The formation of sulfate and elemental sulfur aerosols under varying laboratory conditions: implications for early earth

The presence of sulfur mass-independent fractionation (S-MIF) in sediments more than 2.45?×?10(9) years old is thought to be evidence for an early anoxic atmosphere. Photolysis of sulfur dioxide (SO(2)) by UV light with λ?相似文献   

Analysis of Regolith Properties Using Seismic Signals Generated by InSight’s HP<Superscript>3</Superscript> Penetrator

InSight’s Seismic Experiment for Interior Structure (SEIS) provides a unique and unprecedented opportunity to conduct the first geotechnical survey of the Martian soil by taking advantage of the repeated seismic signals that will be generated by the mole of the Heat Flow and Physical Properties Package (HP³). Knowledge of the elastic properties of the Martian regolith have implications to material strength and can constrain models of water content, and provide context to geological processes and history that have acted on the landing site in western Elysium Planitia. Moreover, it will help to reduce travel-time errors introduced into the analysis of seismic data due to poor knowledge of the shallow subsurface. The challenge faced by the InSight team is to overcome the limited temporal resolution of the sharp hammer signals, which have significantly higher frequency content than the SEIS 100 Hz sampling rate. Fortunately, since the mole propagates at a rate of \(\sim1~\mbox{mm}\) per stroke down to 5 m depth, we anticipate thousands of seismic signals, which will vary very gradually as the mole travels.Using a combination of field measurements and modeling we simulate a seismic data set that mimics the InSight HP3-SEIS scenario, and the resolution of the InSight seismometer data. We demonstrate that the direct signal, and more importantly an anticipated reflected signal from the interface between the bottom of the regolith layer and an underlying lava flow, are likely to be observed both by Insight’s Very Broad Band (VBB) seismometer and Short Period (SP) seismometer. We have outlined several strategies to increase the signal temporal resolution using the multitude of hammer stroke and internal timing information to stack and interpolate multiple signals, and demonstrated that in spite of the low resolution, the key parameters—seismic velocities and regolith depth—can be retrieved with a high degree of confidence.     

Response of the ionospheric F-region in the Brazilian sector during the super geomagnetic storm in April 2000 observed by GPS

The response of the ionospheric F-region in the equatorial and low latitude regions in the Brazilian sector during the super geomagnetic storm on 06–07 April 2000 has been studied in the present investigation. The geomagnetic storm reached a minimum D_st of −288 nT at 0100 UT on 07 April. In this paper, we present vertical total electron content (VTEC) and phase fluctuations (in TECU/min) from GPS observations obtained at Imperatriz (5.5°S, 47.5°W; IMPZ), Brasília (15.9°S, 47.9°W; BRAZ), Presidente Prudente (22.12°S, 51.4°W; UEPP), and Porto Alegre (30.1°S, 51.1°W; POAL) during the period 05–08 April. Also, several GPS-based TEC maps are presented from the global GPS network, showing widespread and drastic TEC changes during the different phases of the geomagnetic storm. In addition, ion density measurements on-board the satellite Defense Meteorological Satellite Program (DMSP) F15 orbiting at an altitude of 840 km and the first Republic of China satellite (ROCSAT-1) orbiting at an altitude of 600 km are presented. The observations indicate that one of the orbits of the DMSP satellite is fairly close to the 4 GPS stations and both the DMSP F15 ion-density plots and the phase fluctuations from GPS observations show no ionospheric irregularities in the Brazilian sector before 2358 UT on the night of 06–07 April 2000. During the fast decrease of D_st on 06 April, there is a prompt penetration of electric field of magnetospheric origin resulting in decrease of VTEC at IMPZ, an equatorial station and large increase in VTEC at POAL, a low latitude station. This resulted in strong phase fluctuations on the night of 06–07 April, up to POAL. During the daytime on 07 April during the recovery phase, the VTEC observations show positive ionospheric storm at all the GPS stations, from IMPZ to POAL, and the effect increasing from IMPZ to POAL. This is possibly linked to the equatorward directed meridional wind. During the daytime on 08 April (the recovery phase continues), the VTEC observations show very small negative ionospheric storm at IMPZ but the positive ionospheric storm effect is observed from BRAZ to POAL possibly linked to enhancement of the equatorial ionospheric anomaly.     

