Adsorption of amino acids (ALA, CYS, HIS, MET) on zeolites: fourier transform infrared and Raman spectroscopy investigations

Minerals adsorb more amino acids with charged R-groups than amino acids with uncharged R-groups. Thus, the peptides that form from the condensation of amino acids on the surface of minerals should be composed of amino acid residues that are more charged than uncharged. However, most of the amino acids (74%) in today's proteins have an uncharged R-group. One mechanism with which to solve this paradox is the use of organophilic minerals such as zeolites. Over the range of pH (pH 2.66-4.50) used in these experiments, the R-group of histidine (His) is positively charged and neutral for alanine (Ala), cysteine (Cys), and methionine (Met). In acidic hydrothermal environments, the pH could be even lower than those used in this study. For the pH range studied, the zeolites were negatively charged, and the overall charge of all amino acids was positive. The conditions used here approximate those of prebiotic Earth. The most important finding of this work is that the relative concentrations of each amino acid (X=His, Met, Cys) to alanine (X/Ala) are close to 1.00. This is an important result with regard to prebiotic chemistry because it could be a solution for the paradox stated above. Pore size did not affect the adsorption of Cys and Met on zeolites, and the Si/Al ratio did not affect the adsorption of Cys, His, and Met. ZSM-5 could be used for the purification of Cys from other amino acids (Student-Newman-Keuls test, p<0.05), and mordenite could be used for separation of amino acids from each other (Student-Newman-Keuls test, p<0.05). As shown by Fourier transform infrared (FT-IR) spectra, Ala interacts with zeolites through the [Formula: see text] group, and methionine-zeolite interactions involve the COO, [Formula: see text], and CH(3) groups. FT-IR spectra show that the interaction between the zeolites and His is weak. Cys showed higher adsorption on all zeolites; however, the hydrophobic Van der Waals interaction between zeolites and Cys is too weak to produce any structural changes in the Cys groups (amine, carboxylic, sulfhydryl, etc.); thus, the FT-IR and Raman spectra are the same as those of solid Cys.     

Analytical solutions for the relative motion of spacecraft subject to Lorentz-force perturbations

A spacecraft capable of producing higher-than-natural electrostatic charges may achieve propellantless orbital maneuvering via the Lorentz-force interaction with a planetary magnetic field. Development of maneuver strategies for these propellantless vehicles is complicated by the fact that the perturbative Lorentz force acts along only a single line of action at any instant. Relative-motion dynamical models are developed that lead to approximate analytical solutions for the motion of charged spacecraft subject to the Lorentz force. These solutions indicate that the principal effects of the Lorentz force on a spacecraft in a circular orbit are to change the intrack position and to change the orbit plane. A rendezvous example is presented in which a spacecraft with a specific charge of ?3.81 $\times$ 10^?4 C/kg reaches a target vehicle initially 10 km away (on the same equatorial low-Earth orbit) in 1 day. Fly-around maneuvers may be achieved in low-Earth orbit with specific charges on the order of 0.001 C/kg.     

Autonomous navigation and guidance system for low thrust driven deep space missions

Presented herein is a concept of an Autonomous Navigation & Guidance System for electrically propelled deep space missions, including hardware configuration, algorithms for autonomous navigation and guidance, and estimates of potential guidance precision and mass consumption. This concept is actually a unified Navigation, Guidance and Attitude Control system. The unification is imposed by strong coupling between the orbital motion and the spacecraft attitude characteristic of low thrust space flights. The sensor set of the system consists of an optical instrument (Coupled Sun Star Tracker), and a block of four vector accelerometers. The propulsion subsystem is a set of nearly parallel Hall thrusters rigidly attached to the spacecraft body. The final stage of data processing is combining the thrust and torque programs and generating power and mass rate shares for every thruster. An end-to-end computer simulation provides guidance accuracy estimates versus the navigation data precision, flight time and available maximum thrust. Terminal guidance errors of a few tens of km in position and a few tens of cm/s in velocities are predicted under plausible assumptions on system parameters. Mass expenditures for the control are typically below one percent of total fuel mass budget.     

The challenges and opportunities of a commercial human spaceflight mission to the ISS

ESA astronauts' ISS flight opportunities are considered as a vital source to meet the utilisation, operation and political objectives that Europe has established for participating in the International Space Station programme. Recent internal ESA assessments have demonstrated that a rate of three flights per year for European Astronauts should be maintained as a minimum objective. The current flight rate is lower than this. In order to improve this situation, in the context of the activation of the ESA ISS Commercialisation programme, ESA is developing the conditions for the establishment of commercially based human spaceflights with the financial support of both ESA and the private sector or, in the future, only the latter. ESA is working in a Partnership with the space industry to facilitate the implementation of such projects and support customers with a range of end-to-end commercial services. The opportunities and challenges of a "commercial human spaceflight", involving a member of the European Astronaut Corps, or a privately employed flight participant, are discussed here.     

