Geochemistry of Carbonates on Mars: Implications for Climate History and Nature of Aqueous Environments

Ongoing research on martian meteorites and a new set of observations of carbonate minerals provided by an unprecedented series of robotic missions to Mars in the past 15 years help define new constraints on the history of martian climate with important crosscutting themes including: the CO₂ budget of Mars, the role of Mg-, Fe-rich fluids on Mars, and the interplay between carbonate formation and acidity. Carbonate minerals have now been identified in a wide range of localities on Mars as well as in several martian meteorites. The martian meteorites contain carbonates in low abundances (<1 vol.%) and with a wide range of chemistries. Carbonates have also been identified by remote sensing instruments on orbiting spacecraft in several surface locations as well as in low concentrations (2–5 wt.%) in the martian dust. The Spirit rover also identified an outcrop with 16 to 34 wt.% carbonate material in the Columbia Hills of Gusev Crater that strongly resembled the composition of carbonate found in martian meteorite ALH 84001. Finally, the Phoenix lander identified concentrations of 3–6 wt.% carbonate in the soils of the northern plains. The carbonates discovered to date do not clearly indicate the past presence of a dense Noachian atmosphere, but instead suggest localized hydrothermal aqueous environments with limited water availability that existed primarily in the early to mid-Noachian followed by low levels of carbonate formation from thin films of transient water from the late Noachian to the present. The prevalence of carbonate along with evidence for active carbonate precipitation suggests that a global acidic chemistry is unlikely and a more complex relationship between acidity and carbonate formation is present.     

Geochemical Consequences of Widespread Clay Mineral Formation in Mars’ Ancient Crust

Clays form on Earth by near-surface weathering, precipitation in water bodies within basins, hydrothermal alteration (volcanic- or impact-induced), diagenesis, metamorphism, and magmatic precipitation. Diverse clay minerals have been detected from orbital investigation of terrains on Mars and are globally distributed, indicating geographically widespread aqueous alteration. Clay assemblages within deep stratigraphic units in the Martian crust include Fe/Mg smectites, chlorites and higher temperature hydrated silicates. Sedimentary clay mineral assemblages include Fe/Mg smectites, kaolinite, and sulfate, carbonate, and chloride salts. Stratigraphic sequences with multiple clay-bearing units have an upper unit with Al-clays and a lower unit with Fe/Mg-clays. The typical restriction of clay minerals to the oldest, Noachian terrains indicates a distinctive set of processes involving water-rock interaction that was prevalent early in Mars history and may have profoundly influenced the evolution of Martian geochemical systems. Current analyses of orbital data have led to the proposition of multiple clay-formation mechanisms, varying in space and time in their relative importance. These include near-surface weathering, formation in ice-dominated near-surface groundwaters, and formation by subsurface hydrothermal fluids. Near-surface, open system formation of clays would lead to fractionation of Mars’ crustal reservoir into an altered crustal reservoir and a sedimentary reservoir, potentially involving changes in the composition of Mars’ atmosphere. In contrast, formation of clays in the subsurface by either aqueous alteration or magmatic cooling would result in comparatively little geochemical fractionation or interaction of Mars’ atmospheric, crustal, and magmatic reservoirs, with the exception of long-term sequestration of water. Formation of clays within ice would have geochemical consequences intermediate between these endmembers. We outline the future analyses of orbital data, in situ measurements acquired within clay-bearing terrains, and analyses of Mars samples that are needed to more fully elucidate the mechanisms of martian clay formation and to determine the consequences for the geochemical evolution of the planet.     

SolidWorks 2013简化了3D设计

Dassault Systèmes作为一家3D体验公司以及在3D设计软件、3D数字化装配和产品生命周期管理(PLM)解决方案领域的全球领导厂商,近期推出了SolidWorks(@)2013,该产品包含新增的和经改进的设计工具,以增强协作、加快模型型创建并简化产品开发流程.     