Effects observed in the ionospheric F-region in the South American sector during the intense geomagnetic storm of 14 December 2006

This investigation presents observations related to the generation of equatorial ionospheric irregularities (also known as equatorial spread F (ESF)) including ionospheric plasma bubbles and dynamic behavior of the ionospheric F-region in the South American sector during an intense geomagnetic storm in December 2006 (a period of low solar activity). In this work, ionospheric sounding observations and GPS data obtained between 13 and 16 December 2006 at several stations in the South American sector are presented. On the geomagnetically disturbed night of 14 and 15 December, ionospheric plasma bubbles were observed after an unusual uplifting of the F-region during pre-reversal enhancement (PRE) period. The unusual uplifting of the F-region during PRE was possibly associated with prompt penetration of electric field of magnetospheric origin. During the geomagnetic disturbance night of 14 and 15 December, strong oscillations due to the propagation of traveling ionospheric disturbances (TIDs) by the Joule heating in the auroral region were observed in the F-region at São José dos Campos (SJC, 23.2°S, 45.9°W; dip latitude 17.6°S), Brazil, and Port Stanley (PST, 51.6°S, 57.9°W; geom. latitude 41.6°S). The VTEC-GPS observations presented on the night of 14 and 15 December 2006 show both positive and negative storm phases in the South American sector, possibly due to changes in the large-scale wind circulation and changes in the O/N₂ ratio in the southern hemisphere, respectively.     

F-region ionospheric parameters observed in the equatorial and low latitude regions during medium solar activity in the Brazilian sector and comparison with the IRI-2007 model results

The ionospheric sounding observations using the Canadian Advanced Digital Ionosondes (CADIs) operational at Palmas (PAL; 10.2°S, 48.2°W; dip latitude 6.6°S; a near-equatorial station), and São José dos Campos (SJC, 23.2°S, 45.9°W; dip latitude 17.6°S; a low-latitude station located under the southern crest of the equatorial ionospheric anomaly), Brazil, are analyzed during the different seasons viz., winter (June and July 2003), spring (September and October 2003), summer (December 2003 and January 2004), and fall (March and April 2004). The period used has medium solar activity (sunspot number between 77.4 and 39.3). The seasonal mean variations (using only geomagnetically quiet days) of the ionospheric parameters foF2 (critical frequency of the F-region), hpF2 (virtual height at 0.834 foF2; considered to be close to hmF2 (peak height of the F-region)), and h’F (minimum virtual height of the F-region) are calculated and compared between PAL and SJC. The prominent differences between PAL and SJC are as follows: h’F variations show strong post-sunset enhancement at PAL during the seasons of spring, summer, and fall; hpF2 variations show pre-sunrise uplifting of the F-layer at both stations during all the seasons and the hpF2 values during the daytime are lower at SJC compared with PAL during all the seasons; the foF2 variations show mid-day bite-out at PAL during all the seasons and SJC shows strong equatorial ionospheric anomaly during summer and fall seasons. Also, the seasonal variations of the ionospheric parameters foF2 and hpF2 (with ±1 standard deviation) observed at PAL and SJC are compared with the IRI-2007 model results of foF2 and hmF2. In addition, variations of the foF2 and hpF2 observed at SJC are compared with the IRI-2001 model results of foF2 and hmF2. It should be pointed out that the ionospheric parameter hpF2 is much easier to obtain using computer program developed at UNIVAP compared with hmF2 (using POLAN program). During the daytime due to underlying ionization hpF2 estimated is higher (approximately 50 km) than the true peak height hmF2. During the nighttime hpF2 is fairly close to hmF2. The comparison between the foF2 variations observed at PAL and SJC with the IRI-2007 model results shows a fairly good agreement during all the seasons. However, the comparison between the hpF2 variations observed at PAL and SJC with the hmF2 variations with the IRI-2007 model results shows: (1) a fairly good agreement during the nighttime in all the seasons; (2) the model results do not show the pre-sunrise uplifting of the F-layer at PAL and SJC in any season; (3) the model results do not show the post-sunset uplifting of the F-layer at PAL; (4) considering that, in general, hpF2 is higher than hmF2 during the daytime by about 50 km, the model results are in good agreement at PAL and SJC during all the seasons except summer at SJC, when large discrepancies in the observed hpF2 and modeled hmF2 are observed. Also, it has been observed that, in general, hmF2 values for SJC calculated using IRI-2001 are higher than IRI-2007 during the daytime in winter, summer, and fall. However, hmF2 values for SJC calculated using IRI-2001, are lower than IRI-2007 during the nighttime in spring.