Ultraviolet-stimulated fluorescence and phosphorescence of aromatic hydrocarbons in water ice

A principal goal of astrobiology is to detect and inventory the population of organic compounds on extraterrestrial bodies. Targets of specific interest include the wealth of icy worlds that populate our Solar System. One potential technique for in situ detection of organics trapped in water ice matrices involves ultraviolet-stimulated emission from these compounds. Here, we report a preliminary investigation into the feasibility of this concept. Specifically, fluorescence and phosphorescence of pure benzene ice and 1% mixtures of benzene, toluene, p-xylene, m-xylene, and o-xylene in water ice, respectively, were studied at temperatures ranging from ～17 K up to 160 K. Spectra were measured from 200-500 nm (50,000-20,000 cm(-1)) while ice mixtures were excited at 248.6 nm. The temperature dependence of the fluorescence and phosphorescence intensities was found to be independent of the thermal history and phase of the ice matrix in all cases examined. All phosphorescent emissions were found to decrease in intensity with increasing temperature. Similar behavior was observed for fluorescence in pure benzene, while the observed fluorescence intensity in water ices was independent of temperature.     

Comparison of the roles of nucleotide synthesis, polymerization, and recombination in the origin of autocatalytic sets of RNAs

Ribozymes that act as polymerases and nucleotide synthases are known experimentally, even though no fully self-replicating system has yet been found. If the RNA World hypothesis is true, ribozymes must have arisen initially from within a random abiotic polymerization system. To investigate the origin of the RNA world, we studied a mathematical model of a chemical reaction system describing RNA polymerization. It is supposed that, in absence of ribozymes, polymerization occurs at a small spontaneous rate, and that in the presence of polymerase ribozymes, polymerization occurs at a faster rate that is proportional to the ribozyme concentration. Chains must be longer than a minimum threshold length in order to have the possibility of acting as ribozymes. The reaction system has two stable states that we term dead and living. The dead state is controlled by the small spontaneous rate and has negligible concentration of ribozymes. The living state has high concentration of ribozymes, and the reaction rates are determined by the ribozymes; thus, the system is autocatalytic. Concentration fluctuations in a finite volume can cause a transition to occur from the dead to the living state, that is, an origin of life occurs within this model. We also consider ribozymes that catalyze nucleotide synthesis. We show that living and dead states arise in the presence of synthase ribozymes in the same way as for polymerases. It has been proposed that recombination reactions are a way of generating long RNA chains in the early stages of life. We show that if the possibility of random reversible recombination reactions is added to our model, this does not lead to an increase in long polymer concentration. Thus, if recombination is fully reversible, there is no autocatalytic state controlled by recombination. Nevertheless, recombination can play an important role in ribozyme synthesis if there is an additional process that keeps the recombination reactions out of equilibrium. We modeled a case studied experimentally in which building block strands of moderate length associate due to RNA secondary structure formation. A recombination reaction then occurs between these strands to form a longer sequence that catalyzes its own formation via the recombination reaction. This system has an autocatalytic state, and it is possible for it to arise within our random polymerization system. If complexes formed by associations of shorter strands can act as catalysts without the requirement that the strands be covalently linked, this would alleviate the need for synthesis of very long strands; hence, it makes the emergence of an autocatalytic system from an abiotic random polymerization system much more likely.     

电动刹车

为了节省燃油,航空公司一直都期望飞机和部件厂商在减重上下功夫。现在,刹车技术在飞机减轻方面的功用也越来越引起关注。刹车供应商适时推出电动刹车,波音787成为率先采用此技术的商用飞机。     