Erratum to: Determination of the Probability of Collision of Near-Earth Space Objects Taking into Account Form and Orientation

Cosmic Research - An Erratum to this paper has been published: https://doi.org/10.1134/S0010952521120030     

Does the endolymph pass through the base of the cupula?

Whether the endolymph of the semicircular canal passes the cupular partition or not was examined using the lateral semicircular canal system of adult pigeons (Columba livia). By applying various pressures by means of injection of a dye solution through the membranous canal, it was found that the dye solution, was seen to pass the cupula even under very low pressures when the pressure was increased gradually. When pulled by a magnet, the ultrafine particles of the dextran magnetite contained in the injected fluid were found to pass through the subcupular space without evident increase of the ampullary pressure.     

Structure of the Venusian atmosphere from surface up to 100 km

The goal of this paper is to summarize the experimental data on the atmosphere of Venus obtained after 1985, when the VIRA (Venus International Reference Atmosphere) or COSPAR model was published. Among the most important results that have appeared since then are the following: measurements of the vertical temperature profile by the VEGA spacecraft with high precision and high altitude resolution; measurements made with balloons of the VEGA spacecraft; radio occultation measurements of Magellan, Venera-15, and Venera-16; and temperature profiles derived from the data of infrared spectrometry obtained by Venera-15. The new result as compared to VIRA is the creation of a model of the atmosphere in the altitude range 55 to 100 km dependent on local time. This model is presented in our paper in tabulated form.     

Analyse du fonctionnement d'un propulseur a éjection modulée

ONERA developed, for studying the response of a propellant to a pressure or velocity fluctuation, an experimental rocket engine whose nozzle throat area can be modulated by a toothed disk.The paper presents a linearized theory of the functioning of this engine in the low frequency domain, i.e. when there is no wave propagation within the combuster.To describe the functioning of this motor, the Ryazantsev-Novozhilov method, which assumes that the gas response is instantaneous, is used. This analysis takes into account the erosion and radiation effects, the combustion efficiency and the thermal losses through the walls.Two particular cases are described, for two values of the Damköhler parameter $\text{D}{}_1\text{=}\text{t}{}_{\mathrm{c}}\text{t}{}_{\mathrm{th}}$, where t_c is the residence time in the combuster and t_th the characteristic thermal time of the heat penetration into the solid propellant. These two cases correspond, one to a classical propellant D₁ > 1, the other to a particular propellant of low burning rate ($\text{J}{}_{\mathrm{b}}\text{? 0.2}\text{to}\text{0.4}\text{mm s}{}^{\mathrm{?1}}$) D₁ < 1. The stability conditions are analysed as well as the pressure amplitute and phase as a function of the nozzle throat modulation frequency.Still in linearized theory, the complete solutions of the problem are presented, using a method of numerical resolution.     

Distribution of calmodulin in corn seedlings: Immunocytochemical localization in coleoptiles and root apices

Immunofluorescence techniques have been used to study the distribution of calmodulin in several tissues in etiolated corn ( , var. Bear Hybrid) seedlings. Uniform staining was seen in the background cytoplasm of most cell types. Cell walls and vacuoles were not stained. In coleoptile mesophyll cells the nucleoplasm of most nuclei was stained as was the stroma of most amyloplasts. The lumen border of mature tracheary elements in coleoptiles also stained. In the rootcap the most intensely stained regions were the cytoplasms of columella cells and of the outermost cells enmeshed in the layer of secreted slime. Nuclei in the rootcap cells did not stain distinctly, but those in all cell types of the root meristem did. Also in the root meristem, the cytoplasm of metaxylem elements stained brightly. These results are compared and contrasted with previous data on the localization of calmodulin in pea root apices and epicotyls and discussed in relation to current hypotheses on mechanisms of gravitropism.     

Social desirability bias in personality testing: implications for astronaut selection

The assessment of personality is recognized by space agencies as an approach to identify candidates likely to perform optimally during spaceflights. In the use of personality scales for selection, the impact of social desirability (SD) has been cited as a concern. Study 1 addressed the impact of SD on responses to the Personality Characteristic Inventory(PCI) and NEO-FFI. This was achieved by contrasting scores from active astronauts (N=65) with scores of successful astronaut applicants (N=63), and between pilots applicants (N=1271) and pilot research subjects (N=120). Secondly, personality scores were correlated with scores on the Marlow Crown Social Desirability Scale among applicants to managerial positions (N=120). The results indicated that SD inflated scores on PCI scales assessing negative interpersonal characteristics, and impacted on four of five scales in NEO-FFI. Still, the effect sizes were small or moderate. Study 2 addressed performance implications of SD during an assessment of males applying to work as rescue personnel operations in the North Sea (N=22). The results showed that SD correlated negatively with cognitive test performance, and positively with discrepancy in performance ratings between self and two observers. In conclusion, caution is needed in interpreting personality scores in applicant populations. SD maybe a negative predictor for performance under stress.