Fuel cell status, 1994

The high efficiency environmental benefits and other attributes of fuel cells have attracted world-wide attention to the technology. Approximately 250 phosphoric acid fuel cell (PAFC) power units, 35 molten carbonate fuel cell (MCFC) stacks, and 12 solid oxide fuel cell (SOFC) modules have been or are being operated. Total capacity installed or operating is close to 45 MW. Fuel cell development has progressed to where complete power plants have reached nearly 16,000 operating hours and this continues to increase. Developers in the U.S. and Japan have embarked on extensive government and private programs to commercialize the technology in those countries and abroad. By mid-1994, the U.S. sold and shipped to other countries at least 33 PAFC 200 kW plants, 20 675 kW PAFC stacks, two SOFC 25 kW modules, and one MCFC system. Additional units have been produced for the domestic market. There is intense interest in Japan where there are very stringent environmental regulations and fuel prices are high. The fuel cell can respond with its combined attributes of low emissions and relative high efficiency. In Europe, the environmental cleanliness of fuel cell power units holds the promise of preserving the quality of life, motivating support and development of the technology. Canada and Australia have spawned important development programs. Interest continues to increase in other parts of the world. The author reviews the 1994 status and outlines the future development trends in this area     

Satellite observations of sea ice

An overview is presented of Antarctic and Arctic sea ice studies using data from the Nimbus-5 ESMR and the Nimbus-7 SMMR passive microwave radiometers. Four years (1973–1976) of ESMR data for the Antarctic Ocean define the characteristics of the seasonal cycle including regional contrasts and interannual variations. Major advances include the discovery of the Weddell polynya and the presence of substantial areas of open water in the Antarctic winter pack ice. Regional differences in sea ice extent on time-scales of about a month are shown to be associated with variations in surface-wind fields. In the Arctic, the computation of sea ice concentration is complicated by the presence of multiyear ice, but the amount of multiyear ice becomes an important measurable quantity with dual-polarized, multifrequency passive microwave sensors. Analysis of SMMR data demonstrates its advantage for studying the spatial and temporal variability of the Arctic ice cover. Large observed interannual variations in the distribution of the multiyear pack ice and the presence of significant divergent areas in the central Arctic during winter contrast markedly with the classical view of the Arctic pack ice.     

Light microscopic analysis of the gravireceptor in Xenopus larvae developed in hypogravity.

The paper describes an investigation of the influence of gravity on the early differentiation of gravity receptors in Xenopus embryos and larvae. There is evidence that the expression of crystals in the saccus endolymphaticus was statistically greater when the embryos developed in near weightlessness (hypogravity) than on earth. The function of these crystals is unknown but they may contribute to the functioning of the vestibular apparatus.     

Origin of organic compounds in carbonaceous chondrites.

Carbonaceous chondrites, a class of primitive meteorite, have long been known to contain their complement of carbon largely in the form of organic, i.e., hydrocarbon-related, matter. Both discrete organic compounds and an insoluble, macromolecular material are present. Several characteristics of these materials provide evidence for their abiotic origin. The principal formation hypotheses have invoked chemistry occurring either in the solar nebula or on the parent body. However, recent stable isotope analyses of the meteorite carboxylic acids and amino acids indicate that they may be related to interstellar cloud compounds. These results suggest a formation scheme in which interstellar compounds were incorporated into the parent body and subsequently converted to the present suite of meteorite organics by the hydrothermal process believed to have formed the clay minerals of the meteorite matrix.     

Free radicals induced in solid DNA by heavy ion bombardment.

Free radical formation after heavy-ion bombardment was studied in solid, polycristalline pellets of DNA-constituents by analysing the dose-yield curves and the spectra obtained by ESR-spectroscopy at low (< 100 K) and ambient temperatures. The dose-yield curves were found to correlate with those found after X-irradiation but shifted to higher doses and lower saturation concentrations. The corresponding radical yields (per 100 eV) exhibit values which are one to two orders of magnitudes lower. The structural aspects as revealed from powder ESR-spectra gave a complex inter-relation between substance, LET, dose and irradiation temperature, which is discussed in terms of mechanistic models.     

Assessing exposure to cosmic radiation on board aircraft.

The assessment of exposure to cosmic radiation on board aircraft is one of the preoccupations of organizations responsible for radiation protection. The cosmic radiation particle flux increases with altitude and latitude and depends on the solar activity. The radiation exposure has been estimated on several airlines using transatlantic, Siberian and transequatorial routes on board subsonic and supersonic aircraft, to illustrate the effect of these parameters. Measurements have been obtained with a tissue equivalent proportional counter using the microdosimetric technique. Data have been collected at maximum solar activity in 1991-92 and at minimum in 1996-98. The lowest mean dose rate measured was 3 microSv/h during a Paris-Buenos Aires flight in 1991; the highest was 6.6 microSv/h during a Paris-Tokyo flight using a Siberian route and 9.7 microSv/h on Concorde in 1996-97. The mean quality factor is around 1.8. The corresponding annual effective dose, based on 700 hours of flight for subsonic aircraft and 300 hours for Concorde, can be estimated between 2 mSv for least-exposed routes and 5 mSv for more exposed routes.     

Physiological, biochemical and molecular processes associated with gravitropism in roots of maize.

This research aims to characterize regulation of the principal cytosolic protein kinases in maize, cultivar 'Merit' root tips, since much evidence indicates that stimuli which modulate the gravitropic response in this system act through regulation of activity of these enzymes. To this end, we have cloned a maize protein kinase belonging to a group of plant protein kinases with a catalytic domain similar in primary structure to the second messenger-regulated protein kinases known in animal and fungal systems. However, both the unique structural features conserved among plant protein kinases in this group, and lack of evidence for cyclic nucleotide signalling in plants point to operation of a novel protein kinase regulatory mechanism in plants. In order to test effects of possible regulators on protein kinase activity, we developed a sensitive method for detecting regulation of autophosphoryl labelling of protein kinases in unfractionated maize protein extracts. Regulation of protein kinase autophosphorylation in these extracts was different from that known in animals and fungi, further suggesting operation of unique protein kinase regulatory mechanisms in plants. Previous research has shown that light, or factors modulated by light, regulate plant protein kinase activity. We found that protein kinase activity was co-immunoprecipitated with the plant photoreceptor phytochrome, and was associated with phytochrome by high-affinity chemical interactions. Far-red reversibility of red-light regulation of phytochrome phosphorylation by the associated protein kinase indicates that it may modulate or transduce the light signals which lead to gravitropic sensitivity in 'Merit' maize.     

Performance and reliability of the NASA Biomass Production Chamber.

The Biomass Production Chamber (BPC) at the Kennedy Space Center is part of the Controlled Ecological Life Support System (CELSS) Breadboard Project. Plants are grown in a closed environment in an effort to quantify their contributions to the requirements for life support. Performance of this system is described. Also, in building this system, data from component and subsystem failures are being recorded. These data are used to identify problem areas in the design and implementation. The techniques used to measure the reliability will be useful in the design and construction of future CELSS. Possible methods for determining the reliability of a green plant, the primary component of a CELSS, are discussed.     

Galactic cosmic ray transport methods: past, present, and future.

The development of the theory of high charge and energy (HZE) ion transport is reviewed. The basic solution behavior and approximation techniques will be described. An overview of the HZE transport codes currently available at the Langley Research Center will be given. The near term goal of the Langley program is to produce a complete set of one-dimensional transport codes. The ultimate goal is to produce a set of complete three-dimensional codes which have been validated in the laboratory and can be applied in the engineering design environment. Recent progress toward completing these goals is discussed.