Effect of temperature on the adsorption of adenine

Equilibrium adsorption isotherms for the purine base adenine on the surface of graphite crystals have been obtained at 30, 40, 50, and 60 degrees C by frontal analysis using water as a mobile phase. These data were fitted to the Langmuir isotherm model and interpreted in terms of the well-characterized adsorbate monolayer structure. A van't Hoff plot was used to estimate the adsorption enthalpy, -delta H degree which we determined to be 20 kJ mol-1. The susceptibility of nucleic acid bases to aqueous-phase hydrolysis may have been a limiting feature for their inclusion in the primordial genetic architecture; our results suggest that the effects of temperature and the presence of inorganic solids must also be included when assessing the prebiotic availability of adenine.     

Comparison of the effects induced by the ordinary (O-mode) and extraordinary (X-mode) polarized powerful HF radio waves in the high-latitude ionospheric <Emphasis Type="Italic">F</Emphasis> region

Using the results of coordinated experiments on the modification of the high-latitude ionosphere by powerful HF radio emission of the EISCAT/Heating facility, effects of the impact of powerful HF radio waves of the ordinary (O-mode) and extraordinary (Х-mode) polarization on the high-latitude ionospheric F region have been compared. During the experiments, a powerful HF radio wave was emitted in the magnetic zenith direction at frequencies within the 4.5–7.9 MHz range. The effective power of the emission was 150–650 MW. The behavior and characteristics of small-scale artificial ionospheric irregularities (SAIIs) during O- and X-heating at low and high frequencies are considered in detail. A principal difference has been found in the development of the Langmuir and ion–acoustic turbulence (intensified by the heating of the plasma and ion–acoustic lines in the spectrum of the EISCAT radar of incoherent scatter of radio waves) in the О- and Х-heating cycles after switching on the heating facility. It has been shown that, under the influence on the ionospheric plasma of a powerful HF radio wave of the Х-polarization, intense spectral components in the spectrum of the narrow-band artificial ionospheric radio emission (ARI) were registered at distances on the order of 1200 km from the heating facility.     

Banded electron cyclotron harmonic instability-a first comparison of theory and experiment

A study, which is the first of its kind, uses information derived from simultaneously measured wave spectra and particle distributions as the input to a theoretical linear instability model of an electrostatic cyclotron harmonic wave event recorded on GEOS-1. The presence of a hot loss cone component of the particle distribution is established experimentally, and the model accounts reasonably for the observed frequencies and relative strengths of the (n+1/2)f _c and upper hybrid emission features.     

A Portrait of the Nucleus of Comet 67P/Churyumov-Gerasimenko

In 2003, comet 67P/Churyumov–Gerasimenko was selected as the new target of the Rosetta mission as the most suitable alternative to the original target, comet 46P/Wirtanen, on the basis of orbital considerations even though very little was known about the physical properties of its nucleus. In a matter of a few years and based on highly focused observational campaigns as well as thorough theoretical investigations, a detailed portrait of this nucleus has been established that will serve as a baseline for planning the Rosetta operations and observations. In this review article, we present a novel method to determine the size and shape of a cometary nucleus: several visible light curves were inverted to produce a size–scale free three–dimensional shape, the size scaling being imposed by a thermal light curve. The procedure converges to two solutions which are only marginally different. The nucleus of comet 67P/Churyumov–Gerasimenko emerges as an irregular body with an effective radius (that of the sphere having the same volume) = 1.72 km and moderate axial ratios a/b = 1.26 and a/c = 1.5 to 1.6. The overall dimensions measured along the principal axis for the two solutions are 4.49–4.75 km, 3.54–3.77 km and 2.94–2.92 km. The nucleus is found to be in principal axis rotation with a period = 12.4–12.7 h. Merging all observational constraints allow us to specify two regions for the direction of the rotational axis of the nucleus: RA = 220°^+50° _−30° and Dec = −70^° ± 10^° (retrograde rotation) or RA = 40°^+50° _-30° and Dec = +70^°± 10^° (prograde), the better convergence of the various determinations presently favoring the first solution. The phase function, although constrained by only two data points, exhibits a strong opposition effect rather similar to that of comet 9P/Tempel 1. The definition of the disk–integrated albedo of an irregular body having a strong opposition effect raises problems, and the various alternatives led to a R-band geometric albedo in the range 0.045–0.060, consistent with our present knowledge of cometary nuclei. The active fraction is low, not exceeding ~ 7% at perihelion, and is probably limited to one or two active regions subjected to a strong seasonal effect, a picture coherent with the asymmetric behaviour of the coma. Our slightly downward revision of the size of the nucleus of comet 67P/Churyumov-Gerasimenko resulting from the present analysis (with the correlative increase of the albedo compared to the originally assumed value of 0.04), and our best estimate of the bulk density of 370 kg m⁻³, lead to a mass of ~ 8 × 10¹² kg which should ease the landing of Philae and insure the overall success of the Rosetta mission.     

The Swedish Small Satellite Program for Space Plasma Investigations

The success of the Swedish small satellite program, in combination with an active participation by Swedish research groups in major international missions, has placed Sweden in the frontline of experimental space research. The program started with the development of the research satellite Viking which was launched in 1986, for detailed investigations of the aurora. To date, Sweden has developed and launched a total of six research satellites; five for space plasma investigations; and the most recent satellite Odin, for research in astronomy and aeronomy. These fall into three main categories according to their physical dimension, financial cost and level of ambition: nano-satellites, micro-satellites, and mid-size satellites with ambitious scientific goals. In this brief review we focus on five space plasma missions, for which operations have ended and a comprehensive scientific data analysis has been conducted, which allows for a judgement of their role and impact on the progress in auroral research. Viking and Freja, the two most well-known missions of this program, were pioneers in the exploration of the aurora. The more recent satellites, Munin, Astrid, and Astrid-2 (category 1 and 2), proved to be powerful tools, both for testing new technologies and for carrying out advanced science missions. The Swedish small satellite program has been internationally recognized as cost efficient and scientifically very successful.     

Swan Observations of the Solar Wind Latitude Distribution and its Evolution Since Launch

SWAN is the first space instrument dedicated to the monitoring of the latitude distribution of the solar wind by the Lyman alpha method. The distribution of interstellar H atoms in the solar system is determined by their destruction during ionization charge-exchange with solar wind protons. Maps of sky Ly-α emission have been recorded regularly since launch. The upwind maximum emission region deviates strongly from the pattern that would be expected from a solar wind that is constant with latitude. It is divided in two lobes by a depression aligned with the solar equatorial plane, called the Lyman-alpha groove, due to enhanced ionization along the neutral sheet where the slow and dense solar wind is concentrated. The groove (or the anisotropy) is more pronounced in 1997 than in 1996, but it then decreases between 1997 and 1998. This revised version was published online in June 2006 with corrections to the Cover Date.     

Observational Evidence for Transfer of Plasma Across the Magnetopause

There is a long history of particle measurements that have established that plasma is being transferred across Earth's magnetopause in both directions. The paper reviews the nature of the observational evidence as well as the implications regarding the transfer mechanisms and their efficiencies.     

The Habitability of Venus

Space Science Reviews - Venus today is inhospitable at the surface, its average temperature of 750&nbsp;K being incompatible to the existence of life as we know it. However, the potential for...