Aqueous corrosion of phosphide minerals from iron meteorites: a highly reactive source of prebiotic phosphorus on the surface of the early Earth

We present the results of an experimental study of aqueous corrosion of Fe-phosphide under conditions relevant to the early Earth. The results strongly suggest that iron meteorites were an important source of reactive phosphorus (P), a requirement for the formation of P-based life. We further demonstrate that iron meteorites were an abundant source of phosphide minerals early in Earth history. Phosphide corrosion was studied in five different solutions: deionized water, deionized water buffered with sodium bicarbonate, deionized water with dissolved magnesium and calcium chlorides, deionized water containing ethanol and acetic acid, and deionized water containing the chlorides, ethanol, and acetic acid. Experiments were performed in the presence of both air and pure Ar gas to evaluate the effect of atmospheric chemistry. Phosphide corrosion in deionized water results in a metastable mixture of mixed-valence, P-bearing ions including pyrophosphate and triphosphate, key components for metabolism in modern life. In a pH-buffered solution of NaHCO(3), the condensed and reduced species diphosphonate is an abundant corrosion product. Corrosion in ethanol- and acetic acid-containing solutions yields additional P-bearing organic molecules, including acetyl phosphonate and a cyclic triphosphorus molecule. Phosphonate is a major corrosion product of all experiments and is the only P-bearing molecule that persists in solutions with high concentrations of magnesium and calcium chlorides, which suggests that phosphonate may have been a primitive oceanic source of P. The stability and reactivity of phosphonate and hypophosphite in solution were investigated to elucidate reaction mechanisms and the role of mineral catalysts on P-solution chemistry. Phosphonate oxidation is rapid in the presence of Fe metal but negligible in the presence of magnetite and in the control sample. The rate of hypophosphite oxidation is independent of reaction substrate.     

Geocorona of Hot Plasma

This review deals with basic results of experimental and theoretical studies (numerical simulations included) of the distributions, composition, and dynamics of particles of a hot plasma in the geomagnetosphere. Attention is drawn mainly to the ring current and the plasma sheet of the magnetotail, which play a key role in physics of the magnetosphere. The integrity (unity) of the system outer radiation belt–ring current–near plasma sheet is substantiated (the concept of a hot plasma geocorona). From the viewpoint of this concept, the physical processes and theories are considered that were suggested in order to explain the structure and dynamics of the hot magnetosphere plasma. An emphasis is made on disputable issues and topical problems so far unsolved.     

Radio Occultation Measurements of the Radio Wave Absorption and the Sulfuric Acid Vapor Content in the Atmosphere of Venus

The results of the determination of centimeter ( = 5 cm) radio waves absorption in the radio occultation experiments, carried out using the Venera-15and Venera-16spacecraft, are presented. The altitude distribution of the absorber substance is analyzed. The absorbing layer is shown to exist at altitudes of 64 to 58 km in the near-polar regions of the planet. At middle latitudes such an absorbing layer was not found. In the altitude range from 56 to 46 km the radio wave absorption by the sulfuric acid (H₂SO₄) vapor is observed. The content of the sulfuric acid vapor is shown to increase with decreasing altitude: in the mid-latitude region at altitudes of 56.7 and 53 km it equals 5 and 20 ppm, respectively, and at polar latitudes the same content of H₂SO₄vapor is observed at altitudes of 51.2 and 47 km, respectively. A comparison of these results with the data of radio wave absorption in the = 13 cm band, obtained in the Pioneer Venus Orbiterradio occultation experiments, leads to the conclusion that the obtained values of the sulfuric acid vapor content well agree in the regions of overlap of the data.     

Effect of volatile metabolites of dill, radish and garlic on growth of bacteria

In a model experiment plants were grown in sealed chambers on expanded clay aggregate under the luminance of 150 W/m2 PAR and the temperature of 24 degrees C. Seven bacterial strains under investigation, replicated on nutrient medium surface in Petri dishes, were grown in the atmosphere of cultivated plants. Microbial response was evaluated by the difference between colony size in experiment and in control. In control, bacteria grew in the atmosphere of clean air. To study the effects of volatile metabolites of various plant on microbial growth, the experimental data were compared with the background values defined for each individual experiment. Expanded clay aggregate, luminance, temperature, and sealed chamber (without plants) for the background were the same. Volatile metabolites from 28-days old radish plants have been reliably established to have no effect on the growth of microbes under investigation. Metabolites of 30-days old dill and 50-days old garlic have been established to have reliable bacteriostatic effect on the growth of three bacterial strains. Dill and garlic have been found to have different range of effects of volatile substances on bacterial growth. Volatile metabolites of dill and garlic differed in their effect on the sensitivity spectrum of bacteria. An attempt has been made to describe the obtained data mathematically.     

Martian polar expeditions: problems and solutions.

