Organic Chemistry and Exobiology on Titan

Exobiology is not only the study of the origin, distribution and evolution of life in the universe, but also of structures — including at the molecular level, and processes — including organic chemical transformations — related to life. In that respect, with its dense nitrogen atmosphere, which includes a noticeable fraction of methane, and the many organic compounds which are present in the gas and aerosols phases, Titan appears to be a planetary object of prime interest for exobiology in the Solar system, allowing the study of chemical organic evolution in a planetary environment over a long time scale. We describe here some aspects of this extraterrestrial organic chemistry which involves many physical and chemical couplings in the different parts of what can be called ‘Titan's geofluid’ (gas phase, aerosol phases and surface solid and maybe liquid phases). The three complementary approaches which can be followed to study such chemistry of exobiological interest are considered. Those are experimental simulations in the laboratory, chemical and photochemical modeling and of course observation, using both remote sensing and in situ measurements, which is an essential approach. The Cassini-Huygens mission, that offers a unique opportunity to study in detail the many aspects of Titan's organic chemistry, is discussed and the many expected exobiological returns from the different instruments of the Cassini orbiter and the Huygens probe are considered. This revised version was published online in August 2006 with corrections to the Cover Date.     

ULF waves: Conjugated ground-satellite relationships

We study the simultaneous occurrence of ULF waves observed on board GEOS and at two of its conjugated stations: Husafell (Iceland) and Skibotn (Norway). We try to deduce some properties of the regions in which these waves are generated. The few number of simultaneous observations of pearl events indicates that such structured oscillations can occur only in specific conditions which are not met generally at the geostationary altitude. We introduce a new method for measuring time delays between the satellite and the ground. We show that this time is much higher than it would be expected from a simple extrapolation of measurements done at lower latitudes on structured events.     

1. Transport of Mass,Momentum and Energy in Planetary Magnetodisc Regions

The rapid rotation of the gas giant planets, Jupiter and Saturn, leads to the formation of magnetodisc regions in their magnetospheric environments. In these regions, relatively cold plasma is confined towards the equatorial regions, and the magnetic field generated by the azimuthal (ring) current adds to the planetary dipole, forming radially distended field lines near the equatorial plane. The ensuing force balance in the equatorial magnetodisc is strongly influenced by centrifugal stress and by the thermal pressure of hot ion populations, whose thermal energy is large compared to the magnitude of their centrifugal potential energy. The sources of plasma for the Jovian and Kronian magnetospheres are the respective satellites Io (a volcanic moon) and Enceladus (an icy moon). The plasma produced by these sources is globally transported outwards through the respective magnetosphere, and ultimately lost from the system. One of the most studied mechanisms for this transport is flux tube interchange, a plasma instability which displaces mass but does not displace magnetic flux—an important observational constraint for any transport process. Pressure anisotropy is likely to play a role in the loss of plasma from these magnetospheres. This is especially the case for the Jovian system, which can harbour strong parallel pressures at the equatorial segments of rotating, expanding flux tubes, leading to these regions becoming unstable, blowing open and releasing their plasma. Plasma mass loss is also associated with magnetic reconnection events in the magnetotail regions. In this overview, we summarise some important observational and theoretical concepts associated with the production and transport of plasma in giant planet magnetodiscs. We begin by considering aspects of force balance in these systems, and their coupling with the ionospheres of their parent planets. We then describe the role of the interaction between neutral and ionized species, and how it determines the rate at which plasma mass and momentum are added to the magnetodisc. Following this, we describe the observational properties of plasma injections, and the consequent implications for the nature of global plasma transport and magnetodisc stability. The theory of the flux tube interchange instability is reviewed, and the influences of gravity and magnetic curvature on the instability are described. The interaction between simulated interchange plasma structures and Saturn’s moon Titan is discussed, and its relationship to observed periodic phenomena at Saturn is described. Finally, the observation, generation and evolution of plasma waves associated with mass loading in the magnetodisc regions is reviewed.     

GPS phase difference variation statistics: A comparison between phase scintillation index and proxy indices

Scintillated GPS phase observations are traditionally characterized by the phase scintillation index, derived from specialized GPS receivers usually tracking at 50 Hz. Geodetic quality GPS receivers, on the other hand, are normally tracking at frequencies up to 1 Hz. However, availability of continuously operating geodetic receivers both in time and geographical location are superior to scintillation receiver’s coverage in many parts of the world. This motivates scintillation studies using regional and global geodetic GPS networks. Previous studies have shown the usefulness of GPS estimated total electron content variations for detecting ionospheric irregularities. In this paper, collocated geodetic and scintillation receivers are employed to compare proxy indices derived from geodetic receivers with the phase scintillation index during quiet and moderately disturbed ionospheric conditions. Sensitivity of the phase scintillation indices at high latitude stations to geomagnetic activity is discussed. Global mapping of ionospheric disturbances using proxy indices from real-time 1 Hz GPS stations are also presented.     

The Solar System d/h Ratio: Observations and Theories

The measured D/H ratios in interstellar environments and in the solar system are reviewed. The two extreme D/H ratios in solar system water - (720±120)×10⁻⁶ in clay minerals and (88±11)×10⁻⁶ in chondrules, both from LL3 chondritic meteorites - are interpreted as the result of a progressive isotopic exchange in the solar nebula between deuterium-rich interstellar water and protosolar H₂. According to a turbulent model describing the evolution of the nebula (Drouart et al., 1999), water in the solar system cannot be a product of thermal (neutral) reactions occurring in the solar nebula. Taking 720×10⁻⁶ as a face value for the isotopic composition of the interstellar water that predates the formation of the solar nebula, numerical simulations show that the water D/H ratio decreases via an isotopic exchange with H₂. During the course of this process, a D/H gradient was established in the nebula. This gradient was smoothed with time and the isotopic homogenization of the solar nebula was completed in 10⁶ years, reaching a D/H ratio of 88×10⁻⁶. In this model, cometary water should have also suffered a partial isotopic re-equilibration with H₂. The isotopic heterogeneity observed in chondrites result from the turbulent mixing of grains, condensed at different epochs and locations in the solar nebula. Recent isotopic determinations of water ice in cold interstellar clouds are in agreement with these chondritic data and their interpretation (Texeira et al., 1999). This revised version was published online in June 2006 with corrections to the Cover Date.     

