Application of the Mars Organic Analyzer to nucleobase and amine biomarker detection

The Mars Organic Analyzer (MOA), a portable microfabricated capillary electrophoresis instrument being developed for planetary exploration, is used to analyze a wide variety of fluorescamine-labeled amine-containing biomarker compounds, including amino acids, mono and diaminoalkanes, amino sugars, nucleobases, and nucleobase degradation products. The nucleobases cytosine and adenine, which contain an exocyclic primary amine, were effectively labeled, separated, and detected at concentrations <500 nM. To test the general applicability of the MOA for biomarker detection, amino acids and mono- and diamines were extracted from bacterial cells using both hydrolysis and sublimation followed by analysis. The extrapolated limit of detection provided by the valine biomarker was approximately 4 x 10(3) cells per sample. Products of an NH(4)CN polymerization that simulate a prebiotic synthesis were also successfully isolated via sublimation and analyzed. Adenine and alanine/serine were detected with no additional sample cleanup at 120 +/- 13 microM and 4.1 +/- 1 microM, respectively, corresponding to a reaction yield of 0.04% and 0.0003%, respectively. This study demonstrates that the MOA provides sensitive detection and analysis of low levels of a wide variety of amine-containing organic compounds from both biological and abiotic sources.     

The Mercury Laser Altimeter Instrument for the MESSENGER Mission

The Mercury Laser Altimeter (MLA) is one of the payload science instruments on the MErcury Surface, Space ENvironment, GEochemistry, and Ranging (MESSENGER) mission, which launched on August 3, 2004. The altimeter will measure the round-trip time of flight of transmitted laser pulses reflected from the surface of the planet that, in combination with the spacecraft orbit position and pointing data, gives a high-precision measurement of surface topography referenced to Mercury’s center of mass. MLA will sample the planet’s surface to within a 1-m range error when the line-of-sight range to Mercury is less than 1,200 km under spacecraft nadir pointing or the slant range is less than 800 km. The altimeter measurements will be used to determine the planet’s forced physical librations by tracking the motion of large-scale topographic features as a function of time. MLA’s laser pulse energy monitor and the echo pulse energy estimate will provide an active measurement of the surface reflectivity at 1,064 nm. This paper describes the instrument design, prelaunch testing, calibration, and results of postlaunch testing.     

Effects of Superthermal Particles on Waves in Magnetized Space Plasmas

Distributions with excess numbers of superthermal particles are common in space environments. They are well modelled by the isotropic kappa distribution, or, where magnetic effects are important, the kappa-Maxwellian. This paper presents a review of some studies of electrostatic and electromagnetic waves in such plasmas, based on the associated generalized plasma dispersion functions, Z _κ and Z _κM. In particular, the effects of low values of κ are considered, i.e. strongly accelerated distribution functions. Recently the full susceptibility tensor for oblique propagation of electromagnetic waves in a kappa-Maxwellian magnetoplasma has been established and has been applied to the study of whistler waves.     

Origin, Internal Structure and Evolution of 4 Vesta

Asteroid 4 Vesta is the only preserved intact example of a large, differentiated protoplanet like those believed to be the building blocks of terrestrial planet accretion. Vesta accreted rapidly from the solar nebula in the inner asteroid belt and likely melted due to heat released due to the decay of ²⁶Al. Analyses of meteorites from the howardite-eucrite-diogenite (HED) suite, which have been both spectroscopically and dynamically linked to Vesta, lead to a model of the asteroid with a basaltic crust that overlies a depleted peridotitic mantle and an iron core. Vesta??s crust may become more mafic with depth and might have been intruded by plutons arising from mantle melting. Constraints on the asteroid??s moments of inertia from the long-wavelength gravity field, pole position and rotation, informed by bulk composition estimates, allow tradeoffs between mantle density and core size; cores of up to half the planetary radius can be consistent with plausible mantle compositions. The asteroid??s present surface is expected to consist of widespread volcanic terrain, modified extensively by impacts that exposed the underlying crust or possibly the mantle. Hemispheric heterogeneity has been observed by poorly resolved imaging of the surface that suggests the possibility of a physiographic dichotomy as occurs on other terrestrial planets. Vesta might have had an early magma ocean but details of the early thermal structure are far from clear owing to model uncertainties and paradoxical observations from the HEDs. Petrological analysis of the eucrites coupled with thermal evolution modeling recognizes two possible mechanisms of silicate-metal differentiation leading to the formation of the basaltic achondrites: equilibrium partial melting or crystallization of residual liquid from the cooling magma ocean. A firmer understanding the plethora of complex physical and chemical processes that contribute to melting and crystallization will ultimately be required to distinguish among these possibilities. The most prominent physiographic feature on Vesta is the massive south polar basin, whose formation likely re-oriented the body axis of the asteroid??s rotation. The large impact represents the likely major mechanism of ejection of fragments that became the HEDs. Observations from the Dawn mission hold the promise of revolutionizing our understanding of 4 Vesta, and by extension, the nature of collisional, melting and differentiation processes in the nascent solar system.     

