Processes that Promote and Deplete the Exosphere of Mercury

It has been speculated that the composition of the exosphere is related to the composition of Mercury’s crustal materials. If this relationship is true, then inferences regarding the bulk chemistry of the planet might be made from a thorough exospheric study. The most vexing of all unsolved problems is the uncertainty in the source of each component. Historically, it has been believed that H and He come primarily from the solar wind (Goldstein, B.E., et al. in J. Geophys. Res. 86:5485–5499, 1981), Na and K come from volatilized materials partitioned between Mercury’s crust and meteoritic impactors (Hunten, D.M., et al. in Mercury, pp. 562–612, 1988; Morgan, T.H., et al. in Icarus 74:156–170, 1988; Killen, R.M., et al. in Icarus 171:1–19, 2004b). The processes that eject atoms and molecules into the exosphere of Mercury are generally considered to be thermal vaporization, photon-stimulated desorption (PSD), impact vaporization, and ion sputtering. Each of these processes has its own temporal and spatial dependence. The exosphere is strongly influenced by Mercury’s highly elliptical orbit and rapid orbital speed. As a consequence the surface undergoes large fluctuations in temperature and experiences differences of insolation with longitude. Because there is no inclination of the orbital axis, there are regions at extreme northern and southern latitudes that are never exposed to direct sunlight. These cold regions may serve as traps for exospheric constituents or for material that is brought in by exogenic sources such as comets, interplanetary dust, or solar wind, etc. The source rates are dependent not only on temperature and composition of the surface, but also on such factors as porosity, mineralogy, and space weathering. They are not independent of each other. For instance, ion impact may create crystal defects which enhance diffusion of atoms through the grain, and in turn enhance the efficiency of PSD. The impact flux and the size distribution of impactors affects regolith turnover rates (gardening) and the depth dependence of vaporization rates. Gardening serves both as a sink for material and as a source for fresh material. This is extremely important in bounding the rates of the other processes. Space weathering effects, such as the creation of needle-like structures in the regolith, will limit the ejection of atoms by such processes as PSD and ion-sputtering. Therefore, the use of laboratory rates in estimates of exospheric source rates can be helpful but also are often inaccurate if not modified appropriately. Porosity effects may reduce yields by a factor of three (Cassidy, T.A., and Johnson, R.E. in Icarus 176:499–507, 2005). The loss of all atomic species from Mercury’s exosphere other than H and He must be by non-thermal escape. The relative rates of photo-ionization, loss of photo-ions to the solar wind, entrainment of ions in the magnetosphere and direct impact of photo-ions to the surface are an area of active research. These source and loss processes will be discussed in this chapter.     

Comet Halley's Gas Composition and Extended Sources: Results from the Neutral Mass Spectrometer on Giotto

The Neutral Mass Spectrometer on the Giotto spacecraft established that H₂O is the dominant species in Comet Halley's volatiles and determined the abundance of more than 10 parent species. The instrument discovered strong extended H₂CO and CO sources in the coma of Comet Halley. Polymerized H₂CO associated with the cometary dust and evaporating slowly as the monomer is most likely the extended H₂CO source. Photodissociation of the H₂CO into CO fully accounts for the extended CO source. This revised version was published online in June 2006 with corrections to the Cover Date.     

Recent experiments in laser supported absorption waves

Recent experimental studies with laser supported absorption waves, arising from intense laser radiation incident upon various surface materials, are discussed. The propagation characteristics of both subsonic (laser supported combustion), intensity about 10⁵ W/cm², and supersonic (laser supported detonation), intensity greater than 10⁶ W/cm², waves are described, including the dependence of wave speed on laser intensity, beam diameter, gas density and laser wave length. Measurements of the plasma properties in such waves are described, and the analysis of these data allows conclusions identifying the dominant transport mechanism in such waves. It is also concluded that in the LSC (subsonic) case, radial flow ahead of and within the wave are dominant features of the wave structure. The equipment and laser facilities used in the experiments are also discussed.     

Radiance calibration of CRISTA-NF

The CRISTA-NF instrument is the airborne version of the CRISTA satellite infrared limb sounder. It has been successfully flown on the Geophysica research airplane during a test campaign in July 2005, during the SCOUT-O3 Tropical Aircraft Campaign in November/December 2005 and during the AMMA campaign in August 2006. Radiance calibrations of the airborne instrument are more complex compared to the satellite instrument because the vacuum shell of CRISTA-NF is confined by a ZnSe (zinc–selenide) window and the detectors can thermally drift during measurement flights. By comprehensive radiance calibrations with a blackbody source the window’s emissivity and transmissivity are determined and the dependence of the instrument sensitivity on the detector temperature is characterized. Taking these effects into account, the remaining radiance error of the calibration is smaller than 3%.     