Mathematical modeling of heat transfer process in a variable domain

In this paper, a brief review and generalization of studies on the heat transfer and heat conduction problem in a variable domain are presented. The equations of the process, where the boundary displacement velocity is the control, are obtained taking into account heat inflow. This article was submitted by the authors in English.     

Organic syntheses in gas phase and chemical evolution in planetary atmospheres

Atmospheric chemistry may be one of the important pathways to the synthesis of organic compounds in a planetary periphery. Depending on the nature of the carbon source (CH₄, CO or CO₂), the main composition of the atmosphere, and the respective roles of the various energy sources, is it possible, and to what extent, to produce organics? What kind of gaseous mixture is the most favourable to prebiotic organic syntheses? How far can the results of laboratory works be extrapolated to the case of planetary atmospheres? These questions are discussed, on the basis of several available laboratory data, and by considering the main atmospheric composition of the planets of the solar system, and the list of organic compounds which have already been dettected in their atmospheres.     

ExoMars 2016 Schiaparelli Module Trajectory and Atmospheric Profiles Reconstruction

On 19^th October 2016 Schiaparelli module of the ExoMars 2016 mission flew through the Mars atmosphere. After successful entry and descent under parachute, the module failed the last part of the descent and crashed on the Mars surface. Nevertheless the data transmitted in real-time by Schiaparelli during the entry and descent, together with the entry state vector as initial condition, have been used to reconstruct both the trajectory and the profiles of atmospheric density, pressure and temperature along the traversed path.The available data-set is only a small sub-set of the whole data acquired by Schiaparelli, with a limited data rate (8 kbps) and a large gap during the entry because of the plasma blackout on the communications.This paper presents the work done by the AMELIA (Atmospheric Mars Entry and Landing Investigations and Analysis) team in the exploitation of the available inertial and radar data. First a reference trajectory is derived by direct integration of the inertial measurements and a strategy to overcome the entry data gap is proposed. First-order covariance analysis is used to estimate the uncertainties on all the derived parameters. Then a refined trajectory is computed incorporating the measurements provided by the on-board radar altimeter.The derived trajectory is consistent with the events reported in the telemetry and also with the impact point identified on the high-resolution images of the landing site.Finally, atmospheric profiles are computed tacking into account the aerodynamic properties of the module. Derived profiles result in good agreement with both atmospheric models and available remote sensing observations.     

The Delivery of Water During Terrestrial Planet Formation

The planetary building blocks that formed in the terrestrial planet region were likely very dry, yet water is comparatively abundant on Earth. Here we review the various mechanisms proposed for the origin of water on the terrestrial planets. Various in-situ mechanisms have been suggested, which allow for the incorporation of water into the local planetesimals in the terrestrial planet region or into the planets themselves from local sources, although all of those mechanisms have difficulties. Comets have also been proposed as a source, although there may be problems fitting isotopic constraints, and the delivery efficiency is very low, such that it may be difficult to deliver even a single Earth ocean of water this way. The most promising route for water delivery is the accretion of material from beyond the snow line, similar to carbonaceous chondrites, that is scattered into the terrestrial planet region as the planets are growing. Two main scenarios are discussed in detail. First is the classical scenario in which the giant planets begin roughly in their final locations and the disk of planetesimals and embryos in the terrestrial planet region extends all the way into the outer asteroid belt region. Second is the Grand Tack scenario, where early inward and outward migration of the giant planets implants material from beyond the snow line into the asteroid belt and terrestrial planet region, where it can be accreted by the growing planets. Sufficient water is delivered to the terrestrial planets in both scenarios. While the Grand Tack scenario provides a better fit to most constraints, namely the small mass of Mars, planets may form too fast in the nominal case discussed here. This discrepancy may be reduced as a wider range of initial conditions is explored. Finally, we discuss several more recent models that may have important implications for water delivery to the terrestrial planets.     

Order out of Randomness: Self-Organization Processes in Astrophysics

Self-organization is a property of dissipative nonlinear processes that are governed by a global driving force and a local positive feedback mechanism, which creates regular geometric and/or temporal patterns, and decreases the entropy locally, in contrast to random processes. Here we investigate for the first time a comprehensive number of (17) self-organization processes that operate in planetary physics, solar physics, stellar physics, galactic physics, and cosmology. Self-organizing systems create spontaneous “order out of randomness”, during the evolution from an initially disordered system to an ordered quasi-stationary system, mostly by quasi-periodic limit-cycle dynamics, but also by harmonic (mechanical or gyromagnetic) resonances. The global driving force can be due to gravity, electromagnetic forces, mechanical forces (e.g., rotation or differential rotation), thermal pressure, or acceleration of nonthermal particles, while the positive feedback mechanism is often an instability, such as the magneto-rotational (Balbus-Hawley) instability, the convective (Rayleigh-Bénard) instability, turbulence, vortex attraction, magnetic reconnection, plasma condensation, or a loss-cone instability. Physical models of astrophysical self-organization processes require hydrodynamic, magneto-hydrodynamic (MHD), plasma, or N-body simulations. Analytical formulations of self-organizing systems generally involve coupled differential equations with limit-cycle solutions of the Lotka-Volterra or Hopf-bifurcation type.