The X-Ray Spectrometer on the MESSENGER Spacecraft

NASA’s MESSENGER (MErcury Surface, Space ENvironment, GEochemistry, and Ranging) mission will further the understanding of the formation of the planets by examining the least studied of the terrestrial planets, Mercury. During the one-year orbital phase (beginning in 2011) and three earlier flybys (2008 and 2009), the X-Ray Spectrometer (XRS) onboard the MESSENGER spacecraft will measure the surface elemental composition. XRS will measure the characteristic X-ray emissions induced on the surface of Mercury by the incident solar flux. The Kα lines for the elements Mg, Al, Si, S, Ca, Ti, and Fe will be detected. The 12° field-of-view of the instrument will allow a spatial resolution that ranges from 42 km at periapsis to 3200 km at apoapsis due to the spacecraft’s highly elliptical orbit. XRS will provide elemental composition measurements covering the majority of Mercury’s surface, as well as potential high-spatial-resolution measurements of features of interest. This paper summarizes XRS’s science objectives, technical design, calibration, and mission observation strategy.     

The Lunar Orbiter Laser Altimeter Investigation on the Lunar Reconnaissance Orbiter Mission

The Lunar Orbiter Laser Altimeter (LOLA) is an instrument on the payload of NASA’s Lunar Reconnaissance Orbiter spacecraft (LRO) (Chin et al., in Space Sci. Rev. 129:391–419, 2007). The instrument is designed to measure the shape of the Moon by measuring precisely the range from the spacecraft to the lunar surface, and incorporating precision orbit determination of LRO, referencing surface ranges to the Moon’s center of mass. LOLA has 5 beams and operates at 28 Hz, with a nominal accuracy of 10 cm. Its primary objective is to produce a global geodetic grid for the Moon to which all other observations can be precisely referenced.     

Oxygen Isotopes and Sampling of the Solar System

The atmospheres of the four giant planets of our Solar System share a common and well-observed characteristic: they each display patterns of planetary banding, with regions of different temperatures, composition, aerosol properties and dynamics separated by strong meridional and vertical gradients in the zonal (i.e., east-west) winds. Remote sensing observations, from both visiting spacecraft and Earth-based astronomical facilities, have revealed the significant variation in environmental conditions from one band to the next. On Jupiter, the reflective white bands of low temperatures, elevated aerosol opacities, and enhancements of quasi-conserved chemical tracers are referred to as ‘zones.’ Conversely, the darker bands of warmer temperatures, depleted aerosols, and reductions of chemical tracers are known as ‘belts.’ On Saturn, we define cyclonic belts and anticyclonic zones via their temperature and wind characteristics, although their relation to Saturn’s albedo is not as clear as on Jupiter. On distant Uranus and Neptune, the exact relationships between the banded albedo contrasts and the environmental properties is a topic of active study. This review is an attempt to reconcile the observed properties of belts and zones with (i) the meridional overturning inferred from the convergence of eddy angular momentum into the eastward zonal jets at the cloud level on Jupiter and Saturn and the prevalence of moist convective activity in belts; and (ii) the opposing meridional motions inferred from the upper tropospheric temperature structure, which implies decay and dissipation of the zonal jets with altitude above the clouds. These two scenarios suggest meridional circulations in opposing directions, the former suggesting upwelling in belts, the latter suggesting upwelling in zones. Numerical simulations successfully reproduce the former, whereas there is a wealth of observational evidence in support of the latter. This presents an unresolved paradox for our current understanding of the banded structure of giant planet atmospheres, that could be addressed via a multi-tiered vertical structure of “stacked circulation cells,” with a natural transition from zonal jet pumping to dissipation as we move from the convectively-unstable mid-troposphere into the stably-stratified upper troposphere.

     

Modeling satellite drag coefficients with response surfaces

Satellite drag coefficients are a major source of uncertainty in predicting the drag force on satellites in low Earth orbit. Among other things, accurately predicting the orbit requires detailed knowledge of the satellite drag coefficient. Computational methods are an important tool in computing the drag coefficient but are too intensive for real-time and predictive applications. Therefore, analytic or empirical models that can accurately predict drag coefficients are desired. This work uses response surfaces to model drag coefficients. The response surface methodology is validated by developing a response surface model for the drag coefficient of a sphere where the closed-form solution is known. The response surface model performs well in predicting the drag coefficient of a sphere with a root mean square percentage error less than 0.3% over the entire parameter space. For more complex geometries, such as the GRACE satellite, the Hubble Space Telescope, and the International Space Station, the model errors are only slightly larger at about 0.9%, 0.6%, and 1.0%, respectively.     

Pumice as a remarkable substrate for the origin of life

The context for the emergence of life on Earth sometime prior to 3.5 billion years ago is almost as big a puzzle as the definition of life itself. Hitherto, the problem has largely been addressed in terms of theoretical and experimental chemistry plus evidence from extremophile habitats like modern hydrothermal vents and meteorite impact structures. Here, we argue that extensive rafts of glassy, porous, and gas-rich pumice could have had a significant role in the origin of life and provided an important habitat for the earliest communities of microorganisms. This is because pumice has four remarkable properties. First, during eruption it develops the highest surface-area-to-volume ratio known for any rock type. Second, it is the only known rock type that floats as rafts at the air-water interface and then becomes beached in the tidal zone for long periods of time. Third, it is exposed to an unusually wide variety of conditions, including dehydration. Finally, from rafting to burial, it has a remarkable ability to adsorb metals, organics, and phosphates as well as to host organic catalysts such as zeolites and titanium oxides. These remarkable properties now deserve to be rigorously explored in the laboratory and the early rock record.