Organic chemistry by irradiation in space

The irradiation of grains and/or ices by particles from solar or stellar winds, as well as cosmic rays, induces the synthesis of molecular species. We have shown by in-situ infrared spectroscopy of irradiated samples that this chemistry may be responsible for the presence of organic compounds in a large variety of astrophysical sites such as: lunar and asteroidal regoliths, cometary nucleus, rings and satellites of outer planets, circumstellar shells, interstellar clouds. We present our experimental results concerning the nature and efficiency of C and N irradiation chemistries, and give plausible astrophysical implications.     

On the stereoselective aminoacylation of RNA

Aminoacylation of the “internal” 2′-hydroxyl groups of poly(A) with the imidazolide of racemic DL-leucine resulted in the formation of an enantiomeric excess of the D-ester, whereas aminoacylation with the imidazolide of racemic N-3,5-dinitrobenzoyl-DL-leucine gave an enantiomeric excess of the L-ester. Comparison of these results with those obtained earlier for alanine shows that the larger side chain tends to favor the formation of the D-ester. High resolution proton magnetic resonance spectroscopy was performed on the D- and L-alanyl “internal” 2′-esters of 3′,5′-ApA. The resonance of the side chain methyl group of the D-ester is upfield from that of the L-ester, and the separation of the peaks increases with a decrease in temperature.     

Dynamic considerations for control of closed life support systems

Reliability of closed life support systems will depend on their ability to continue supplying the crew's needs in the face of perturbations and equipment failures. These dynamic considerations interact with the basic static (equilibrium) design through the sizing of storages, the specification of excess capacities in processors, and the choice of system initial state (total mass in the system). This paper uses a very simple system flow model to examine the possibilities for system failures even when there is sufficient storage to buffer the immediate effects of the perturbation. Two control schemes are shown which have different dynamic consequences in response to component failures.     

Advanced regenerative environmental control and life support systems: Air and water regeneration

Extended manned space missions will require regenerative life support techniques. Past U.S. manned missions used nonregenerative expendables, except for a molecular sieve-based carbon dioxide removal system aboard Skylab. The resupply penalties associated with expendables becomes prohibitive as crew size and mission duration increase. The U.S. Space Station, scheduled to be operational in the 1990's, is based on a crew of four to sixteen and a resupply period of 90 days or greater. It will be the first major spacecraft to employ regenerable techniques for life support. The paper uses the requirements for the Space Station to address these techniques.     

The organic aerosols of Titan

A dark reddish organic solid, called tholin, is synthesized from simulated Titanian atmospheres by irradiation with high energy electrons in a plasma discharge. The visible reflection spectrum of this tholin is found to be similar to that of high altitude aerosols responsible for the albedo and reddish color of Titan. The real (n) and imaginary (k) parts of the complex refractive index of thin films of Titan tholin prepared by continuous D.C. discharge through a 0.9 N₂/0.1 CH₄ gas mixture at 0.2 mb is determined from x-ray to microwave frequencies. Values of n (1.65) and k (0.004 to 0.08) in the visible are consistent with deductions made by ground-based and spaceborne observations of Titan. Many infrared absorption features are present in k(λ), including the 4.6 μm nitrile band. Molecular analysis of the volatile component of this tholin was performed by sequential and non-sequential pyrolytic gas chromatography/mass spectrometry. More than one hundred organic compounds are released; tentative identifications include saturated and unsaturated aliphatic hydrocarbons, substituted polycyclic aromatics, nitriles, amines, pyrroles, pyrazines, pyridines, pyrimidines, and the purine, adenine. In addition, acid hydrolysis produces a racemic mixture of biological and non-biological amino acids. Many of these molecules are implicated in the origin of life on Earth, suggesting Titan as a contemporary laboratory environment for prebiological organic chemistry on a planetary scale.     

X-ray synchrotron nebulae and the origin of neutron stars

“With all reserve, we advance the view that a supernova represents the transition of an ordinary star into a neutron star.”This conclusion, reached just 50 years ago in a classic paper by Walter Baade and Fritz Zwicky (1934), was published three decades before the first direct observational evidence for the existence of neutron stars was uncovered. It still informs the standard picture of neutron star production in the Galaxy. We examine herein some recent evidence bearing on this question which has been derived from Observatory X-ray observations of supernova remnants and radio pulsars. In particular, the discovery that X-ray synchrotron nebulae are found surrounding most young ( 10⁶ yr) pulsars observed to date is discussed. We explore the implications of the lack of such nebulae in the majority of supernova remnants (SNR) for the properties and frequency of neutron star formation in supernova events.     

Balloon altitude studies of southern hemisphere hard X-ray sources by the Imperial College-University of Tasmania-INPE collaboration

Hard X-ray balloon altitude measurements with a 1600 cm² phoswich array are described. Data from observations on Sco X-1, GX1+4, GX5−1, Nova Oph. 1977, SMC X-1, SS433, IC 4329A and MR 2251-178 are presented. The role of Comptonisation in X-ray production for Sco X-1 and GX1+4 is discussed.     

Hard X-ray observations of the Crab Pulsar

The Crab was observed in a balloon flight from Palestine/Texas on 9/28/81 at hard X-ray energies (20–200 keV). The light curve is significantly sharper than reported previously for this energy range. The pulse-averaged as well as the interpulse spectra show breaks in our energy-range. The variation of spectral index across the pulse has an amplitude similar to that found at lower energies by OSO-8 and larger than reported by HEAO-1 A4 at hard X-rays. For a sharp emission line at 77 keV a 99% upper limit of 1.0*10⁻³ photons/ cm² sec can be placed, a factor of 4 lower than line fluxes reported previously. Pulse-shape fits to the optical, X-ray, hard X-ray and gamma ray light-curves reveal a consistent picture of the origin of the interpulse and off-pulse emission, the breaks in the spectra and the variation of spectral index, providing arguments against a thermal component and also a polar cap emission model for NP0532.     

Superclustering of galaxies and X-ray sources

An attempt is made to compare optical properties of Abell clusters with X-ray sources.