction are considered (specified either by equalities or inequalities), as well as mixed constraints. Some examples of the constraints are presented. A modified method of the transporting trajectory is applied in order to find the optimal transfer under the linear constraints on the thrust direction. This method also gives the necessary condition for a transfer possibility at a given constraint on the thrust direction. A numerical example is considered, in which the propellant consumption is analyzed for the cases of transfers with and without constraints.     

An analysis of low-frequency component in microacceleration measurements made onboard the <Emphasis Type="Italic">Foton M-2</Emphasis> satellite

The low-frequency component is investigated in the data of measurements performed onboard the Foton M-2 satellite with the three-component accelerometer TAS-3. Investigations consisted in comparison of this component with its calculated analog found from a reconstruction of the satellite’s attitude motion. The influence of the Earth’s magnetic field on the accelerometer readings is discovered by way of spectral analysis of the functions representing the results of determining the low-frequency microacceleration by two methods. After making correction for this influence, the results obtained by these two methods coincided within a root-mean-square error of less than 10^?6 m/s².     

Which solar EUV indices are best for reconstructing the solar EUV irradiance?

The solar EUV irradiance is of key importance for space weather. Most of the time, however, surrogate quantities such as EUV indices have to be used by lack of continuous and spectrally resolved measurements of the irradiance. The ability of such proxies to reproduce the irradiance from different solar atmospheric layers is usually investigated by comparing patterns of temporal correlations. We consider instead a statistical approach. The TIMED/SEE experiment, which has been continuously operating since February 2002, allows for the first time to compare in a statistical manner the EUV spectral irradiance to five EUV proxies: the sunspot number, the f10.7, Ca K, and Mg II indices, and the He I equivalent width.     

Influence of Body Waves,Instrumentation Resonances,and Prior Assumptions on Rayleigh Wave Ellipticity Inversion for Shallow Structure at the InSight Landing Site

Based on an updated model of the regolith’s elastic properties, we simulate the ambient vibrations background wavefield recorded by InSight’s Seismic Experiment for Interior Structure (SEIS) on Mars to characterise the influence of the regolith and invert SEIS data for shallow subsurface structure. By approximately scaling the synthetics based on seismic signals of a terrestrial dust devil, we find that the high-frequency atmospheric background wavefield should be above the self-noise of SEIS’s SP sensors, even if the signals are not produced within 100–200 m of the station. We compare horizontal-to-vertical spectral ratios and Rayleigh wave ellipticity curves for a surface-wave based simulation on the one hand with synthetics explicitly considering body waves on the other hand and do not find any striking differences. Inverting the data, we find that the results are insensitive to assumptions on density. By contrast, assumptions on the velocity range in the upper-most layer have a strong influence on the results also at larger depth. Wrong assumptions can lead to results far from the true model in this case. Additional information on the general shape of the curve, i.e. single or dual peak, could help to mitigate this effect, even if it cannot directly be included into the inversion. We find that the ellipticity curves can provide stronger constraints on the minimum thickness and velocity of the second layer of the model than on the maximum values. We also consider the effect of instrumentation resonances caused by the lander flexible modes, solar panels, and the SEIS levelling system. Both the levelling system resonances and the lander flexible modes occur at significantly higher frequencies than the expected structural response, i.e. above 35 Hz and 20 Hz, respectively. While the lander and solar panel resonances might be too weak in amplitude to be recorded by SEIS, the levelling system resonances will show up clearly in horizontal spectra, the H/V and ellipticity curves. They are not removed by trying to extract only Rayleigh-wave dominated parts of the data. However, they can be distinguished from any subsurface response by their exceptionally low damping ratios of 1% or less as determined by random decrement analysis. The same applies to lander-generated signals observed in actual data from a Moon analogue experiment, so we expect this analysis will be useful in identifying instrumentation resonances in SEIS data.     

Organic chemistry in Titan's atmosphere: new data from laboratory simulations at low temperature.

Many experiments have already been carried out to simulate organic chemistry on Titan, the largest satellite of Saturn. They can provide fruitful information on the nature of minor organic constituents likely to be present in Titan's atmosphere, both in gas and aerosol phases. Indeed, all the organic compounds but one already detected in Titan's atmosphere have been identified in simulation experiments. The exception, C4N2, as well as other compounds expected in Titan from theoretical modeling, such as other N-organics, and polyynes, first of all C6H2, have never been detected in experimental simulation thus far. All these compounds are thermally unstable, and the temperature conditions used during the simulation experiments were not appropriate. We have recently started a new program of simulation experiments with temperature conditions close to that of Titan's environment. It also uses dedicated analytical techniques and procedures compatible with the analysis of organics only stable at low temperatures, as well solid products of low stability in the presence of O2 and H2O. Spark discharge of N2-CH4 gas mixtures was carried out at low temperature in the range 100-150 K. Products were analysed by FTIR, GC and GC-MS techniques. GC-peaks were identified by their mass spectrum, and, in most cases, by comparison of the retention time and mass spectrum with standard ones. We report here the first detection in Titan simulation experiments of C6H2 and HC5N. Their abundance is a few percent relative to C4H2 and HC3N, respectively. Preliminary data on the solid products indicate an elemental composition corresponding to (H11C11N)n. These results open new prospects in the modeling of Titan's haze making.