Aqueous corrosion of phosphide minerals from iron meteorites: a highly reactive source of prebiotic phosphorus on the surface of the early Earth

We present the results of an experimental study of aqueous corrosion of Fe-phosphide under conditions relevant to the early Earth. The results strongly suggest that iron meteorites were an important source of reactive phosphorus (P), a requirement for the formation of P-based life. We further demonstrate that iron meteorites were an abundant source of phosphide minerals early in Earth history. Phosphide corrosion was studied in five different solutions: deionized water, deionized water buffered with sodium bicarbonate, deionized water with dissolved magnesium and calcium chlorides, deionized water containing ethanol and acetic acid, and deionized water containing the chlorides, ethanol, and acetic acid. Experiments were performed in the presence of both air and pure Ar gas to evaluate the effect of atmospheric chemistry. Phosphide corrosion in deionized water results in a metastable mixture of mixed-valence, P-bearing ions including pyrophosphate and triphosphate, key components for metabolism in modern life. In a pH-buffered solution of NaHCO(3), the condensed and reduced species diphosphonate is an abundant corrosion product. Corrosion in ethanol- and acetic acid-containing solutions yields additional P-bearing organic molecules, including acetyl phosphonate and a cyclic triphosphorus molecule. Phosphonate is a major corrosion product of all experiments and is the only P-bearing molecule that persists in solutions with high concentrations of magnesium and calcium chlorides, which suggests that phosphonate may have been a primitive oceanic source of P. The stability and reactivity of phosphonate and hypophosphite in solution were investigated to elucidate reaction mechanisms and the role of mineral catalysts on P-solution chemistry. Phosphonate oxidation is rapid in the presence of Fe metal but negligible in the presence of magnetite and in the control sample. The rate of hypophosphite oxidation is independent of reaction substrate.     

Neutral buoyancy and sleep-deprived serum factors alter expression of cytokines regulating osteogenesis

We examined expression of genes associated with cytokine production, and genes implicated in regulating bone metabolism, in bone stromal and osteoblast cells incubated under standard ground conditions and under conditions of neutral buoyancy, and in the presence/absence of serum from normal or sleep-deprived mice. We observed a clear interaction between these two conditions (exposure to neutral buoyancy and serum stimulation) in promoting enhanced osteoclastogenesis. Both conditions independently altered expression of a number of cytokines implicated in the regulation of bone metabolism. However, using stromal cells from IL-1 and TNFx cytokine(r) KO mice, we concluded that the increased bone loss under microgravity conditions was not primarily cytokine mediated.     

Electrostatic Noise Spectrum at the Electron Cyclotron Frequency and Electromagnetic Emission in the Inhomogeneous Plasma of the Topside Ionosphere

Measurements of the wave emission of the topside ionosphere made onboard the APEX satellite using the electric component of the wave field in the 0.1–10 MHz frequency band are presented. At middle latitudes a wave intensity decrease was observed in the broad-band spectrum of the electrostatic noise at the electron cyclotron frequency. It is shown that a break in the spectrum of electrostatic modes at the electron cyclotron frequency (the absence of the plasma eigen-frequencies) may be a cause of the observed effect. The increase of the intensity at the electron cyclotron frequency in the ionospheric trough and at latitudes above the trough region as compared to middle latitudes may be explained by the capture by plasma irregularities of the electromagnetic emission of the auroral electron fluxes.__________Translated from Kosmicheskie Issledovaniya, Vol. 43, No. 3, 2005, pp. 201–208.Original Russian Text Copyright © 2005 by Izhovkina, Prutensky, Pulinets, Kiraga, Klos, Rothkael.     

Stability of resonance rotation of a satellite with respect to its center of mass in the orbit plane

The stability of resonance oscillations and rotations of a satellite in the plane of its orbit in the case when the difference of the moments of inertia with respect to the principal axes lying in the orbit plane is small is determined at a given rotation number m by the sign of function Φ_m(e), introduced by F.L. Chernous’ko in 1963. In this paper, convenient analytical representations of functions Φ_m(e) are described in the form of integrals and series of Bessel functions regular at e → 1^?. Values of Φ_m(1) are calculated in explicit form. A theorem about the double asymptotic form of functions Φ_m(e) at m → ∞ and e → 1^? is proved by the saddlepoint method.     

华东地区围护结构节能研究

根据南京市的典型年逐时气象参数，对于该市的某一座高层建筑物，应用自编的逐时动态负荷模拟程序，输入围护结构（窗户、墙体和屋顶）相关的物理参数及其与周围环境的关系（地点及朝向等），计算围护结构冬季采暖期散热量及夏季制冷得热量。结果表明，采用双层塑窗代替单层塑窗，使用节能墙体代替传统墙体能够使得冬季围护结构传散热量减少51％，夏季围护结构总得热量减少46％。因此，这一结果为华东地区建筑节能技术提供了理论依据。     

无穷观问题的研究(Ⅲ)——‘每一''与‘所有''

本组系列论文（I）－（Ⅴ）从数学和认识论的角度系统地研究了无穷观问题的历史发展和现状，确立了无穷观背景世界的三分法原则，指出了两种穷观相互排斥的局限性，形成了统一两种无穷于同一框架中的基本观点，并建立了一个统一实无限与潜无限于同一框架中的公理集合论系统APAS。     

金属载体上线天线阻抗与辐射特性的矩量法研究

用线网格模拟金属载体表面，应用矩量法求出天线及载体网格上的电流分布，据此研究在该金属载体影响下的天线特性，在计算阻抗矩阵元素时，利用了非对称正弦偶极子辐射场的精确表达式，并采用了直接复数积分，简化了计算公式，本文给出了几种金属载体上线天线的阻抗与辐射特性的计算结果，它们与有关文献上的数据或实验结果一致，最后计算了一种舰船简单模型上两根线天线的远区辐射场及它们的自阻抗与互阻抗。     

飞机穿越微下击暴流风切变的智能控制

在应用模糊逻辑建模与辨识方法建立微下击暴流风切变模型的基础上，根据恒定俯仰姿态改出微下击暴流的飞行引导策略，提出了一种改出微下击暴流风切变的模糊反馈控制系统，并将遗传算法应用于该模糊逻辑控制器的设计。结果表明，本文提出的建模方法能够更真实地反映出飞机穿越微下击暴流风场的动态特性；采用模糊逻辑控制器，可使得飞机在穿越微下击暴流风场时具有较好的改出性能；另外，遗传算法的应用对已设计的模糊逻辑控制器进行了优化，进一步改善了飞机穿越微下击暴流的性能。     

基于批生产的逐段式车间作业调度算法

探讨了离散作业型（Job shop）车间中的作业调度的分阶段模型，并根据离散作业调度的阶段性提出了基于作业状态空间的逐段式车间作业调度算法，通过对一个实际车间作业调度仿真比较，此算法运算速度比最短加工时间（SPT）和最少工作量剩余（LWR）算法快，其调度结果在实际作业车间具有可执行性。     

一种新颖组合变换器拓扑研究与应用

基于电源模块并联和串联的思想，提出了一种新颖双管正激组合变换器拓扑，克服了双管正激变换器副边二极管电压应力过高，输出电压和电流脉动大，只能应用于输出中低压场合的缺点，具有副边二极管电压应力低，可靠性高，原边开关管电流应力低，输出电压和电流脉动小，磁芯元件体积小等优点，本文对该新颖组合变换器进行分析，仿真和实验，表明适合应用于输入中，高电压，输出高压，大电流场合，并成功应用于某型飞机6KVA逆变器前级变换器，各项技术指标均符合设计要求。