Additional historical solid rocket motor burns

The use of orbital solid rocket motors (SRM) is responsible for the release of a high number of slag and Al₂O₃ dust particles which contribute to the space debris environment. This contribution has been modeled for the ESA space debris model MASTER (Meteoroid and Space Debris Terrestrial Environment Reference). The current model version, MASTER-2005, is based on the simulation of 1076 orbital SRM firings which mainly contributed to the long-term debris environment. SRM firings on very low earth orbits which produce only short living particles are not considered. A comparison of the modeled flux with impact data from returned surfaces shows that the shape and quantity of the modeled SRM dust distribution matches that of recent Hubble Space Telescope (HST) solar array measurements very well. However, the absolute flux level for dust is under-predicted for some of the analyzed Long Duration Exposure Facility (LDEF) surfaces. This indicates that some past SRM firings are not included in the current event database. Thus it is necessary to investigate, if additional historical SRM burns, like the retro-burn of low orbiting re-entry capsules, may be responsible for these dust impacts. The most suitable candidates for these firings are the large number of SRM retro-burns of return capsules. This paper focuses on the SRM retro-burns of Russian photoreconnaissance satellites, which were used in high numbers during the time of the LDEF mission. It is discussed which types of satellites and motors may have been responsible for this historical contribution. Altogether, 870 additional SRM retro-burns have been identified. An important task is the identification of such missions to complete the current event data base. Different types of motors have been used to de-orbit both large satellites and small film return capsules. The results of simulation runs are presented.     

Towards a Global Unified Model of Europa’s Tenuous Atmosphere

Despite the numerous modeling efforts of the past, our knowledge on the radiation-induced physical and chemical processes in Europa’s tenuous atmosphere and on the exchange of material between the moon’s surface and Jupiter’s magnetosphere remains limited. In lack of an adequate number of in situ observations, the existence of a wide variety of models based on different scenarios and considerations has resulted in a fragmentary understanding of the interactions of the magnetospheric ion population with both the moon’s icy surface and neutral gas envelope. Models show large discrepancy in the source and loss rates of the different constituents as well as in the determination of the spatial distribution of the atmosphere and its variation with time. The existence of several models based on very different approaches highlights the need of a detailed comparison among them with the final goal of developing a unified model of Europa’s tenuous atmosphere. The availability to the science community of such a model could be of particular interest in view of the planning of the future mission observations (e.g., ESA’s JUpiter ICy moons Explorer (JUICE) mission, and NASA’s Europa Clipper mission). We review the existing models of Europa’s tenuous atmosphere and discuss each of their derived characteristics of the neutral environment. We also discuss discrepancies among different models and the assumptions of the plasma environment in the vicinity of Europa. A summary of the existing observations of both the neutral and the plasma environments at Europa is also presented. The characteristics of a global unified model of the tenuous atmosphere are, then, discussed. Finally, we identify needed future experimental work in laboratories and propose some suitable observation strategies for upcoming missions.     

The mass and speed dependence of meteor air plasma temperatures

The speed and mass dependence of meteor air plasma temperatures is perhaps the most important data needed to understand how small meteoroids chemically change the ambient atmosphere in their path and enrich the ablated meteoric organic matter with oxygen. Such chemistry can play an important role in creating prebiotic compounds. The excitation conditions in various air plasma emissions were measured from high-resolution optical spectra of Leonid storm meteors during NASA's Leonid Multi-Instrument Aircraft Campaign. This was the first time a sufficient number and range of temperature measurements were obtained to search for meteoroid mass and speed dependencies. We found slight increases in temperature with decreasing altitude, but otherwise nearly constant values for meteoroids with speeds between 35 and 72 km/s and masses between 10(-5) g and 1 g. We conclude that faster and more massive meteoroids produce a larger emission volume, but not a higher air plasma temperature. We speculate that the meteoric plasma may be in multiphase equilibrium with the ambient atmosphere, which could mean lower plasma temperatures in a CO(2)-rich early Earth atmosphere.     

Quantification of spatial structure of human proximal tibial bone biopsies using 3D measures of complexity

Changes in trabecular bone composition during development of osteoporosis are used as a model for bone loss in microgravity conditions during a space flight. Symbolic dynamics and measures of complexity are proposed and applied to assess quantitatively the structural composition of bone tissue from 3D data sets of human tibia bone biopsies acquired by a micro-CT scanner. In order to justify the newly proposed approach, the measures of complexity of the bone architecture were compared with the results of traditional 2D bone histomorphometry. The proposed technique is able to quantify the structural loss of the bone tissue and may help to diagnose and to monitor changes in bone structure of patients on Earth as well as of the space-flying personnel.     

A culture-independent survey of the bacterial community in a radon hot spring

Paralana is an active, radon-containing hot spring situated in a region of South Australia's Flinders Ranges with a long history of hydrothermal activity. Our aim was to determine the bacterial composition of Paralana using a culture-independent, 16S rRNA-based technique. The presence of a diverse bacterial community was strongly suggested by the large number (approximately 180) of different ribotypes obtained upon analysis of nine hot spring samples. DNA sequencing of Paralana 16S rRNA genes corroborated this observation, identifying representatives of seven confirmed and two candidate divisions of the domain Bacteria. These included Cyanobacteria, Proteobacteria (both beta and delta subdivisions), the Cytophaga-Flexibacter-Bacteroides group, Low G + C Gram-positives, Nitrospira, green non-sulfur bacteria, green sulfur bacteria, OP8, and OP12. No known ionizing radiation-resistant Bacteria were identified. Only one Paralana 16S rRNA sequence type (recombinant B5D) was homologous to a sequence previously identified from a radioactive environment.