Aqueous corrosion of phosphide minerals from iron meteorites: a highly reactive source of prebiotic phosphorus on the surface of the early Earth

We present the results of an experimental study of aqueous corrosion of Fe-phosphide under conditions relevant to the early Earth. The results strongly suggest that iron meteorites were an important source of reactive phosphorus (P), a requirement for the formation of P-based life. We further demonstrate that iron meteorites were an abundant source of phosphide minerals early in Earth history. Phosphide corrosion was studied in five different solutions: deionized water, deionized water buffered with sodium bicarbonate, deionized water with dissolved magnesium and calcium chlorides, deionized water containing ethanol and acetic acid, and deionized water containing the chlorides, ethanol, and acetic acid. Experiments were performed in the presence of both air and pure Ar gas to evaluate the effect of atmospheric chemistry. Phosphide corrosion in deionized water results in a metastable mixture of mixed-valence, P-bearing ions including pyrophosphate and triphosphate, key components for metabolism in modern life. In a pH-buffered solution of NaHCO(3), the condensed and reduced species diphosphonate is an abundant corrosion product. Corrosion in ethanol- and acetic acid-containing solutions yields additional P-bearing organic molecules, including acetyl phosphonate and a cyclic triphosphorus molecule. Phosphonate is a major corrosion product of all experiments and is the only P-bearing molecule that persists in solutions with high concentrations of magnesium and calcium chlorides, which suggests that phosphonate may have been a primitive oceanic source of P. The stability and reactivity of phosphonate and hypophosphite in solution were investigated to elucidate reaction mechanisms and the role of mineral catalysts on P-solution chemistry. Phosphonate oxidation is rapid in the presence of Fe metal but negligible in the presence of magnetite and in the control sample. The rate of hypophosphite oxidation is independent of reaction substrate.     

Gravity and perceptual stability during translational head movement on earth and in microgravity

We measured the amount of visual movement judged consistent with translational head movement under normal and microgravity conditions. Subjects wore a virtual reality helmet in which the ratio of the movement of the world to the movement of the head (visual gain) was variable. Using the method of adjustment under normal gravity 10 subjects adjusted the visual gain until the visual world appeared stable during head movements that were either parallel or orthogonal to gravity. Using the method of constant stimuli under normal gravity, seven subjects moved their heads and judged whether the virtual world appeared to move “with” or “against” their movement for several visual gains. One subject repeated the constant stimuli judgements in microgravity during parabolic flight. The accuracy of judgements appeared unaffected by the direction or absence of gravity. Only the variability appeared affected by the absence of gravity. These results are discussed in relation to discomfort during head movements in microgravity.     

Odyssey: Principles for enduring space exploration

As the USA, Europe and other nations embark on a new voyage of exploration to the Moon, Mars and beyond, they should lay the foundations and establish precedents that invite a host of participants and followers. We argue that international cooperation, driven by foreign-policy and cost-sharing considerations, has taken a prominent role but must be pragmatically and flexibly balanced with economic and strategic self-interest. Since exploration visions are likely to differ, the steps each country will pursue, the funding provided, and schedules followed will also differ. To support an enduring exploration vision, it will be important to remain flexible to changing priorities and amenable to the inclusion of new, non-traditional participants. Open-systems principles and metaprinciples should be employed at all levels—hardware, software, programmatic, political and cultural. Equally important, national leadership and decision makers should be mindful of the potential pitfalls that might undermine the venture. While the new vision inspires us all, it will take creativity, resourcefulness, hard work and cooperation to succeed.     

Electrostatic Noise Spectrum at the Electron Cyclotron Frequency and Electromagnetic Emission in the Inhomogeneous Plasma of the Topside Ionosphere

Measurements of the wave emission of the topside ionosphere made onboard the APEX satellite using the electric component of the wave field in the 0.1–10 MHz frequency band are presented. At middle latitudes a wave intensity decrease was observed in the broad-band spectrum of the electrostatic noise at the electron cyclotron frequency. It is shown that a break in the spectrum of electrostatic modes at the electron cyclotron frequency (the absence of the plasma eigen-frequencies) may be a cause of the observed effect. The increase of the intensity at the electron cyclotron frequency in the ionospheric trough and at latitudes above the trough region as compared to middle latitudes may be explained by the capture by plasma irregularities of the electromagnetic emission of the auroral electron fluxes.__________Translated from Kosmicheskie Issledovaniya, Vol. 43, No. 3, 2005, pp. 201–208.Original Russian Text Copyright © 2005 by Izhovkina, Prutensky, Pulinets, Kiraga, Klos, Rothkael.     

