Geochemical Reservoirs and Timing of Sulfur Cycling on Mars

Sulfate-dominated sedimentary deposits are widespread on the surface of Mars, which contrasts with the rarity of carbonate deposits, and indicates surface waters with chemical features drastically different from those on Earth. While the Earth’s surface chemistry and climate are intimately tied to the carbon cycle, it is the sulfur cycle that most strongly influences the Martian geosystems. The presence of sulfate minerals observed from orbit and in-situ via surface exploration within sedimentary rocks and unconsolidated regolith traces a history of post-Noachian aqueous processes mediated by sulfur. These materials likely formed in water-limited aqueous conditions compared to environments indicated by clay minerals and localized carbonates that formed in surface and subsurface settings on early Mars. Constraining the timing of sulfur delivery to the Martian exosphere, as well as volcanogenic H₂O is therefore central, as it combines with volcanogenic sulfur to produce acidic fluids and ice. Here, we reassess and review the Martian geochemical reservoirs of sulfur from the innermost core, to the mantle, crust, and surficial sediments. The recognized occurrences and the mineralogical features of sedimentary sulfate deposits are synthesized and summarized. Existing models of formation of sedimentary sulfate are discussed and related to weathering processes and chemical conditions of surface waters. We also review existing models of sulfur content in the Martian mantle and analyze how volcanic activities may have transferred igneous sulfur into the exosphere and evaluate the mass transfers and speciation relationships between volcanic sulfur and sedimentary sulfates. The sedimentary clay-sulfate succession can be reconciled with a continuous volcanic eruption rate throughout the Noachian-Hesperian, but a process occurring around the mid-Noachian must have profoundly changed the composition of volcanic degassing. A hypothetical increase in the oxidation state or in water content of Martian lavas or a decrease in atmospheric pressure is necessary to account for such a change in composition of volcanic gases. This would allow the pre mid-Noachian volcanic gases to be dominated by water and carbon-species but late Noachian and Hesperian volcanic gases to be sulfur-rich and characterized by high SO₂ content. Interruption of early dynamo and impact ejection of the atmosphere may have decreased the atmospheric pressure during the early Noachian whereas it remains unclear how the redox state or water content of lavas could have changed. Nevertheless, volcanic emission of SO₂ rich gases since the late Noachian can explain many features of Martian sulfate-rich regolith, including the mass of sulfate and the particular chemical features (i.e. acidity) of surface waters accompanying these deposits. How SO₂ impacted on Mars’s climate, with possible short time scale global warming and long time scale cooling effects, remains controversial. However, the ancient wet and warm era on Mars seems incompatible with elevated atmospheric sulfur dioxide because conditions favorable to volcanic SO₂ degassing were most likely not in place at this time.     

Experimental and theoretical burning of solid rocket propellants near the pressure deflagration limit

Burning of composite solid rocket propellants near the pressure deflagration limit (PDL) was studied experimentally in two different test chambers. The propellant tested was a nonmetallized ammonium perchlorate-based composite propellant (AP 84/CTPB 16). Measurements were taken of the regression rate, oscillations frequency and flame luminosity. Self-sustained oscillations were detected near the PDL that matched reasonably well the predictions of the analytical nonlinear stability theory and of the numerically solved nonlinear mathematical model. Both experimental and numerical results show the burning rate oscillations near the PDL due to statically unstable burning, that is the only combustion regime possible below a certain pressure. When pressure is further reduced the amplitude of the oscillations increases and their frequency decreases, until extinction follows abruptly below a pressure that corresponds to the PDL.     

The comprehensive aerospace index (CASI): Tracking the economic performance of the aerospace industry

In this paper, we described the Comprehensive AeroSpace Index (CASI), a financial index aimed at representing the economic performance of the aerospace industry. CASI is build upon a data set of approximately 20 years of daily close prices set, from January 1987 to June 2007, from a comprehensive sample of leading aerospace-related companies with stocks negotiated on the New York Exchange (NYSE) and on the over-the-counter (OTC) markets. We also introduced the sub-indices CASI-AERO, for aeronautical segment, and CASI-SAT, for satellite segment, and considered the relation between them. These three indices are compared to others aerospace indices and to more traditional general financial indices like DJIA, S&P500 and Nasdaq. Our results have shown that the CASI is an index that describes very well the aerospace sector behavior, since it is able to reflect the aeronautical segment comportment as well as the satellite one. Therefore, in this sense, it can be considered as a representative index of the aerospace sector. Moreover, the creation of two sub-indices, the CASI-AERO and the CASI-SAT, allows to elucidate capital movements within the aerospace sector, particularly those of speculative nature, like the dot.com bubble and crash of 1998–2001.     

Dynamics and Composition of Rings

Planetary rings are found around all four giant planets of our solar system. These collisional and highly flattened disks exhibit a whole wealth of physical processes involving dust grains up to meter-sized boulders. These processes, together with ring composition, can help understand better the formation and evolution of proto-satellite and proto-planetary disks in the early solar system. The present chapter reviews some fundamental aspects of ring dynamics and composition. The forthcoming exploration of the Saturn system by the Cassini mission will bring both high resolution and time-dependent information on Saturn’s rings.     

