Bioelectrochemical degradation of urea at platinized boron doped diamond electrodes for bioregenerative systems

The recovery of potable water from space mission wastewater is critical for the life support and environmental health of crew members in long-term missions. NASA estimates reveal that at manned space missions 1.91 kg/person day of urine is produced, with urea and various salts as its main components. In this research we explore the utilization of urease (EC 3.5.1.5, 15,000 U/g) along with a platinized boron doped diamond electrode (Pt-BDD) to degrade urea. Urea is directly degraded to nitrogen by the in situ utilization of the reaction products as a strategy to increase the amount of clean water in future space expeditions. The biochemical reaction of urease produces ammonia and carbon dioxide from urea. Thereafter, ammonia is electrooxidized at the interface of the Pt-BDD producing molecular nitrogen. The herein presented system has been proven to have 20% urea conversion efficiency. This research has potential applications for future long-term space missions since the reaction byproducts could be used for a biomass subsystem (in situ resource recovery), while generating electricity from the same process.     

Mathematical modeling of heat transfer process in a variable domain

In this paper, a brief review and generalization of studies on the heat transfer and heat conduction problem in a variable domain are presented. The equations of the process, where the boundary displacement velocity is the control, are obtained taking into account heat inflow. This article was submitted by the authors in English.     

Organizing and managing satellite solar power

Building an organization and management structure to create, launch, utilize and protect a satellite solar power energy system will require a global policy for the beneficial use of SSP. The fundamental organizational tasks are: (1) R&D, achieved through a project organization characterized by the integrated management of applied science, development research and construction engineering; (2) investment, generated by a series of groups creating financial vehicles for public and private investment; (3) transmission and distribution, characterized by attention to an engineering and maintenance process emphasizing high reliability; and (4) crisis response, demanding readiness for instant response to potential internal or external scenarios. A differentiated global organization spanning the long timeframe of SSP will need to have a central management core representative of all parts of the organization, with the capacity for self-renewal and re-adaptation. To be successful over its long timeframe, the SSP organization will need to build continuity and public confidence through intergenerational communication, public education, and community outreach. Integrating structures must be created at all levels of the organization, and should encompass joint work tasks and information-sharing among both industrial and government members. Developmental and alliance partners who support the formation and financing of a differentiated satellite solar power organization will share commensurately in the technologies and competencies that are created.     

On the effects of electron-cyclotron masers during flares

First recognized by Wu and Lee (Ap. J. 230, 621, 1979), electron-cyclotron masers can be activated under very mild conditions. Large growth rates can occur even for relatively mild anisotropies in the electron velocity distribution, e.g., the one-sided loss cones that commonly occur when electrons with small pitch angles precipitate into high density regions at the footpoints of flaring loops while others are reflected in the converging field in the corona. Maser action can plausibly occur at the second harmonic of the local gyrofrequency and so explain certain very bright (? 10¹⁰ K) microwave bursts from the sun and other stars. However, the preponderance of the energy is at the first harmonic.We suggest that masers operating at the local gyrofrequency in a flaring loop generate radiation at decimeter wavelengths that is a significant fraction of the total energy of the flare, in fact (and not coincidentally) comparable with the energy in electrons associated with hard X-ray bursts. Essentially all of the radio energy is trapped in the corona and serves to produce localized heating in a volume large compared with the energy release region. Thus it can transfer energy by radiation from one magnetic loop to another, possibly inducing further instabilities, and spreading the course of the flare. Eventually the energy probably escapes the corona as soft X-rays. The electron-cyclotron maser saturates by extracting the perpendicular energy of the electrons, thereby diffusing them into the loss cone at the maximum possible rate; the enhanced precipitation into the footpoints can produce bright emission in hard X-rays, EUV and Hα and remove any necessity for directive acceleration in the energy release region.Details of the proposed mechanism and effects are contained in two papers by Melrose and Dulk (Ap. J. 259, 1982).This work was sponsored by NASA under grants NAGW-91 and NSG-7287 to the University of Colorado.     

Optimization of imperfect stiffened cylinders under destabilizing loads

A design procedure is outlined for optimizing stiffened, thin circular, cylindrical shells subject to a given set of destabilizing loads, in the presence of a specified initial geometric imperfection. The procedure incorporates two distinct steps (a) optimization based on linear buckling analyses and (b) imperfection sensitivity studies of the optimum design point from (a) as well as of the surrounding design space. A comparison of all these designs yield the true optimum in the presence of the specified geometric imperfection. The present methodology is fully demonstrated through two illustrative examples, one dealing with an axially loaded stiffened cylinder and one with a torsionally loaded one.     

