Mass spectrometric measurements of stratospheric ions

Recent in situ measurements with balloon borne quadrupole mass spectrometers, between 20 and 45 km altitude, are reviewed and discussed.The major stratospheric positive ions observed are proton hydrates [H⁺(H₂O)_n] and non proton hydrates of the form H⁺X_m(H₂O)₂. The data analysis allows a derivation of the vertical mixing ratio profile of X (most probably CH₃CN), which is compared with recent model calculations. From negative ion composition data, showing the presence of NO₃^? and HSO₄^? cluster ions, the density of sulfuric acid in the stratosphere is deduced. The implications of these findings on our understanding of the sulfur chemistry is briefly treated.Finally some other aspects such as contamination, cluster break up and the use of stratospheric ion mass spectra for determination of thermochemical data and other minor constituents are discussed.     

Thermal and thermosolutal convective effects in bridgman solidification: Effect of orientation relative to gravity

A concentrated binary system (Ge-Si) and a dilute one (Ge-Ga) have been solidified at 1 g, in a new vertical Bridgman furnace where radial thermal gradients have been minimized. Very different solutal boundary layer extents (δ_Ge-Si = 3 cm, δ_Ge-Ga = 2.5 mm) obtained for both systems solidified in the same thermal conditions are explained by simple analytical hydrodynamic models. It is demonstrated that :1. The convective transport of Ga in the Ge-Ga system is due to the unavoidable residual horizontal thermal gradients associated with discontinuity of thermal properties at the solid-liquid interface.2. The larger boundary layer extent observed for Ge-Si and the corresponding pure diffusive transport is the result of the stabilizing effect of the longitudinal solutal gradient in this system.Thus, in the case of dilute systems, convective effects can only be cancelled through a reduction of the gravity level. On the opposite, pure diffusive solute transport can be achieved in the vertical configuration a 1 g in the case of concentrated systems where a stabilizing solutal effect is operating.     

Radio aurora magnetic and streaming aspect sensitivities on 6 simultaneous links at 50 MHz

During August 1981, a 50 MHz c.w. radar system was operated in central Canada to measure auroral scatter amplitudes and Doppler spectra from a scattering region centered near 66° magnetic invariant latitude (L ≈ 6.0). Narrow beams from 3 transmitters, differing in frequency by 1 KHz, were directed to cover a common volume of the ionosphere over a ground location at 56.3°N, 103.5°W. The scattered signals were received on narrow beam antennas at two receiving sites, and recorded in analog form on magnetic tape under the control of an AIM65 microcomputer. The analog tapes were digitized later and FFT-processed to obtain Doppler spectra and amplitudes.The 6 transmission paths were designed to provide several magnetic aspect angles varying by 1.5°-7° from perpendicularity with the earth's field B and two streaming aspect angles differing by ～38°. The objective was to employ controlled geometric factors to study the functional dependency of signal amplitudes and Doppler shifts on magnetic and streaming aspect angles. Several hundred hours of excellent data were obtained in continuous operation during the month of August 1981. Preliminary results will be reported.     

America's Abundant Electricity and the ASME Boiler Code

The building of great steam power plants with utmost consideration for public safety has created today's American miracle of abundant electricity. Behind this great achievement stand the mechanical engineers who have designed and built these power plants under their ethical responsibilities for public safety, in full compliance with the American Society of Mechanical Engineers (ASME) Boiler Code and under the strict disciplines imposed by a specialist insurance company willing to write 100 percent insurance coverage against boiler explosions. The historical origin of this great achievement dates back to the days of the Civil War and a small group of men with exceptional vision and a profound concern for public safety. They saw the opportunity to apply their talents and sense of responsibility to solving the problem of steam boiler explosions and the terrible losses of human lives. These early leaders have earned the esteem and honor of our present and future generations, but who remembers them? Today, in the scientific revolution of this century, there is a critical need for similar new leaders of exceptional integrity, responsibility, and initiative, both in engineering and in industry.     