The Motion of Coaxial Bodies of Varying Composition on the Active Leg of Descent

The motion of a spacecraft (SC) with double rotation and variable mass on the active leg of its descent is considered. The SC consists of two coaxial bodies. The coaxial scheme is used for gyroscopic stabilization of the SC longitudinal axis by the method of partial spin-up. The equations of spatial motion of coaxial bodies of varying composition are derived and approximate solutions for the angles of spatial orientation are found. The condition of decreasing amplitude of nutation oscillations is obtained, which allows the estimation of efficiency of the stabilization by partial spin-up. The errors in the magnitude and direction of the vector of braking thrust are also determined.__________Translated from Kosmicheskie Issledovaniya, Vol. 43, No. 3, 2005, pp. 224–232.Original Russian Text Copyright © 2005 by Aslanov, Doroshin, Kruglov.     

The effect of small vibrations on Marangoni convection and the free surface of a liquid bridge

The effects of small vibrations on Marangoni convection were investigated experimentally using a liquid bridge of 5 cSt silicone oil with a disk diameter of 7.0 mm, and an aspect ratio close to 0.5. Experiments were performed to determine the critical temperature difference data for no vibration case and with small vibrations applied. The experimental results have shown that the effect of small vibrations on the onset of oscillatory flow is small since the critical temperature difference data for different aspect ratios were not affected by the vibrations. To clarify the surface oscillation phenomena induced by external vibrations, a 3-D numerical simulation model was also developed using a level set algorithm to predict the surface oscillations of isothermal silicone oil bridges. By subjecting the liquid bridge to small vibrations, the surface oscillation characteristics were predicted numerically, and the numerical results compared well with the predictions of an analytical model proposed previously. Furthermore, the effect of small vibrations on the surface vibration amplitude of the liquid bridge is also discussed.     

Detection of ultrahigh-energy cosmic rays and neutrinos by radio method using artificial lunar satellites

An estimate of the feasibility of the ultrahigh-energy cosmic ray and neutrino detection using a lunar satellite-borne radio receiver is presented. The data obtained in the proposed experiment will make resolving the current contradictions in the ultrahigh-energy cosmic ray spectra measured with the major ground-based instruments possible. Moreover, they will enable us to considerably extend the accessible energy range and to check predictions of various models of the origin of the highest-energy particles in the Universe. At the same time the lunar radio detector provides a means of searching for ultrahigh-energy neutrinos with a high sensitivity combined with a very large target effective mass.     

Mechanisms of generation and dynamics of HF and LF emissions in the experiments with electron beams injected into the earth’s ionosphere

Mechanisms of generation and dynamics of HF and LF emissions related to an electron beam injection from a spacecraft into the ionosphere are studied. The choice of the source and region of emission is substantiated. The plasma current neutralizing the spacecraft charge and the region of spatial charge in the vicinity of the spacecraft are chosen. Mechanisms of the generation of HF and LF emissions are proposed and their characteristics are determined. For the considered ranges of emission, the explanation of the facts related to the difficulties in interpretation of the amplitude value observed experimentally and the behavior of its envelope are presented. It is shown that the results obtained in this work agree well with the data of the conducted experiments.     

Bacterial community in ancient Siberian permafrost as characterized by culture and culture-independent methods

The microbial composition of ancient permafrost sediments from the Kolyma lowland of Northeast Eurasia was examined through culture and culture-independent approaches. These sediments have been continuously frozen for 5,000 to 2-3 million years. A total of 265 Bacteria 16S rRNA gene sequences were amplified from the permafrost total-community genomic DNA and screened by amplified ribosomal 16S rRNA restriction analysis. Members of three major lineages were found: gamma-Proteobacteria (mostly Xanthomonadaceae), Actinobacteria, and Firmicutes. We also determined partial 16S rRNA gene sequences of 49 isolates from a collection of 462 aerobes isolated from these sediments. The bacteria included Actinomycetales (Arthrobacter and Microbacteriaceae); followed by the Firmicutes (Exiguobacterium and Planomicrobium); the Bacteroidetes (Flavobacterium); the gamma-Proteobacteria (Psychrobacter); and the alpha-Proteobacteria (Sphingomonas). Both culture and culture-independent approaches showed the presence of high and low G+C Gram-positive bacteria and gamma-Proteobacteria. Some of the 16S rRNA gene sequences of environmental clones matched those of Arthrobacter isolates. Two-thirds of the isolates grew at -2.5 degrees C, indicating that they are psychroactive, and all are closely related to phylogenetic groups with strains from other cold environments, mostly commonly from Antarctica. The culturable and non-culturable microorganisms found in the terrestrial permafrost provide a prototype for possible life on the cryogenic planets of the Solar System.