Rosina – Rosetta Orbiter Spectrometer for Ion and Neutral Analysis

The Rosetta Orbiter Spectrometer for Ion and Neutral Analysis (ROSINA) will answer important questions posed by the mission’s main objectives. After Giotto, this will be the first time the volatile part of a comet will be analyzed in situ. This is a very important investigation, as comets, in contrast to meteorites, have maintained most of the volatiles of the solar nebula. To accomplish the very demanding objectives through all the different phases of the comet’s activity, ROSINA has unprecedented capabilities including very wide mass range (1 to >300 amu), very high mass resolution (m/Δ m > 3000, i.e. the ability to resolve CO from N₂ and ¹³C from ¹²CH), very wide dynamic range and high sensitivity, as well as the ability to determine cometary gas velocities, and temperature. ROSINA consists of two mass spectrometers for neutrals and primary ions with complementary capabilities and a pressure sensor. To ensure that absolute gas densities can be determined, each mass spectrometer carries a reservoir of a calibrated gas mixture allowing in-flight calibration. Furthermore, identical flight-spares of all three sensors will serve for detailed analysis of all relevant parameters, in particular the sensitivities for complex organic molecules and their fragmentation patterns in our electron bombardment ion sources.     

飞机日历寿命确定的区域定寿法

给出一种飞机结构日历寿命的区域定寿法,该方法根据腐蚀环境的差异,把全国各型飞机划分成若干个区域,分别编制出每个区域的腐蚀环境谱,然后用每个区域的腐蚀环境谱,分别进行该区域中的各种机型飞机的日历寿命确定,这与飞机疲劳寿命确定方法有较大不同。用该方法确定飞机日历寿命可以提高定寿效率,缩短定寿时间,节约定寿经费。     

用重要性抽样方法估计分组码同时纠错和检错时的性能

研究用重要性抽样仿真方法估计线性分组码同时纠错和检错时的不可检错误概率。从理论上得到了最佳偏置转移概率和仿真效率的表达式。对 (1 5,7) BCH码和 (2 3,12 ) Golay码的仿真表明,重要性抽样是一种非常有效的仿真方法。     

RPC-MIP: the Mutual Impedance Probe of the Rosetta Plasma Consortium

The main objective of the Mutual Impedance Probe (MIP), part of the Rosetta Plasma Consortium (RPC), is to measure the electron density and temperature of Comet 67P/Churyumov-Gerasimenko’s coma, in particular inside the contact surface. Furthermore, MIP will determine the bulk velocity of the ionised outflowing atmosphere, define the spectral distribution of natural plasma waves, and monitor dust and gas activities around the nucleus. The MIP instrumentation consists of an electronics board for signal processing in the 7 kHz to 3.5 MHz range and a sensor unit of two receiving and two transmitting electrodes mounted on a 1-m long bar. In addition, the Langmuir probe of the RPC/LAP instrument that is at about 4 m from the MIP sensor can be used as a transmitter (in place of the MIP ones) and MIP as a receiver in order to have access to the density and temperature of plasmas at higher Debye lengths than those for which the MIP is originally designed.     

Primordial matter in the outer solar system: A study of its chemical composition from remote spectroscopic analysis

Our knowledge of the primordial matter from the objects of the outer solar system has made a considerable progress over the past years, in spite of the lack of any in situ measurements of these objects at the present time. The recent progress of ground-based instrumentation and the launch of the two Voyager fly-by missions have provided a huge amount of new informations about the origin and the evolution of the primitive Solar System objects.The most significant discoveries concerning the atmospheres of the Giant Planets can be summarized as follows: (1) there does not seem to be any differentiation in the internal structure of Jupiter during the planet's history; thus, the H₂/He ratio measured on Jupiter seems to be representative of the H/He ratio of the Primordial Nebula; (2) there is some evidence for a helium differentiation, relative to hydrogen, in Saturn's interior; (3) there seems to be a carbon enrichment on both Jupiter and Saturn by a factor about 2; this result is consistent with a model in which the planetary core is formed first, and the atmosphere accreted by this core in a second stage; (4) the D/H ratio measured on Jupiter should be representative of the D/H value in the Primordial Nebula, 4.5 billion years ago; this value is 2 to 5 times larger than the mean value measured in the local interstellar medium now; (5) Titan's atmosphere is dominated by nitrogen and contains traces of organic and prebiotic molecules (HCN, C₂N₂, HC₃N); the chemical composition of Titan's atmosphere could be favorable for the early stages of life development.The small bodies of the Solar System — asteroïds and comets — are still very poorly known. However they contain a key information about the physical and chemical properties of dust in the Primordial Nebula and the interstellar medium. With the launch of expected fly-by missions towards Comet Halley and, possibly, towards asteroïds, we may hope to know a new development of our understanding of these objects, comparable to the progress we have known on the Giant Planets over the past ten years.