Why space physics needs to go beyond the MHD box

Magnetohydrodynamic (MHD) theory has been used in space physics for more than forty years, yet many important questions about space plasmas remain unanswered. We still do not understand how the solar wind is accelerated, how mass, momentum and energy are transported into the magnetosphere and what mechanisms initiate substorms. Questions have been raised from the beginning of the space era whether MHD theory can describe correctly space plasmas that are collisionless and rarely in thermal equilibrium. Ideal MHD fluids do not induce electromotive force, hence they lose the capability to interact electromagnetically. No currents and magnetic fields are generated, rendering ideal MHD theory not very useful for space plasmas. Observations from the plasma sheet are used as examples to show how collisionless plasmas behave. Interpreting these observations using MHD and ideal MHD concepts can lead to misleading conclusions. Notably, the bursty bulk flows (BBF) with large mean velocities left(〈 v 〉≥400 km s right) that have been interpreted previously as E×B flows are shown to involve much more complicated physics. The sources of these nonvanishing 〈 v 〉 events, while still not known, are intimately related to mechanisms that create large phase space gradients that include beams and acceleration of ions to MeV energies. The distributions of these nonvanishing 〈 v 〉 events are associated with large amplitude variations of the magnetic field at frequencies up to and exceeding the local Larmor frequency where MHD theory is not valid. Understanding collisionless plasma dynamics such as substorms in the plasma sheet requires the self-consistency that only kinetic theory can provide. Kinetic modeling is still undergoing continual development with many studies limited to one and two dimensions, but there is urgent need to improve these models as more and more data show kinetic physics is fundamentally important. Only then will we be able to make progress and obtain a correct picture of how collisionless plasmas work in space.     

ExoMars 2016 Schiaparelli Module Trajectory and Atmospheric Profiles Reconstruction

On 19^th October 2016 Schiaparelli module of the ExoMars 2016 mission flew through the Mars atmosphere. After successful entry and descent under parachute, the module failed the last part of the descent and crashed on the Mars surface. Nevertheless the data transmitted in real-time by Schiaparelli during the entry and descent, together with the entry state vector as initial condition, have been used to reconstruct both the trajectory and the profiles of atmospheric density, pressure and temperature along the traversed path.The available data-set is only a small sub-set of the whole data acquired by Schiaparelli, with a limited data rate (8 kbps) and a large gap during the entry because of the plasma blackout on the communications.This paper presents the work done by the AMELIA (Atmospheric Mars Entry and Landing Investigations and Analysis) team in the exploitation of the available inertial and radar data. First a reference trajectory is derived by direct integration of the inertial measurements and a strategy to overcome the entry data gap is proposed. First-order covariance analysis is used to estimate the uncertainties on all the derived parameters. Then a refined trajectory is computed incorporating the measurements provided by the on-board radar altimeter.The derived trajectory is consistent with the events reported in the telemetry and also with the impact point identified on the high-resolution images of the landing site.Finally, atmospheric profiles are computed tacking into account the aerodynamic properties of the module. Derived profiles result in good agreement with both atmospheric models and available remote sensing observations.     

The Delivery of Water During Terrestrial Planet Formation

The planetary building blocks that formed in the terrestrial planet region were likely very dry, yet water is comparatively abundant on Earth. Here we review the various mechanisms proposed for the origin of water on the terrestrial planets. Various in-situ mechanisms have been suggested, which allow for the incorporation of water into the local planetesimals in the terrestrial planet region or into the planets themselves from local sources, although all of those mechanisms have difficulties. Comets have also been proposed as a source, although there may be problems fitting isotopic constraints, and the delivery efficiency is very low, such that it may be difficult to deliver even a single Earth ocean of water this way. The most promising route for water delivery is the accretion of material from beyond the snow line, similar to carbonaceous chondrites, that is scattered into the terrestrial planet region as the planets are growing. Two main scenarios are discussed in detail. First is the classical scenario in which the giant planets begin roughly in their final locations and the disk of planetesimals and embryos in the terrestrial planet region extends all the way into the outer asteroid belt region. Second is the Grand Tack scenario, where early inward and outward migration of the giant planets implants material from beyond the snow line into the asteroid belt and terrestrial planet region, where it can be accreted by the growing planets. Sufficient water is delivered to the terrestrial planets in both scenarios. While the Grand Tack scenario provides a better fit to most constraints, namely the small mass of Mars, planets may form too fast in the nominal case discussed here. This discrepancy may be reduced as a wider range of initial conditions is explored. Finally, we discuss several more recent models that may have important implications for water delivery to the terrestrial planets.     

Order out of Randomness: Self-Organization Processes in Astrophysics

Self-organization is a property of dissipative nonlinear processes that are governed by a global driving force and a local positive feedback mechanism, which creates regular geometric and/or temporal patterns, and decreases the entropy locally, in contrast to random processes. Here we investigate for the first time a comprehensive number of (17) self-organization processes that operate in planetary physics, solar physics, stellar physics, galactic physics, and cosmology. Self-organizing systems create spontaneous “order out of randomness”, during the evolution from an initially disordered system to an ordered quasi-stationary system, mostly by quasi-periodic limit-cycle dynamics, but also by harmonic (mechanical or gyromagnetic) resonances. The global driving force can be due to gravity, electromagnetic forces, mechanical forces (e.g., rotation or differential rotation), thermal pressure, or acceleration of nonthermal particles, while the positive feedback mechanism is often an instability, such as the magneto-rotational (Balbus-Hawley) instability, the convective (Rayleigh-Bénard) instability, turbulence, vortex attraction, magnetic reconnection, plasma condensation, or a loss-cone instability. Physical models of astrophysical self-organization processes require hydrodynamic, magneto-hydrodynamic (MHD), plasma, or N-body simulations. Analytical formulations of self-organizing systems generally involve coupled differential equations with limit-cycle solutions of the Lotka-Volterra or Hopf-bifurcation type.