Hydrodynamic forces resulting from liquid motion in capillary tubes

The wetting kinetics of model tubes of different geometrical shape has been investigated theoretically and experimentally under conditions of simulated zero-gravity (earthbound laboratory experiments) and low gravity (sounding rocket experiments within the TEXUS-programme). The present note deals with the hydrodynamic forces (capillary-, friction-, inertia forces, etc.) resulting from capillary rise in cylindrical, conical and sinusoidal tubes. The rôle of these forces is studied numerically in some detail.     

The infrared synthetic spectrum of comet Halley

In order to prepare infrared sounding of comet Halley from the flyby VEGA probes, we have computed the synthetic spectrum between 2.5 and 15 μ of a typical comet at a heliocentric distance of ～ 0.8 AU. The present paper is particularly devoted to the contribution from the cometary gases. For a selection of 20 possible parent molecules, the most efficient excitation process is resonant fluorescence by the solar radiation field. The H₂O, CO, CO₂, CH₄, NH₃ and H₂CO molecules are the best candidates for detection by the IKS infrared spectrometers aboard the VEGA probes. For the water molecule, collisions are too rare to ensure thermal equilibrium in the whole coma ; therefore a limited number of fluorescence lines are expected to be present in the H₂O vibrational bands.     

Recovery of lower limb function following 6 weeks of non-weight bearing

Skeletal muscle weakness and atrophy occur following an extended period of decreased use, including space flight and limb unloading. It is also likely that affected muscles will be susceptible to a re-loading injury when they begin return to earth or weight bearing. However, there is a paucity of literature evaluating the response of human unloaded muscle to exercise and return to activity.

The purpose of this pilot study was to evaluate the soreness, function and strength response of muscle to re-loading in seven patients who were non-weight bearing for 6 weeks, compared to five healthy subjects.

Function improved significantly over time for the patients but was still less than the healthy subjects over 12 weeks of physiotherapy. Concentric quadriceps muscle strength increased significantly over time for the patients. There was considerable variability in the patients’ reports of muscle soreness but there were no significant changes over time or between groups.     

Antibody engineering--a valuable asset in preventing closed environment epidemics

Investigations of Mir, Space Shuttle, Skylab and Apollo missions report extensive colonisation of the spacecraft by bacteria and fungi, which can lead to degradative effects on spacecraft equipment and devastating effects on space-grown crops. More than 80% of terrestrial greenhouse epidemics are due to the fungal genera Phytophthora, Pythium and Fusarium, which have been found in life support system test-beds. The advent of recombinant antibody technologies, including ribosome display and phage display, has made it possible to develop antibodies against virtually any toxin or organism and allows for maturation of antibodies by in vitro molecular evolution. These antibodies may play an important role in an integrated pest management regime for life support systems. Efficacy of existing fungal countermeasures could be increased by chemical linkage to antibodies, which target the site of action of the biocide or trap the pathogen in a biofilter. Novel recombinant antibody-biocide fusions can be expressed in situ by plants or symbiotic microbes to create direct disease resistance.     

Electric Field Detection and Ranging of Aircraft

The electric field transported by charged aircraft during free flight can be observed quantitatively in distances of up to some 100 m. A system of three plane sensors arranged in the corners of a triangle or the Earth surface is described, by which the flight path of aircraft is detected in the range of 40 to 500 m with velocities of approximately 50 m/s. The theory and typical experimental results are discussed.     

Error Analysis for Relay Type Satellite-Aided Search and Rescue Systems

An analysis is made of the errors in the determination of the position of an emergency transmitter in a satellite-aided search and rescue system. The satellite is assumed to be at a height of 820 km in a near-circular near polar orbit. Short data spans of four minutes or less are used. The error sources considered are measurement noise, transmitter frequency drift, ionospheric effects, and error in the assumed height of the transmitter. The errors are calculated for several different transmitter positions, data rates, and data spans. The only transmitter frequency used was 406 MHz, but the result can be scaled to different frequencies.