Investigation of nuclear electric powered interstellar precursor missions

Nuclear Electric Propulsion (NEP) is a technology conceptually proposed since the 1940s by E. Stuhlinger in Germany. The JIMO mission originally planned by NASA in the early 2000s produced at least two designs of ion thrusters fed by a 20–30 kW nuclear powerplant. When compared to conventional (chemical) propulsion, the major advantage of NEP in the JIMO context was recognized to be the much higher I_sp (lab-tested at up to 15,000 s) and the capability for sustained power generation, up to 8–10 years when derated to I_sp about 8000 s.The goal of this paper is to show that current or near term NEP technology enables missions far beyond our immediate interplanetary backyard. In fact, by extending the semi-analytical approach used by Stuhlinger, with reasonable ratios α≡power/mass of the propulsion system (i.e., 0.1– 0.4 kW/kg), missions to the Kuiper Belt (40 AU and beyond) and even the so-called FOCAL mission (at 540 AU) become feasible with an attractive payload fraction and in times of order 10–15 years.Further results regarding missions to Sedna’s perihelion/aphelion, and to Oort’s cloud will also be presented, showing the constraints affecting their feasibility and mass budget.     

Broad band X-ray properties of GRO J1948+32/KS 1947+300

We present here results obtained from three BeppoSAX observations of the transient X-ray pulsar GRO J1948+32 carried out during the declining phase of its 2000 November–2001 June outburst. Timing analysis of the data clearly shows a 18.7 s pulsation in the X-ray light curves in 0.1–100 keV energy band. The pulse profile of GRO 1948+32 is characterized by a broad peak with a sharp rise followed by a narrow dip. The dip in the pulse profile shows very strong energy dependence. Phase-averaged spectroscopy obtained with three of the BeppoSAX instruments shows that the 0.1–100 keV energy spectrum is described by a Comptonized component, a weak blackbody component (7% of the total emission) for soft X-rays, a narrow and weak iron emission line at 6.7 keV and low column density of material in the line of sight. The results obtained from the analysis are discussed in this paper.     

Two CFAR algorithms for interfering targets and nonhomogeneousclutter

The greatest-of-order statistics estimator (GOOSE) constant false alarm rate (CFAR) and the censored greatest-of (CGO) CFAR are described. Both are designed to accommodate interfering targets in the reference window as well as control false alarms in the presence of clutter boundaries. Both succeed in accomplishing these tasks although the CGO-CFAR is preferred as it has a designed graceful degradation as the number of interfering targets exceeds the number of samples censored. The advantage of the GOOSE-CFAR is a theoretical one in that one can derive analytical results for clutter boundary analysis and thus not have to resort to simulations     

Recent results form measurements of the energy spectrum of cosmic-ray induced neutrons aboard an ER-2 airplane and on the ground.

Crews of future high-altitude commercial aircraft may be significantly exposed to atmospheric cosmic radiation from galactic cosmic rays (GCR). To help determine such exposures, the Atmospheric Ionizing Radiation Project, an international collaboration of 15 laboratories, made simultaneous radiation measurements with 14 instruments on a NASA ER-2 high-altitude aircraft. The primary instrument was a sensitive extended-energy multisphere neutron spectrometer, which was also used to make measurements on the ground. Its detector responses were calculated for neutrons and charged hadrons at energies up to 100 GeV using the radiation transport code MCNPX. We have now recalculated the detector responses including the effects of the airplane structure. We are also using new FLUKA calculations of GCR-induced hadron spectra in the atmosphere to correct for spectrometer counts produced by charged hadrons. Neutron spectra are unfolded from the corrected measured count rates using the MAXED code. Results for the measured cosmic-ray neutron spectrum (thermal to >10 GeV), total neutron fluence rate, and neutron dose equivalent and effective dose rates, and their dependence on altitude and geomagnetic cutoff generally agree well with results from recent calculations of GCR-induced neutron spectra.     

Determining Ionospheric Parameters over Regions of Denied Access

Utilization of high frequencies for over-the-horizon surveillance necessitated a refined approach to the determination of actual ray paths. Various ray-tracing programs have been developed. The basic problem lies in accurately determining values of the appropriate ionospheric parameters. A possible means is by utilization of oblique sounding devices located at the path terminals to provide 1) relative propagation time difference (?t) between the modes, 2) maximum frequency propagated by any given mode (MUF), and 3) difference in MUF between the various modes (?MUF). The technique has not been fully verified; preliminary results are encouraging.