The Martian polar ice caps are regions of substantial scientific interest, being the most dynamic regions of Mars. They are volatile sinks and thus closely linked to Martian climatic conditions. Because of their scale and the precedent set by the past history of polar exploration on Earth, it is likely that an age of polar exploration will emerge on the surface of Mars after the establishment of a capable support structure at lower latitudes. Expeditions might be launched either from a lower latitude base camp or from a human-tended polar base. Based on previously presented expeditionary routes to the Martian poles, in this paper a "spiral in-spiral out" unsupported transpolar assault on the Martian north geographical pole is used as a Reference expedition to propose new types of equipment for the human polar exploration of Mars. Martian polar "ball" tents and "hover" modifications to the Nansen sledge for sledging on CO2-containing water ice substrates under low atmospheric pressures are suggested as elements for the success of these endeavours.Other challenges faced by these expeditions are quantitatively and qualitatively addressed.     

Making space for history

This report summarizes the presentations given at the third annual British Rocketry Oral-History Project, held in Surrey, UK in April 2001. A wide range of papers was given (to an equally diverse audience), covering past and present developments in air and space, both military and civilian. Many of the scientists and engineers who had worked on specific projects were present and their personal reminiscences enlivened proceedings. The importance of history in understanding not only the past but also the future of space efforts was emphasized.     

Mineralogical biosignatures and the search for life on Mars

If life ever existed, or still exists, on Mars, its record is likely to be found in minerals formed by, or in association with, microorganisms. An important concept regarding interpretation of the mineralogical record for evidence of life is that, broadly defined, life perturbs disequilibria that arise due to kinetic barriers and can impart unexpected structure to an abiotic system. Many features of minerals and mineral assemblages may serve as biosignatures even if life does not have a familiar terrestrial chemical basis. Biological impacts on minerals and mineral assemblages may be direct or indirect. Crystalline or amorphous biominerals, an important category of mineralogical biosignatures, precipitate under direct cellular control as part of the life cycle of the organism (shells, tests, phytoliths) or indirectly when cell surface layers provide sites for heterogeneous nucleation. Biominerals also form indirectly as by-products of metabolism due to changing mineral solubility. Mineralogical biosignatures include distinctive mineral surface structures or chemistry that arise when dissolution and/or crystal growth kinetics are influenced by metabolic by-products. Mineral assemblages themselves may be diagnostic of the prior activity of organisms where barriers to precipitation or dissolution of specific phases have been overcome. Critical to resolving the question of whether life exists, or existed, on Mars is knowing how to distinguish biologically induced structure and organization patterns from inorganic phenomena and inorganic self-organization. This task assumes special significance when it is acknowledged that the majority of, and perhaps the only, material to be returned from Mars will be mineralogical.     

Dynamics of Planetary Waves in the Ionosphere as Observed from GPS Satellites

The GPS satellite data are used to study the dynamics of the ionospheric total electron content (TEC) over Central Europe in the summer season from June 23 to September 30, 1996. The TEC variations within the range of periods typical of the planetary waves were found to be nearly synchronous with the neutral wind variations in the mesosphere and with the variations in the occurrence of ionospheric sporadic layers. The observed TEC variations were interpreted as the result of penetration of energy carried by nonstationary Rossby waves to the upper atmospheric altitudes.     

Synthesis of biomass and utilization of plants wastes in a physical model of biological life-support system

The paper considers problems of biosynthesis of higher plants' biomass and "biological incineration" of plant wastes in a working physical model of biological LSS. The plant wastes are "biologically incinerated" in a special heterotrophic block involving Californian worms, mushrooms and straw. The block processes plant wastes (straw, haulms) to produce soil-like substrate (SLS) on which plants (wheat, radish) are grown. Gas exchange in such a system consists of respiratory gas exchange of SLS and photosynthesis and respiration of plants. Specifics of gas exchange dynamics of high plants--SLS complex has been considered. Relationship between such a gas exchange and PAR irradiance and age of plants has been established. Nitrogen and iron were found to the first to limit plants' growth on SLS when process conditions are deranged. The SLS microflora has been found to have different kinds of ammonifying and denitrifying bacteria which is indicative of intensive transformation of nitrogen-containing compounds. The number of physiological groups of microorganisms in SLS was, on the whole, steady. As a result, organic substances--products of exchange of plants and microorganisms were not accumulated in the medium, but mineralized and assimilated by the biocenosis. Experiments showed that the developed model of a man-made ecosystem realized complete utilization of plant wastes and involved them into the intrasystem turnover.     

Plasma irregularities in unstable outer ionosphere according to the Intercosmos-Bulgaria-1300 satellite data

The results of the satellite low-latitude and mid-latitude measurements of the disturbed plasma concentration, electron temperature, and quasi-stable electric field at heights of ～900 km after sunset are discussed. It is shown that the sharp fronts of changes in the electron temperature and plasma density observed in the experiment onboard the Intercosmos-Bulgaria-1300 satellite in the low-latitude (and equatorial) outer ionosphere can be related to damping of the oscillations of plasma electrons at local decreases of the plasma density (plasma “pits”) and formation of the vortex plasma structures at density and temperature gradients, which promotes conservation of ionosphere irregularities and makes the fronts of concentration variations steeper. Nonmonotonic variations in the plasma conductivity for the ionosphere currents in unstable plasma can be a cause of observed nonmonotonic disturbances of the vertical component of the “constant” electric field.