The Planets and Titan Observed by ISO

Infrared spectroscopic observations of planets and Saturn's satellite Titan with the Infrared Space Observatory led to many significant discoveries that improved our understanding on the formation, physics and chemistry of these objects. The prime results achieved by ISO are: (1) a new and consistent determination of the D/H ratios on the giant planets and Titan; (2) the first precise measurement of the ¹⁵N/¹⁴N ratio in Jupiter, a valuable indicator of the protosolar nitrogen isotopic ratio; (3) the first detection of an external oxygen flux for all giant planets and Titan; (4) the first detection of some stratospheric hydrocarbons (CH₃, C₂H₄, CH₃C₂H, C₄H₂, C₆H₆); (5) the first detection of tropospheric water in Saturn; (6) the tentative detection of carbonate minerals on Mars; (7) the first thermal lightcurve of Pluto. Based on observations with ISO, an ESA project with instruments funded by ESA Member States (especially the PI countries: France, Germany, The Netherlands, and the United Kingdom), and with the participation of ISAS and NASA.     

Modeling irregular small bodies gravity field via extreme learning machines and Bayesian optimization

Close proximity operations around small bodies are extremely challenging due to their uncertain dynamical environment. Autonomous guidance and navigation around small bodies require fast and accurate modeling of the gravitational field for potential on-board computation. In this paper, we investigate a model-based, data-driven approach to compute and predict the gravitational acceleration around irregular small bodies. More specifically, we employ Extreme Learning Machine (ELM) theories to design, train and validate Single-Layer Feedforward Networks (SLFN) capable of learning the relationship between the spacecraft position and the gravitational acceleration. ELM-base neural networks are trained without iterative tuning therefore dramatically reducing the training time. Analysis of performance in constant density models for asteroid 25143 Itokawa and comet 67/P Churyumov-Gerasimenko show that ELM-based SLFN are able learn the desired functional relationship both globally and in selected localized areas near the surface. The latter results in a robust neural algorithm for on-board, real-time calculation of the gravity field needed for guidance and control in close-proximity operations near the asteroid surface.     

Potential fossil endoliths in vesicular pillow basalt, Coral Patch Seamount, eastern North Atlantic Ocean

The chilled rinds of pillow basalt from the Ampère-Coral Patch Seamounts in the eastern North Atlantic were studied as a potential habitat of microbial life. A variety of putative biogenic structures, which include filamentous and spherical microfossil-like structures, were detected in K-phillipsite-filled amygdules within the chilled rinds. The filamentous structures (～2.5 μm in diameter) occur as K-phillipsite tubules surrounded by an Fe-oxyhydroxide (lepidocrocite) rich membranous structure, whereas the spherical structures (from 4 to 2 μm in diameter) are associated with Ti oxide (anatase) and carbonaceous matter. Several lines of evidence indicate that the microfossil-like structures in the pillow basalt are the fossilized remains of microorganisms. Possible biosignatures include the carbonaceous nature of the spherical structures, their size distributions and morphology, the presence and distribution of native fluorescence, mineralogical and chemical composition, and environmental context. When taken together, the suite of possible biosignatures supports the hypothesis that the fossil-like structures are of biological origin. The vesicular microhabitat of the rock matrix is likely to have hosted a cryptoendolithic microbial community. This study documents a variety of evidence for past microbial life in a hitherto poorly investigated and underestimated microenvironment, as represented by the amygdules in the chilled pillow basalt rinds. This kind of endolithic volcanic habitat would have been common on the early rocky planets in our Solar System, such as Earth and Mars. This study provides a framework for evaluating traces of past life in vesicular pillow basalts, regardless of whether they occur on early Earth or Mars.     

Optical,ultraviolet, and infrared observations of isolated neutron stars

Forty years passed since the optical identification of the first isolated neutron star (INS), the Crab pulsar. 25 INSs have been now identified in the optical (O), near-ultraviolet (nUV), or near-infrared (nIR), hereafter UVOIR, including rotation-powered pulsars (RPPs), magnetars, and X-ray-dim INSs (XDINSs), while deep investigations have been carried out for compact central objects (CCOs), Rotating RAdio transients (RRATs), and high-magnetic field radio pulsars (HBRPs). In this review I describe the status of UVOIR observations of INSs, their emission properties, and I present the results from recent observations.     

Ground and satellite-based observations of ionospheric plasma bubbles and blobs at 5.65° latitude in the Brazilian sector

This investigation uses simultaneous observations from all-sky imager system and an ionosonde collocated at Araguatins (5.65° S, 48.07° W and dip-latitude of 4.17° S), a near-equatorial region in Brazil. These simultaneous observations were used to investigate the occurrence of plasma bubbles and blobs in the field of the imaging system and their association with atypical range Spread-F signature in ionograms. Also, in-situ observation of plasma density from Swarm satellites were used to support the ground-based observations. Using a few cases, a methodology will be established to identify in the plasma blobs (atypical ESF) in the ionograms when there is the simultaneous observation of plasma bubbles and blobs in the field of view of the ionosonde. For this purpose, simultaneous sequence of OI 630.0 nm nightglow images and ionograms are presented for different case studies; 1. when there is the absence of a plasma bubble or blob, 2. when there is only the occurrence of plasma bubbles and 3. when there is the occurrence of plasma bubbles and blobs, in order to compare traces in the ionogram in all these case studies. With these we can cover all kinds of signatures in the ionograms corresponding to no irregularities, plasma bubbles only and plasma bubbles-blobs. These OI 630.0 nm nightglow and ionograms recorded simultaneously make it possible to establish a novel methodology to recognize in ionograms cases when there is the occurrence of Spread-F signature associated with bubble-blob in the FOV of the ionosonde.     

Electrostatic accelerometer with bias rejection for gravitation and Solar System physics

Radio tracking of interplanetary probes is an important tool for navigation purposes as well as for testing the laws of physics or exploring planetary environments. The addition of an accelerometer on board a spacecraft provides orbit determination specialists and physicists with an additional observable of great interest: it measures the value of the non-gravitational acceleration acting on the spacecraft, i.e. the departure of the probe from geodesic motion.