Heterogeneous solid/gas chemistry of organic compounds related to comets,meteorites, Titan,and Mars: Laboratory and in lower Earth orbit experiments

To understand the evolution of organic molecules involved in extraterrestrial environments and with exobiological implications, many experimental programs in the laboratory are devoted to photochemical studies in the gaseous phase as well as in the solid state. The validity of such studies and their applications to extraterrestrial environments can be questioned as long as experiments conducted in space conditions, with the full solar spectrum, especially in the short wavelength domain, have not been implemented. The experiments that are described here will be carried out on a FOTON capsule, using the BIOPAN facility, and on the International Space Station, using the EXPOSE facility. Vented and sealed exposition cells will be used, which will allow us to study the chemical evolution in the gaseous phase as well as heterogeneous processes, such as the degradation of solid compounds and the release of gaseous fragments.     

Detection of martian amino acids by chemical derivatization coupled to gas chromatography: in situ and laboratory analysis.

If there is, or ever was, life in our solar system beyond the Earth, Mars is the most likely place to search for. Future space missions will have then to take into account the detection of prebiotic molecules or molecules of biological significance such as amino acids. Techniques of analysis used for returned samples have to be very sensitive and avoid any chemical or biological contamination whereas in situ techniques have to be automated, fast and low energy consuming. Several possible methods could be used for in situ amino acid analyses on Mars, but gas chromatography would likely be the most suitable. Returned samples could be analyzed by any method in routine laboratory use such as gas chromatography, already successfully performed for analyses of organic matter including amino acids from martian meteorites. The derivatization step, which volatilizes amino acids to perform both in situ and laboratory analysis by gas chromatography, is discussed here.     

Cosac, The Cometary Sampling and Composition Experiment on Philae

Comets are thought to preserve the most pristine material currently present in the solar system, as they are formed by agglomeration of dust particles in the solar nebula, far from the Sun, and their interiors have remained cold. By approaching the Sun, volatile components and dust particles are released forming the cometary coma. During the phase of Heavy Bombardment, 3.8--4 billion years ago, cometary matter was delivered to the Early Earth. Precise knowledge on the physico-chemical composition of comets is crucial to understand the formation of the Solar System, the evolution of Earth and particularly the starting conditions for the origin of life on Earth. Here, we report on the COSAC instrument, part of the ESA cometary mission Rosetta, which is designed to characterize, identify, and quantify volatile cometary compounds, including larger organic molecules, by in situ measurements of surface and subsurface cometary samples. The technical concept of a multi-column enantio-selective gas chromatograph (GC) coupled to a linear reflectron time-of-flight mass-spectrometer instrument is presented together with its realisation under the scientific guidance of the Max-Planck-Institute for Solar System Research in Katlenburg-Lindau, Germany. The instrument's technical data are given; first measurements making use of standard samples are presented. The cometary science community is looking forward to receive fascinating data from COSAC cometary in situ measurements in 2014.     

Radar-Derived Properties of the InSight Landing Site in Western Elysium Planitia on Mars

We carried out an assessment of surface and subsurface properties based on radar observations of the region in western Elysium Planitia selected as the landing site for the InSight mission. Using observations from Arecibo Observatory and from the Mars Reconnaissance Orbiter’s Shallow Radar (SHARAD), we examined the near-surface properties of the landing site, including characterization of reflectivity, near-surface roughness, and layering. In the Arecibo data (12.6-cm wavelength), we found a radar-reflective surface with no unusual properties that would cause problems for the InSight radar altimeter (7-cm wavelength). In addition, the moderately low backscatter strength is indicative of a relatively smooth surface at \({\sim} 10\mbox{-cm}\) scales that is composed of load-bearing materials and should not present a hazard for landing safety. For roughness at 10–100 m scales derived from SHARAD data, we find relatively low values in a narrow distribution, similar to those found at the Phoenix and Opportunity landing sites. The power of returns at InSight is similar to that at Phoenix and thus suggestive of near-surface layering, consistent with a layer of regolith over bedrock (e.g., lava flows) that is largely too shallow (\({<}10\mbox{--}20~\mbox{m}\)) for SHARAD to discern distinct reflectors. However, an isolated area outside of the ellipse chosen in 2015 for InSight’s landing shows faint returns that may represent such a contact at depths of \({\sim} 20\mbox{--}43~\mbox{m}\).